Cover Feature: K3

The Cover Feature shows a 3D view of the single‐crystal structure of K3[MO4][MO3N] with M=Tc, Re together with the Raman spectrum of K3[ReO4][ReO3N]. Both compounds were synthesized using a highly alkaline KOH hydroflux. Since single‐crystal X‐ray diffraction does not prove the presence of nitrogen...

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Bibliographic Details
Published in:European journal of inorganic chemistry 2023-09, Vol.26 (26)
Main Authors: Badea, Désirée, Olthof, Selina, Neudörfl, Jörg M, Glaum, Robert, Pöttgen, Rainer, Reimann, Maximilian Kai, Meerholz, Klaus, Reimer, Max, Logemann, Christian, Strub, Erik, Bruns, Jörn
Format: Article
Language:English
Subjects:
Crystal structure
Diamagnetism
Infrared spectroscopy
Inorganic chemistry
Rhenium
Tetrahedra
X ray photoelectron spectroscopy
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Summary:The Cover Feature shows a 3D view of the single‐crystal structure of K3[MO4][MO3N] with M=Tc, Re together with the Raman spectrum of K3[ReO4][ReO3N]. Both compounds were synthesized using a highly alkaline KOH hydroflux. Since single‐crystal X‐ray diffraction does not prove the presence of nitrogen within the (MO4)‐tetrahedra unambiguously, Raman and IR spectroscopy as well as XPS and elemental analysis were conducted. Furthermore, magnetochemical measurements provide evidence for the diamagnetic behavior of the closed‐shell heptavalent rhenium species and UV‐Vis spectroscopy underpins the absence of mixed valences. The cover was designed by Dr. David van Gerven and Désirée Badea. More information can be found in the Research Article by J. Bruns and co‐workers.
ISSN:1434-1948
1099-0682
DOI:10.1002/ejic.202300481