Tailoring the performance of poly(lactic acid)‐based reactive blends: The effect of vinyl acetate and dicumyl peroxide content

• Published in: Journal of applied polymer science 2023-09, Vol.140 (35), p.n/a
• Main Authors: Ferreira, Eduardo da Silva Barbosa, Nascimento, Emanuel Pereira, Luna, Carlos Bruno Barreto, Santos Filho, Edson Antonio, Wellen, Renate Maria Ramos, Araújo, Edcleide Maria
• Format: Article
• Language: English
• Subjects: Biodegradable materials; Biopolymers; Compatibilizers; Crosslinking; Dicumyl peroxide; Elongation; Ethylene vinyl acetates; Fragility; Impact strength; Materials science; poly(lactic acid); Polylactic acid; Polymer blends; Polymers; super toughness; Vinyl acetate; vulcanized thermoplastics
• ISSN: 0021-8995; 1097-4628
• DOI: 10.1002/app.54353

Poly(lactic acid) has been gaining prominence in academia and industry, mainly due to being a biopolymer and biodegradable material. Nevertheless, mainly due to its high fragility, work has been carried out in order to seek alternatives to improve this drawback. Hence, this work aims to evaluate the effect of the vinyl acetate content using two types of EVA (EVA1 with 28% and EVA2 with 19%) in dynamically vulcanized PLA/EVA blends, using several dicumyl peroxide (DCP) contents, that is, 0.3, 0.5, and 0.7 phr. Blends were produced using an internal mixer, and the tensile, impact and HDT specimens were injection molded. By FTIR and torque rheometry, it was verified that, upon DCP addition, there was evidences of reticulation, resulting in crosslinked PLA, crosslinked EVA, as well as PLA‐g‐EVA. Through tensile and impact strength tests, it was observed substantial increases in the elongation at break, and in impact strength, mainly for the compounds with higher content of vinyl acetate (EVA1). Impact specimens made with PLA/EVA120 0.7 DCP, PLA/EVA130 0.5 DCP, and 0.7 DCP, did not completely break, due to the probable development of the in situ PLA‐g‐EVA compatibilizer among the present phases. Therefore, it is believed that a more homogeneous microstructure was obtained, as observed by SEM images, highlighted upon the DCP content increase. It was verified that the highest vinyl acetate content is of paramount importance for obtaining PLA/EVA blends with better compatibility as well as EVA1 being more susceptible to crosslinking using DCP, resulting in blends with greater toughness. Production of super‐toughened poly (lactic acid)‐based blends.