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Ionic liquid treated cellulose-based intelligent pH-responsive color indicator film, with excellent anti-ultraviolet function
Three instant pH-responsive intelligent chromogenic indicator films were fabricated by ionic liquid regenerated cellulose and introduction of shikonin with solution-casting method. The sensitive color change of the indicator film from reddish purple to light bluish purple could be observed in three...
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Published in: | Journal of polymer research 2023-09, Vol.30 (9), Article 343 |
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creator | An, Nan Hu, Jingwan Ding, Yun Sheng, Pinghou Zhang, Zhicheng Guo, Xiangrui |
description | Three instant pH-responsive intelligent chromogenic indicator films were fabricated by ionic liquid regenerated cellulose and introduction of shikonin with solution-casting method. The sensitive color change of the indicator film from reddish purple to light bluish purple could be observed in three cellulose-based films as the pH increased. Furthermore, the stimuli-responsive color change of hemp/shikonin film is more pronounced in the narrow region from pH 5.5 to 8.5. During real-time monitoring of shrimp freshness, the utilization of hemp/shikonin indicator film revealed a highly responsive alteration in discoloration from shrimp fresh (pH = 6.7) to spoiled (pH = 7.2), without noticeable change on the appearance of the shrimp visually. Besides, the shikonin-added indicator film exhibited notable UV-light barrier property and free radical scavenging activity, as well as greater thermal stability and mechanical strength. Due to its versatility and pH stimuli-responsive color changing, this novel indicator film has great application potential in smart food packaging. |
doi_str_mv | 10.1007/s10965-023-03716-4 |
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The sensitive color change of the indicator film from reddish purple to light bluish purple could be observed in three cellulose-based films as the pH increased. Furthermore, the stimuli-responsive color change of hemp/shikonin film is more pronounced in the narrow region from pH 5.5 to 8.5. During real-time monitoring of shrimp freshness, the utilization of hemp/shikonin indicator film revealed a highly responsive alteration in discoloration from shrimp fresh (pH = 6.7) to spoiled (pH = 7.2), without noticeable change on the appearance of the shrimp visually. Besides, the shikonin-added indicator film exhibited notable UV-light barrier property and free radical scavenging activity, as well as greater thermal stability and mechanical strength. 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The sensitive color change of the indicator film from reddish purple to light bluish purple could be observed in three cellulose-based films as the pH increased. Furthermore, the stimuli-responsive color change of hemp/shikonin film is more pronounced in the narrow region from pH 5.5 to 8.5. During real-time monitoring of shrimp freshness, the utilization of hemp/shikonin indicator film revealed a highly responsive alteration in discoloration from shrimp fresh (pH = 6.7) to spoiled (pH = 7.2), without noticeable change on the appearance of the shrimp visually. Besides, the shikonin-added indicator film exhibited notable UV-light barrier property and free radical scavenging activity, as well as greater thermal stability and mechanical strength. Due to its versatility and pH stimuli-responsive color changing, this novel indicator film has great application potential in smart food packaging.</description><subject>Cellulose</subject><subject>Characterization and Evaluation of Materials</subject><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Color</subject><subject>Discoloration</subject><subject>Food packaging</subject><subject>Founding</subject><subject>Free radicals</subject><subject>Freshness</subject><subject>Hemp</subject><subject>Hydrogen-ion concentration</subject><subject>Industrial Chemistry/Chemical Engineering</subject><subject>Ionic liquids</subject><subject>Original Paper</subject><subject>Polymer Sciences</subject><subject>Scavenging</subject><subject>Shrimps</subject><subject>Stimuli</subject><subject>Thermal stability</subject><subject>Ultraviolet