Preparation and Characterization of Ag2O Thin Films on Construction Textiles for Optoelectronics Applications: Effect of Aging on Its Optical and Structural Properties

• Published in: Coatings (Basel) 2023-09, Vol.13 (9), p.1613
• Main Authors: Krylova, Valentina, Dobilaitė, Vaida, Jucienė, Milda
• Format: Article
• Language: English
• Subjects: Adsorption; Aging; Aging (artificial); Alternative energy sources; Architecture; Carbon; Chemical synthesis; Composite materials; Decomposition; Heat; High temperature; Investigations; Mechanical properties; Metal oxides; Methods; Mineralization; Nanoparticles; Optical properties; Optoelectronics; Oxide coatings; Photocatalysis; Photovoltaic cells; Physical properties; Protective coatings; Refractivity; Silver; Silver oxides; Solar energy; Tear strength; Temperature; Tensile strength; Textiles; Thermal energy; Thin films; Ultraviolet reflection; Ultraviolet spectra
• ISSN: 2079-6412; 2079-6412
• DOI: 10.3390/coatings13091613

The aim of the research was to modify the surface of construction textiles by means of the use of thin silver oxide films, investigate the structure and optical and mechanical properties, and determine the structure, optical and mechanical properties of the aged composites. Thin films of silver oxide (Ag2O) were synthesized on a flexible PET/PVC construction textile (CT); the structural, optical, and physical properties, as well as the effect of artificial aging on these properties, were investigated. The SILAR method (successive ionic layer adsorption and reaction) was used to synthesize thin Ag2O films on the CT surface. Before the thin films were deposited, the CT surface was mechanically roughened and pretreated with acidic and alkaline solutions at an elevated temperature. XRD analysis showed that the deposited films were a polycrystalline mixed phase material consisting of Ag2O, AgO, and metallic Ag. Diffuse reflectance spectra in the ultraviolet and visible ranges (UV-Vis) were used to study the optical properties of the deposited thin films. The synthesized Ag2O/CT composites were direct-gap semiconductors (the optical band gap (Eg) was 0.89 ± 0.02 eV). Eg and refractive indices (n) increased as the aging tests were carried out. Higher Eg and n meant that the composites were a good material for optoelectronic applications. The results showed that, after modification, the structural properties and tear strength of the PET/PVC fabric remained the same while the tensile strength decreased. The same tendencies remained after artificial aging.