A homogeneity study on (Ce,Gd)3Ga2Al3O12 crystal scintillators grown by an optical floating zone method and a traveling solvent floating zone method

1 at% Ce3+-doped Gd3Ga2Al3O12 (GGAG) single crystals were grown by an optical floating zone (OFZ) method and a traveling solvent floating zone (TSFZ) method. To reveal their structure and chemical composition homogeneity, X-ray diffraction (XRD) and high-resolution inductively coupled plasma atomic...

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Bibliographic Details
Published in:CrystEngComm 2023-05, Vol.25 (26), p.3755-3765
Main Authors: Wu, Tong, Wang, Ling, Shi, Yun, Zhang, Qian, Xiong, Yifei, Yuan, Qiang, Li, Tongtong, Ma, Kaicheng, Wang, Hui, Fang, Jinghong, Ni, Jinqi, He, Huan, Zhou, Zhenzhen, Liu, Qian, Yu, Jianding, Zou, Jun
Format: Article
Language:English
Subjects:
Cerium
Chemical composition
Crystal growth
Crystals
Gadolinium
Glow curves
Homogeneity
Inductively coupled plasma
Photoluminescence
Scintillation counters
Single crystals
Solidification
Solvents
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Summary:1 at% Ce3+-doped Gd3Ga2Al3O12 (GGAG) single crystals were grown by an optical floating zone (OFZ) method and a traveling solvent floating zone (TSFZ) method. To reveal their structure and chemical composition homogeneity, X-ray diffraction (XRD) and high-resolution inductively coupled plasma atomic emission spectrometry (ICP-AES) were conducted on the as-grown Ce:GGAG crystals at 4 different positions along the growth direction. Compared with the Ce:GGAG crystals grown by the OFZ method (Ce:GGAG-OFZ), the Ce:GGAG crystals grown by the TSFZ method (Ce:GGAG-TSFZ) presented better Ce3+ distribution homogeneity which varied from 0.21 to 0.29 at%. However, the segregation coefficient of Ce3+ in Ce:GGAG-OFZ was found to be higher than that in Ce:GGAG-TSFZ, revealing a different solidification rate between them. The comparison study shows that the photoluminescence (PL) intensity of Ce:GGAG-TSFZ is about twice higher than that of Ce:GGAG-OFZ and the maximum light yield (LY) of 35 340 photons per MeV also occurs in the former. Trap depths were measured to be 0.70 eV and 0.98 eV by TL glow curves. The LY value of Ce:GGAG-TSFZ along the growth direction fluctuated to a lesser extent with respect to that of Ce:GGAG-OFZ; the latter decreases gradually along the growth direction. It is concluded that the TSFZ method helps to improve the homogeneity of crystal composition when growing crystals with multiple compositions or incongruent compounds.
ISSN:1466-8033
DOI:10.1039/d3ce00144j