Applications of phenyliodine(III) diacetate in heterocyclic ring formations: An update from 2015 to date

Diacetoxyiodobenzene (PhI(OAc)2), commonly referred to as DAIB or phenyliodine(III) diacetate (PIDA), is one of the most frequently used hypervalent iodines employed as an oxidizing agent in organic chemistry. In this review, PIDA is highlighted exclusively in relation to its applications in organic...

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Bibliographic Details
Published in:Journal of heterocyclic chemistry 2023-08, Vol.60 (8), p.1326-1355
Main Authors: Alam, Mohammed Mujahid, Hussien, Mohamed, Bollikolla, Hari Babu, Seema, Vittal, Dubasi, Narsimhaswamy, Amanullah, Mohammed, Varala, Ravi
Format: Article
Language:English
Subjects:
Organic chemistry
Oxidation
Oxidizing agents
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Summary:Diacetoxyiodobenzene (PhI(OAc)2), commonly referred to as DAIB or phenyliodine(III) diacetate (PIDA), is one of the most frequently used hypervalent iodines employed as an oxidizing agent in organic chemistry. In this review, PIDA is highlighted exclusively in relation to its applications in organic synthesis involving heterocyclic ring formations and is critically and in‐depth examined from the summer of 2015 to the present with a specific focus on the mechanistic pathway. In this review, authors have updated PIDA‐mediated synthesis of various biologically relevant heterocyclic rings with a specific focus on the mechanistic pathway.
ISSN:0022-152X
1943-5193
DOI:10.1002/jhet.4627