Enhanced efficiency in organic solar cells by incorporation of small molecule based on tosylate anion

A small molecule electrolyte (SME) based on tosylate anion (FN-NDI-OTs) was synthesized and applied as the cathode interlayer in organic solar cells (OSCs). This material generates a beneficial interface dipole at the cathode interface by the tosylate anion functionality, leading to the improvement...

Full description

Saved in:
Bibliographic Details
Published in:Molecular Crystals and Liquid Crystals 2023-07, Vol.760 (1), p.16-26
Main Authors: Nasrun, Rahmatia Fitri Binti, Son, Dong Hwan, Park, Sung Heum, Ko, Minseong, Kim, Joo Hyun
Format: Article
Language:English
Subjects:
Anions
Cathodes
Dipoles
Electrolytic cells
Energy conversion efficiency
Interlayer
Interlayers
inverted organic solar cells
Photovoltaic cells
small molecule electrolyte
Solar cells
tosylate anion
Zinc oxide
Citations: Items that this one cites
Items that cite this one
Online Access:Get full text
Tags: Add Tag
No Tags, Be the first to tag this record!
cited_by cdi_FETCH-LOGICAL-c338t-9588c06a14eb994134663c9077f94c3f7969351534848d73dad9224803d408f33
cites cdi_FETCH-LOGICAL-c338t-9588c06a14eb994134663c9077f94c3f7969351534848d73dad9224803d408f33
container_end_page 26
container_issue 1
container_start_page 16
container_title Molecular Crystals and Liquid Crystals
container_volume 760
creator Nasrun, Rahmatia Fitri Binti
Son, Dong Hwan
Park, Sung Heum
Ko, Minseong
Kim, Joo Hyun
description A small molecule electrolyte (SME) based on tosylate anion (FN-NDI-OTs) was synthesized and applied as the cathode interlayer in organic solar cells (OSCs). This material generates a beneficial interface dipole at the cathode interface by the tosylate anion functionality, leading to the improvement of power conversion efficiency (PCE). The device based on the blend of PTB7-Th:PC 71 BM as the active layer exhibits improved PCE, increasing from 8.79% based on pristine ZnO to 9.53% using the ZnO/SME as the interlayer, which mainly resulted from the enhancement. These results indicate the potential of SME with tosylate anion as an interlayer in OSCs.
doi_str_mv 10.1080/15421406.2022.2164654
format article
fullrecord <record><control><sourceid>proquest_infor</sourceid><recordid>TN_cdi_proquest_journals_2846837094</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>2846837094</sourcerecordid><originalsourceid>FETCH-LOGICAL-c338t-9588c06a14eb994134663c9077f94c3f7969351534848d73dad9224803d408f33</originalsourceid><addsrcrecordid>eNp9kE1LAzEURYMoWKs_QQi4nprvSXZKqR9QcKPrkGYSTclMajJF-u_N0Lp19R68c--DA8AtRguMJLrHnBHMkFgQRMiCYMEEZ2dghrmgDSeyPZ92RpoJugRXpWwRIqzFcgbcavgyg3UddN4HG9xgDzAMMOVPMwQLS4omQ-tiLHAzXWzKu5TNGFKFPCy9iRH2KTq7jw5uTKlV9TSmcohmdLC2pOEaXHgTi7s5zTn4eFq9L1-a9dvz6_Jx3VhK5dgoLqVFwmDmNkoxTJkQ1CrUtl4xS32rhKIcc8okk11LO9MpQphEtGNIekrn4O7Yu8vpe-_KqLdpn4f6UhPJhKQtUqxS_EjZnErJzutdDr3JB42RnozqP6N6MqpPRmvu4ZgLg0-5Nz8px06P5hBT9rlaDEXT_yt-AbM2e_Q</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>2846837094</pqid></control><display><type>article</type><title>Enhanced efficiency in organic solar cells by incorporation of small molecule based on tosylate anion</title><source>EBSCOhost MLA International Bibliography With Full Text</source><source>Taylor and Francis Science and Technology Collection</source><creator>Nasrun, Rahmatia Fitri Binti ; Son, Dong Hwan ; Park, Sung Heum ; Ko, Minseong ; Kim, Joo Hyun</creator><creatorcontrib>Nasrun, Rahmatia Fitri Binti ; Son, Dong Hwan ; Park, Sung Heum ; Ko, Minseong ; Kim, Joo Hyun</creatorcontrib><description>A small molecule electrolyte (SME) based on tosylate anion (FN-NDI-OTs) was synthesized and applied as the cathode interlayer in organic solar cells (OSCs). This material generates a beneficial interface dipole at the cathode interface by the tosylate anion functionality, leading to the improvement of power conversion efficiency (PCE). The device based on the blend of PTB7-Th:PC 71 BM as the active layer exhibits improved PCE, increasing from 8.79% based on pristine ZnO to 9.53% using the ZnO/SME as the interlayer, which mainly resulted from the enhancement. These results indicate the potential of SME with tosylate anion as an interlayer in OSCs.