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Enhanced room temperature ferromagnetism in YMnO3-modified lead-free ferroelectric Bi0.5Na0.5TiO3 materials
The strongly enhanced room temperature ferromagnetism in Bi 0.5 Na 0.5 TiO 3 materials was obtained via modification of YMnO 3 as solid solutions. The weak ferromagnetism in pure Bi 0.5 Na 0.5 TiO 3 was changed to ferromagnetism and antiferromagnetic-like with increasing the concentration of YMnO 3...
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Published in: | Applied physics. A, Materials science & processing Materials science & processing, 2023-08, Vol.129 (8), Article 547 |
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Main Authors: | , , , , , |
Format: | Article |
Language: | English |
Subjects: | |
Citations: | Items that this one cites Items that cite this one |
Online Access: | Get full text |
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Summary: | The strongly enhanced room temperature ferromagnetism in Bi
0.5
Na
0.5
TiO
3
materials was obtained via modification of YMnO
3
as solid solutions. The weak ferromagnetism in pure Bi
0.5
Na
0.5
TiO
3
was changed to ferromagnetism and antiferromagnetic-like with increasing the concentration of YMnO
3
addition. The maxima magnetic moment was estimated at around 28.4 memu/g for 9 mol.% YMnO
3
-modified Bi
0.5
Na
0.5
TiO
3
as a solid solution. The reduction of the optical bandgap energy from 3.18 eV to 2.01 eV was obtained via increasing YMnO
3
addition into host Bi
0.5
Na
0.5
TiO
3
crystal as solid solutions with amounts up to 9 mol.%. We suggested that the observation in the reduction of optical bandgap energy and great enhancement of the magnetic moment in YMnO
3
-modified Bi
0.5
Na
0.5
TiO
3
compounds were strongly related to the random distribution of Y and Mn cations into the host lattice of Bi
0.5
Na
0.5
TiO
3
crystals. We expected that our work will provide a simple way to integrate room temperature ferromagnetism into currently developed green ferroelectric materials. |
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ISSN: | 0947-8396 1432-0630 |
DOI: | 10.1007/s00339-023-06820-w |