Kinetics and Mechanism of the Oxidation of CO to CO2 in the PdBr2–CuBr2–THF–H2O Catalytic System

The kinetics of the oxidation of CO to CO 2 in the PdBr 2 –CuBr 2 –THF–H 2 O system outside the coupled process of cyclohexene hydrocarboxylation was studied. A kinetic model was constructed, and a reaction mechanism was proposed. It was found that the alkene hydrocarboxylation affects the oxidation...

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Bibliographic Details
Published in:Kinetics and catalysis 2023-08, Vol.64 (4), p.412-420
Main Authors: Putin, A. Yu, Katsman, E. A., Bruk, L. G.
Format: Article
Language:English
Subjects:
Carbon dioxide
Carbon monoxide
Catalysis
Chemistry
Chemistry and Materials Science
Copper bromide
Kinetics
Oxidation
Physical Chemistry
Reaction kinetics
Reaction mechanisms
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Summary:The kinetics of the oxidation of CO to CO 2 in the PdBr 2 –CuBr 2 –THF–H 2 O system outside the coupled process of cyclohexene hydrocarboxylation was studied. A kinetic model was constructed, and a reaction mechanism was proposed. It was found that the alkene hydrocarboxylation affects the oxidation of CO to CO 2 in the coupled process, which was investigated previously.
ISSN:0023-1584
1608-3210
DOI:10.1134/S0023158423040122