</description><identifier>ISSN: 1542-1406</identifier><identifier>EISSN: 1563-5287</identifier><identifier>EISSN: 1527-1943</identifier><identifier>DOI: 10.1080/15421406.2022.2164654</identifier><language>eng</language><publisher>Philadelphia: Taylor &amp; Francis</publisher><subject>Anions ; Cathodes ; Dipoles ; Electrolytic cells ; Energy conversion efficiency ; Interlayer ; Interlayers ; inverted organic solar cells ; Photovoltaic cells ; small molecule electrolyte ; Solar cells ; tosylate anion ; Zinc oxide</subject><ispartof>Molecular Crystals and Liquid Crystals, 2023-07, Vol.760 (1), p.16-26</ispartof><rights>2023 Taylor &amp; Francis Group, LLC 2023</rights><rights>2023 Taylor &amp; Francis Group, LLC</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c338t-9588c06a14eb994134663c9077f94c3f7969351534848d73dad9224803d408f33</citedby><cites>FETCH-LOGICAL-c338t-9588c06a14eb994134663c9077f94c3f7969351534848d73dad9224803d408f33</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,780,784,27924,27925</link.rule.ids></links><search><creatorcontrib>Nasrun, Rahmatia Fitri Binti</creatorcontrib><creatorcontrib>Son, Dong Hwan</creatorcontrib><creatorcontrib>Park, Sung Heum</creatorcontrib><creatorcontrib>Ko, Minseong</creatorcontrib><creatorcontrib>Kim, Joo Hyun</creatorcontrib><title>Enhanced efficiency in organic solar cells by incorporation of small molecule based on tosylate anion</title><title>Molecular Crystals and Liquid Crystals</title><description>A small molecule electrolyte (SME) based on tosylate anion (FN-NDI-OTs) was synthesized and applied as the cathode interlayer in organic solar cells (OSCs). This material generates a beneficial interface dipole at the cathode interface by the tosylate anion functionality, leading to the improvement of power conversion efficiency (PCE). The device based on the blend of PTB7-Th:PC 71 BM as the active layer exhibits improved PCE, increasing from 8.79% based on pristine ZnO to 9.53% using the ZnO/SME as the interlayer, which mainly resulted from the enhancement. These results indicate the potential of SME with tosylate anion as an interlayer in OSCs.</description><subject>Anions</subject><subject>Cathodes</subject><subject>Dipoles</subject><subject>Electrolytic cells</subject><subject>Energy conversion efficiency</subject><subject>Interlayer</subject><subject>Interlayers</subject><subject>inverted organic solar cells</subject><subject>Photovoltaic cells</subject><subject>small molecule electrolyte</subject><subject>Solar cells</subject><subject>tosylate anion</subject><subject>Zinc oxide</subject><issn>1542-1406</issn><issn>1563-5287</issn><issn>1527-1943</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2023</creationdate><recordtype>article</recordtype><recordid>eNp9kE1LAzEURYMoWKs_QQi4nprvSXZKqR9QcKPrkGYSTclMajJF-u_N0Lp19R68c--DA8AtRguMJLrHnBHMkFgQRMiCYMEEZ2dghrmgDSeyPZ92RpoJugRXpWwRIqzFcgbcavgyg3UddN4HG9xgDzAMMOVPMwQLS4omQ-tiLHAzXWzKu5TNGFKFPCy9iRH2KTq7jw5uTKlV9TSmcohmdLC2pOEaXHgTi7s5zTn4eFq9L1-a9dvz6_Jx3VhK5dgoLqVFwmDmNkoxTJkQ1CrUtl4xS32rhKIcc8okk11LO9MpQphEtGNIekrn4O7Yu8vpe-_KqLdpn4f6UhPJhKQtUqxS_EjZnErJzutdDr3JB42RnozqP6N6MqpPRmvu4ZgLg0-5Nz8px06P5hBT9rlaDEXT_yt-AbM2e_Q</recordid><startdate>20230724</startdate><enddate>20230724</enddate><creator>Nasrun, Rahmatia Fitri Binti</creator><creator>Son, Dong Hwan</creator><creator>Park, Sung Heum</creator><creator>Ko, Minseong</creator><creator>Kim, Joo Hyun</creator><general>Taylor &amp; Francis</general><general>Taylor &amp; Francis Ltd</general><scope>AAYXX</scope><scope>CITATION</scope><scope>7SP</scope><scope>7U5</scope><scope>8FD</scope><scope>L7M</scope></search><sort><creationdate>20230724</creationdate><title>Enhanced efficiency in organic solar cells by incorporation of small molecule based on tosylate anion</title><author>Nasrun, Rahmatia Fitri Binti ; Son, Dong Hwan ; Park, Sung Heum ; Ko, Minseong ; Kim, Joo