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Recent advances in kinetic and thermodynamic regulation of magnesium hydride for hydrogen storage
Developing safer and more efficient hydrogen storage technology is a pivotal step to realizing the hydrogen economy. Owing to the lightweight, high hydrogen storage density and abundant reserves, MgH 2 has been widely studied as one of the most promising solid-state hydrogen storage materials. Howev...
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Published in: | Rare metals 2023-09, Vol.42 (9), p.2906-2927 |
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Main Authors: | , , , , , , , , , , |
Format: | Article |
Language: | English |
Subjects: | |
Citations: | Items that this one cites Items that cite this one |
Online Access: | Get full text |
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Summary: | Developing safer and more efficient hydrogen storage technology is a pivotal step to realizing the hydrogen economy. Owing to the lightweight, high hydrogen storage density and abundant reserves, MgH
2
has been widely studied as one of the most promising solid-state hydrogen storage materials. However, defects such as stable thermodynamics, sluggish kinetics and rapid capacity decay have seriously hindered its practical application. This article reviews recent advances in catalyst doping and nanostructures for improved kinetic performance of MgH
2
/Mg systems for hydrogen release/absorption, the tuning of their thermodynamic stability properties by alloying and reactant destabilization, and the dual thermodynamic and kinetic optimization of the MgH
2
/Mg system achieved by nanoconfinement with in situ catalysis and ball milling with in situ aerosol spraying, aiming to open new perspectives for the scale-up of MgH
2
for hydrogen storage applications.
Graphic Abstract |
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ISSN: | 1001-0521 1867-7185 |
DOI: | 10.1007/s12598-023-02306-z |