Molecular Complexes, Supramolecular Architectures and Metallo-polymers Based on Chiral Terpene-fused 2,2′:6′,2′′-Terpyridines

Chiral 2,2′:6′,2′′-terpyridines (tpys) are of particular importance in coordination chemistry and supramolecular self-assembly on account of their unique spatial configuration and outstanding coordination ability. Thanks to the advance of synthetic strategies based on the Kröhnke reaction, a number...

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Published in:Chemistry letters 2023-05, Vol.52 (5), p.370-380
Main Authors: He, Hongdi, Zhang, Shunran, Chen, Zhi, Wang, Heng, Yu, Xiujun, Li, Xiaopeng
Format: Article
Language:English
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Coordination
Metallography
Polymers
Self-assembly
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description Chiral 2,2′:6′,2′′-terpyridines (tpys) are of particular importance in coordination chemistry and supramolecular self-assembly on account of their unique spatial configuration and outstanding coordination ability. Thanks to the advance of synthetic strategies based on the Kröhnke reaction, a number of chiral terpene-fused tpys (cttpys) have been synthesized and have greatly promoted the construction of cttpy-based molecular complexes, supramolecular architectures and metallo-polymers. This review summarizes the progress of cttpy-based complexes and metallo-polymers in the past decades, aiming to shed more light on the design and construction of novel supramolecular architectures and metallo-polymers with high precision and multiple functions through coordination.
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subjects Coordination
Metallography
Polymers
Self-assembly
title Molecular Complexes, Supramolecular Architectures and Metallo-polymers Based on Chiral Terpene-fused 2,2′:6′,2′′-Terpyridines
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