Metal-free and atom-efficient protocol for diarylation of selenocyanate by diaryliodonium salts

We developed an atom- and reaction mass efficient strategy for the preparation of diarylselenides using iodonium salts as reactants. The developed approach allows the obtaining of diarylselenides from the corresponding trimethoxyphenyl-substituted iodonium salts via a two-step one-pot reaction seque...

Full description

Saved in:
Bibliographic Details
Published in:Organic & biomolecular chemistry 2023-08, Vol.21 (33), p.6743-6749
Main Authors: Radzhabov, Amirbek D, Soldatova, Natalia S, Ivanov, Daniil M, Yusubov, Mekhman S, Kukushkin, Vadim Yu, Postnikov, Pavel S
Format: Article
Language:English
Subjects:
Salts
Citations: Items that this one cites
Items that cite this one
Online Access:Get full text
Tags: Add Tag
No Tags, Be the first to tag this record!
Description
Summary:We developed an atom- and reaction mass efficient strategy for the preparation of diarylselenides using iodonium salts as reactants. The developed approach allows the obtaining of diarylselenides from the corresponding trimethoxyphenyl-substituted iodonium salts via a two-step one-pot reaction sequence. The proposed metal-free methodology is based on the involvement of both iodonium aryl groups for diarylation. A metal-free and atom-efficient protocol for diarylation of selenocyanate by diaryliodonium salts has been developed.
ISSN:1477-0520
1477-0539
DOI:10.1039/d3ob00833a