Rücktitelbild: A Photosensitizing Metal–Organic Framework as a Tandem Reaction Catalyst for Primary Alcohols from Terminal Alkenes and Alkynes (Angew. Chem. 35/2023)

A photosensitizing covalent metal–organic framework (CMOF) was prepared as a tandem reaction catalyst by Guo‐Hong Ning, Dan Li, and co‐workers in their Research Article (e202306497). By combining Cu‐CTUs as metal‐catalytic sites and Bodipy linkers as photosensitizers, this CMOF can catalyze terminal...

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Bibliographic Details
Published in:Angewandte Chemie 2023-08, Vol.135 (35), p.n/a
Main Authors: Lin, Xiao‐Chun, Wang, Yu‐Mei, Chen, Xu, You, Pei‐Ye, Mo, Kai‐Ming, Ning, Guo‐Hong, Li, Dan
Format: Article
Language:English
Subjects:
Active sites
Alcohols
Alkenes
Alkynes
Anti-Markovnikov Selectivity
Cascade chemical reactions
Catalysts
Chemistry
Copper
Covalent Metal–Organic Frameworks
Metal-organic frameworks
Photosensitization
Primary Alcohols
Regioselectivity
Substrates
Tandem Reaction
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Summary:A photosensitizing covalent metal–organic framework (CMOF) was prepared as a tandem reaction catalyst by Guo‐Hong Ning, Dan Li, and co‐workers in their Research Article (e202306497). By combining Cu‐CTUs as metal‐catalytic sites and Bodipy linkers as photosensitizers, this CMOF can catalyze terminal alkenes and alkynes to produce primary alcohols via one‐pot tandem reactions with excellent regioselectivity, good overall yields for two‐step reactions, broad substrate compatibility and good reusability under mild conditions.
ISSN:0044-8249
1521-3757
DOI:10.1002/ange.202309195