Hyun</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c338t-9588c06a14eb994134663c9077f94c3f7969351534848d73dad9224803d408f33</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2023</creationdate><topic>Anions</topic><topic>Cathodes</topic><topic>Dipoles</topic><topic>Electrolytic cells</topic><topic>Energy conversion efficiency</topic><topic>Interlayer</topic><topic>Interlayers</topic><topic>inverted organic solar cells</topic><topic>Photovoltaic cells</topic><topic>small molecule electrolyte</topic><topic>Solar cells</topic><topic>tosylate anion</topic><topic>Zinc oxide</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Nasrun, Rahmatia Fitri Binti</creatorcontrib><creatorcontrib>Son, Dong Hwan</creatorcontrib><creatorcontrib>Park, Sung Heum</creatorcontrib><creatorcontrib>Ko, Minseong</creatorcontrib><creatorcontrib>Kim, Joo Hyun</creatorcontrib><collection>CrossRef</collection><collection>Electronics &amp; Communications Abstracts</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>Technology Research Database</collection><collection>Advanced Technologies Database with Aerospace</collection><jtitle>Molecular Crystals and Liquid Crystals</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Nasrun, Rahmatia Fitri Binti</au><au>Son, Dong Hwan</au><au>Park, Sung Heum</au><au>Ko, Minseong</au><au>Kim, Joo Hyun</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Enhanced efficiency in organic solar cells by incorporation of small molecule based on tosylate anion</atitle><jtitle>Molecular Crystals and Liquid Crystals</jtitle><date>2023-07-24</date><risdate>2023</risdate><volume>760</volume><issue>1</issue><spage>16</spage><epage>26</epage><pages>16-26</pages><issn>1542-1406</issn><eissn>1563-5287</eissn><eissn>1527-1943</eissn><abstract>A small molecule electrolyte (SME) based on tosylate anion (FN-NDI-OTs) was synthesized and applied as the cathode interlayer in organic solar cells (OSCs). This material generates a beneficial interface dipole at the cathode interface by the tosylate anion functionality, leading to the improvement of power conversion efficiency (PCE). The device based on the blend of PTB7-Th:PC 71 BM as the active layer exhibits improved PCE, increasing from 8.79% based on pristine ZnO to 9.53% using the ZnO/SME as the interlayer, which mainly resulted from the enhancement. These results indicate the potential of SME with tosylate anion as an interlayer in OSCs.</abstract><cop>Philadelphia</cop><pub>Taylor &amp; Francis</pub><doi>10.1080/15421406.2022.2164654</doi><tpages>11</tpages></addata></record>
fulltext fulltext
identifier ISSN: 1542-1406
ispartof Molecular Crystals and Liquid Crystals, 2023-07, Vol.760 (1), p.16-26
issn 1542-1406
1563-5287
1527-1943
language eng
recordid cdi_proquest_journals_2846837094
source EBSCOhost MLA International Bibliography With Full Text; Taylor and Francis Science and Technology Collection
subjects Anions
Cathodes
Dipoles
Electrolytic cells
Energy conversion efficiency
Interlayer
Interlayers
inverted organic solar cells
Photovoltaic cells
small molecule electrolyte
Solar cells
tosylate anion
Zinc oxide
title Enhanced efficiency in organic solar cells by incorporation of small molecule based on tosylate anion
url http://sfxeu10.hosted.exlibrisgroup.com/loughborough?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-01-07T15%3A17%3A16IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest_infor&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Enhanced%20efficiency%20in%20organic%20solar%20cells%20by%20incorporation%20of%20small%20molecule%20based%20on%20tosylate%20anion&rft.jtitle=Molecular%20Crystals%20and%20Liquid%20Crystals&rft.au=Nasrun,%20Rahmatia%20Fitri%20Binti&rft.date=2023-07-24&rft.volume=760&rft.issue=1&rft.spage=16&rft.epage=26&rft.pages=16-26&rft.issn=1542-1406&rft.eissn=1563-5287&rft_id=info:doi/10.1080/15421406.2022.2164654&rft_dat=%3Cproquest_infor%3E2846837094%3C/proquest_infor%3E%3Cgrp_id%3Ecdi_FETCH-LOGICAL-c338t-9588c06a14eb994134663c9077f94c3f7969351534848d73dad9224803d408f33%3C/grp_id%3E%3Coa%3E%3C/oa%3E%3Curl%3E%3C/url%3E&rft_id=info:oai/&rft_pqid=2846837094&rft_id=info:pmid/&rfr_iscdi=true