Structure, Hirshfeld Surface Analysis and Electrochemical Properties of Ni(II)-based Coordination Polymer with Mixed Ligand

In this work, a novel complex [Ni(HL)(dib)(H 2 O) 2 ] n ( 1 ) was synthesized by hydrothermal method using 2-(4-carboxyphenoxy)terephthalic acid (H 3 L) as the main ligand and 1,4-di(1 H-imidazole-1-yl)benzene (dib) as an auxiliary N-donor linker. 1 exhibits a 4-connected two-dimensional (2D) topolo...

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Bibliographic Details
Published in:Journal of inorganic and organometallic polymers and materials 2023-08, Vol.33 (8), p.2378-2385
Main Authors: Lei, Xin-You, Qin, Tianrui, Yang, Quan-Sheng, Li, Duqingcuo, Shi, Zhan, Si, Chang-Dai, Srivastava, Devyani, Muddassir, Mohd, Sakiyama, Hiroshi, Kumar, Abhinav
Format: Article
Language:English
Subjects:
Benzene
Chemistry
Chemistry and Materials Science
Coordination polymers
Electrochemical analysis
Fingerprinting
Hydrogen bonds
Imidazole
Inorganic Chemistry
Ligands
Organic Chemistry
Polymer Sciences
Surface analysis (chemical)
Terephthalic acid
Thermogravimetry
Topology
Two dimensional analysis
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Summary:In this work, a novel complex [Ni(HL)(dib)(H 2 O) 2 ] n ( 1 ) was synthesized by hydrothermal method using 2-(4-carboxyphenoxy)terephthalic acid (H 3 L) as the main ligand and 1,4-di(1 H-imidazole-1-yl)benzene (dib) as an auxiliary N-donor linker. 1 exhibits a 4-connected two-dimensional (2D) topology with the point symbol {4 4 .6 2 }, and the 2D structure was further assembled to form a three-dimensional (3D) framework by intermolecular C-O···H hydrogen bonds. Moreover, a series of characterizations such as elemental analysis, thermogravimetry, 2D fingerprinting and Hirshfeld surface analysis were carried out for 1 , and its electrochemical properties were studied.
ISSN:1574-1443
1574-1451
DOI:10.1007/s10904-023-02635-7