Local Atomic Environment of Zn2+ Ions in a Low-Concentration ZnCl2 Aqueous Solution: XANES Study

The diverse local environment of zinc ions in a ZnCl 2 solution, depending on the symmetry, ligand type, and solution concentration, has been analyzed using the data in the literature. Experimental zinc K -edge XANES spectra in a ZnCl 2 aqueous solution with a critically low concentration (10 –3 М)...

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Published in:Crystallography reports 2023-04, Vol.68 (2), p.242-246
Main Authors: Lysenko, V. Yu, Kremennaya, M. A., Yalovega, G. E.
Format: Article
Language:English
Subjects:
Aqueous solutions
Crystallography and Scattering Methods
Physics
Physics and Astronomy
Structure of Inorganic Compounds
Zinc chloride
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Yalovega, G. E.
description The diverse local environment of zinc ions in a ZnCl 2 solution, depending on the symmetry, ligand type, and solution concentration, has been analyzed using the data in the literature. Experimental zinc K -edge XANES spectra in a ZnCl 2 aqueous solution with a critically low concentration (10 –3 М) have been theoretically analyzed. It is shown that Zn(H 2 O) complexes with Zn 2+ ions in the octahedral coordination environment of water molecules are dominant in this solution.
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subjects Aqueous solutions
Crystallography and Scattering Methods
Physics
Physics and Astronomy
Structure of Inorganic Compounds
Zinc chloride
title Local Atomic Environment of Zn2+ Ions in a Low-Concentration ZnCl2 Aqueous Solution: XANES Study
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