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Fabrication of Ag nanoparticles decorated on the NiAl-oxide@PPy for non-enzymatic H2O2 sensing

The NiAlO@PPy-Ag sensing material was designed and prepared via in-situ oxidative polymerization of pyrrole monomer on the NiAl-oxide (NiAlO), and then anchoring Ag nanoparticles (NPs) on the surface of the NiAlO@PPy carrier. It was determined that the NiAlO particles were encased by PPy chains and...

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Published in:Ionics 2023-09, Vol.29 (9), p.3759-3767
Main Authors: Yan, Wei, Zeng, Hong-Yan, Zhang, Kai, Zou, Kai-Min
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container_title Ionics
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creator Yan, Wei
Zeng, Hong-Yan
Zhang, Kai
Zou, Kai-Min
description The NiAlO@PPy-Ag sensing material was designed and prepared via in-situ oxidative polymerization of pyrrole monomer on the NiAl-oxide (NiAlO), and then anchoring Ag nanoparticles (NPs) on the surface of the NiAlO@PPy carrier. It was determined that the NiAlO particles were encased by PPy chains and Ag NPs were homogeneously distributed on the NiAlO@PPy based on various structural characterization. Subsequently, the NiAlO@PPy-Ag was directly fabricated into a non-enzymatic sensor for the detection of H 2 O 2 , which sensor showed a high sensitivity and selectivity toward H 2 O 2 with a low detection limit of 0.03 μmol∙L −1 and high sensitivity of 346.50 μA∙mmol −1 ∙cm −2 , and excellent repeatability and reproducibility. The results demonstrated that the NiAlO@PPy-Ag was a promising electrocatalytic material for H 2 O 2 detection in the biological, clinical and environmental fields. Graphical abstract
doi_str_mv 10.1007/s11581-023-05138-0
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subjects Chemistry
Chemistry and Materials Science
Condensed Matter Physics
Electrochemistry
Energy Storage
Hydrogen peroxide
Intermetallic compounds
Nanoparticles
Nickel aluminides
Nickel base alloys
Nickel compounds
Optical and Electronic Materials
Original Paper
Renewable and Green Energy
Reproducibility
Sensitivity
Structural analysis
title Fabrication of Ag nanoparticles decorated on the NiAl-oxide@PPy for non-enzymatic H2O2 sensing
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