Preparation and performance study of modified soybean oil polyurethane foam used for soccer equipment

• Published in: Journal of applied polymer science 2023-08, Vol.140 (29), p.n/a
• Main Authors: Zhang, Jincheng, Hao, Ruoyu, Tian, Xiaoke, Hao, Tonghui
• Format: Article
• Language: English
• Subjects: Bulk density; Carbon; Chemical synthesis; Compressive strength; Dynamic stability; dynamic thermomechanical analysis (DMA); Electron microscopes; high resilience flexible polyurethane foam (HR‐PUF); Hydroxyl groups; Materials science; Polymers; Polyols; Polyurethane foam; polyurethane foams; Reaction time; Resilience; Room temperature; Soccer; Soybean oil; Soybeans; Stability analysis; synthetic process; Thermal stability; Thermogravimetric analysis; thermogravimetric analysis (TGA); Thermomechanical analysis; Vegetable oils
• ISSN: 0021-8995; 1097-4628
• DOI: 10.1002/app.54071

Soccer is known as the world's largest sport and has a wide range of players. Most of the materials used in existing football equipment are polyurethane extracted from petrochemical resources, which are gradually reduced and non‐renewable. Finding an alternative new material is an inevitable trend. Soybean oil (SO) was quantitatively transformed into polyols to afford industrially important high resilience flexible polyurethane foam(HR‐PUF). Photoinduced thiol‐ene click chemistry was investigated for the efficient preparation of modified soybean oil polyols (MESO) with primary hydroxyl groups. In order to improve the reaction efficiency and the degree of carbon–carbon double bonds functionalization, reduce reaction time, we have chosen a step‐by‐step method of adding. The effects of different reaction times and [thiol]/[ene] ratios on conversion and degree of functionalization were discussed. It is realized that under room temperature conditions, after 12 h of reaction, the carbon–carbon double bond of SO is almost completely converted and quantitatively converted into a hydroxyl group to a degree of 89%. The corresponding HR‐PUFs were prepared by mixing MESO with L2000 (Polyether Polyol). The effect of the difference in the amount of MESO added to the foam properties was investigated. Through the apparent density and a scanning electron microscope (SEM), it can be concluded that with the amount of MESO added increases, the cell size, opening ratio and the number of cells of HR‐PUF are decreased, the density is increased. Through thermogravimetric analysis (TGA) and dynamic thermomechanical analysis (DMA), it was proved that the thermal stability of the foam increased with the addition of MESO. Through 40% compression strength (CLD40%), ball rebound experiments, and static compression experiment. It is proved that the increase of the addition of MESO, the rebound resilience of HR‐PUF can be improved. The preparation route of HR‐PUF.