Role of surface morphological parameters on wettability of obliquely deposited Cu thin films in a plasma focus device

• Published in: Journal of materials research 2023-08, Vol.38 (15), p.3666-3676
• Main Authors: Foadi, Farnaz, Etminan, Mahsa, Aghamir, Farzin M., Mohammadizadeh, Mohammad R.
• Format: Article
• Language: English
• Subjects: Angular position; Applied and Technical Physics; Biomaterials; Chemical properties; Chemistry and Materials Science; Contact angle; Copper; Copper oxides; Focus devices; Fourier transforms; Fractal geometry; Fractals; Inorganic Chemistry; Materials Engineering; Materials research; Materials Science; Morphology; Nanotechnology; Parameters; Plasma focus; Thin films; Wettability
• ISSN: 0884-2914; 2044-5326
• DOI: 10.1557/s43578-023-01090-x

Correlation between surface statistical parameters obtained by atomic force microscopy (AFM) analysis such as root-mean-square roughness, correlation length, fractal dimension, as well as surface chemistry and wetting behavior of obliquely deposited copper thin films is investigated. Six samples were positioned at different angular locations with respect to anode axis during deposition process in a plasma focus device. Grazing incidence x-ray diffraction (GIXRD) analysis of the samples shows formation of cubic copper crystalline structure and Fourier transform infrared spectroscopy (FTIR) studies depicts presence of copper oxide. The morphological characterization reveals that the wettability of films obeys the Wenzel regime and the surface fractal dimension plays a key role in determination of the contact angle of surfaces. There is a similar behavioral trend for fractal dimension and water contact angle in the investigated samples. Findings of this study reflect the role of irregularity at short length scales in surface wettability. Graphical Abstract In order to investigate the effects of surface morphology on wettability properties of Cu on glass thin films, different samples were produced by Plasma Focus device. Samples positioned at different angular positions with respect to the anode axis in the PF device, showed different morphological characteristics. Although, surface chemical properties of the samples don’t differ according to surface composition analyses, surface morphology plays a dominant role in wettability determination.