Rücktitelbild: Ligand‐Free Ultrasmall Recyclable Iridium(0) Nanoparticles for Regioselective Aromatic Hydrogenation of Phosphine Oxide Scaffolds: An Easy Access to New Phosphine Ligands (Angew. Chem. 39/2023)

Heterogeneous and recyclable ligand‐free nanoparticles of iridium(0) enabled highly selective hydrogenation of distal unsubstituted aromatic rings to generate novel phosphine ligands. The iridium‐hydride species and hydrogen bonding between the substrate and solvent facilitate the catalysis, as repo...

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Bibliographic Details
Published in:Angewandte Chemie 2023-09, Vol.135 (39), p.n/a
Main Authors: Hedouin, Gaspard, Sharma, Sudripet, Kaur, Karanjeet, Choudhary, Ramesh Hiralal, Jasinski, Jacek B., Gallou, Fabrice, Handa, Sachin
Format: Article
Language:English
Subjects:
Aromatic compounds
Catalysis
Chemistry
Hydrogen bonding
Hydrogenation
Iridium
Ligands
Nanoparticles
Phosphine
Phosphine oxide
Phosphine Oxides
Substrates
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Summary:Heterogeneous and recyclable ligand‐free nanoparticles of iridium(0) enabled highly selective hydrogenation of distal unsubstituted aromatic rings to generate novel phosphine ligands. The iridium‐hydride species and hydrogen bonding between the substrate and solvent facilitate the catalysis, as reported by Fabrice Gallou, Sachin Handa et al. in their Research Article (e202307139).
ISSN:0044-8249
1521-3757
DOI:10.1002/ange.202312348