radiation</subject><issn>1022-9760</issn><issn>1572-8935</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2023</creationdate><recordtype>article</recordtype><recordid>eNp9kclOBCEQhjtGE9cX8NSJV1GapWGOxrglJl70TGi6GDEMjEC7HHx3GdvEm-FAVfF_RcHfNMcdPuswFue5w4ueI0wowlR0PWJbzV7HBUFyQfl2jTEhaCF6vNvs5_yCMeeil3vN110MzrTevU5ubEsCXWBsDXg_-ZgBDTrX3IVSK24JobTrW5Qgr2PI7g1aE31M9Xx0RpcaWedXp-27K88tfGzabBAdikOTL0m_ueihtHYKprgYDpsdq32Go9_9oHm6vnq8vEX3Dzd3lxf3yFAuC7IS9DjIhSBg5aAF08ZAZ3sje8ZHYg02jFHMBCEAQHpDCa9VobtxZMPQ04PmZO67TvF1glzUS5xSqFcqIplklBOBq-psVi21B-WCjXViU9cIK2digPo4UBf1E4kUkpMKkBkwKeacwKp1ciudPlWH1cYXNfuiqi_qxxfFKkRnKFdxWEL6m-Uf6hsvOZP9</recordid><startdate>20230901</startdate><enddate>20230901</enddate><creator>An, Nan</creator><creator>Hu, Jingwan</creator><creator>Ding, Yun</creator><creator>Sheng, Pinghou</creator><creator>Zhang, Zhicheng</creator><creator>Guo, Xiangrui</creator><general>Springer Netherlands</general><general>Springer</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>8FD</scope><scope>JG9</scope><orcidid>https://orcid.org/0000-0001-8685-5349</orcidid></search><sort><creationdate>20230901</creationdate><title>Ionic liquid treated cellulose-based intelligent pH-responsive color indicator film, with excellent anti-ultraviolet function</title><author>An, Nan ; Hu, Jingwan ; Ding, Yun ; Sheng, Pinghou ; Zhang, Zhicheng ; Guo, Xiangrui</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c358t-f8eadb8972ef8ba74acce1f6c8645d2fc0c44304722eee26c3252fc7a1dd4bb63</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2023</creationdate><topic>Cellulose</topic><topic>Characterization and Evaluation of Materials</topic><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>Color</topic><topic>Discoloration</topic><topic>Food packaging</topic><topic>Founding</topic><topic>Free radicals</topic><topic>Freshness</topic><topic>Hemp</topic><topic>Hydrogen-ion concentration</topic><topic>Industrial Chemistry/Chemical Engineering</topic><topic>Ionic liquids</topic><topic>Original Paper</topic><topic>Polymer Sciences</topic><topic>Scavenging</topic><topic>Shrimps</topic><topic>Stimuli</topic><topic>Thermal stability</topic><topic>Ultraviolet radiation</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>An, Nan</creatorcontrib><creatorcontrib>Hu, Jingwan</creatorcontrib><creatorcontrib>Ding, Yun</creatorcontrib><creatorcontrib>Sheng, Pinghou</creatorcontrib><creatorcontrib>Zhang, Zhicheng</creatorcontrib><creatorcontrib>Guo, Xiangrui</creatorcontrib><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><jtitle>Journal of polymer research</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>An, Nan</au><au>Hu, Jingwan</au><au>Ding, Yun</au><au>Sheng, Pinghou</au><au>Zhang, Zhicheng</au><au>Guo, Xiangrui</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Ionic liquid treated cellulose-based intelligent pH-responsive color indicator film, with excellent anti-ultraviolet function</atitle><jtitle>Journal of polymer research</jtitle><stitle>J Polym Res</stitle><date>2023-09-01</date><risdate>2023</risdate><volume>30</volume><issue>9</issue><artnum>343</artnum><issn>1022-9760</issn><eissn>1572-8935</eissn><abstract>Three instant pH-responsive intelligent chromogenic indicator films were fabricated by ionic liquid regenerated cellulose and introduction of shikonin with solution-casting method. The sensitive color change of the indicator film from reddish purple to light bluish purple could be observed in three cellulose-based films as the pH increased. Furthermore, the stimuli-responsive color change of hemp/shikonin film is more pronounced in the narrow region from pH 5.5 to 8.5. During real-time monitoring of shrimp freshness, the utilization of hemp/shikonin indicator film revealed a highly responsive alteration in discoloration from shrimp fresh (pH = 6.7) to spoiled (pH = 7.2), without noticeable change on the appearance of the shrimp visually. Besides, the shikonin-added indicator film exhibited notable UV-light barrier property and free radical scavenging activity, as well as greater thermal stability and mechanical strength. Due to its versatility and pH stimuli-responsive color changing, this novel indicator film has great application potential in smart food packaging.</abstract><cop>Dordrecht</cop><pub>Springer Netherlands</pub><doi>10.1007/s10965-023-03716-4</doi><orcidid>https://orcid.org/0000-0001-8685-5349</orcidid></addata></record> |
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subjects | Cellulose Characterization and Evaluation of Materials Chemistry Chemistry and Materials Science Color Discoloration Food packaging Founding Free radicals Freshness Hemp Hydrogen-ion concentration Industrial Chemistry/Chemical Engineering Ionic liquids Original Paper Polymer Sciences Scavenging Shrimps Stimuli Thermal stability Ultraviolet radiation |
title | Ionic liquid treated cellulose-based intelligent pH-responsive color indicator film, with excellent anti-ultraviolet function |
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