Study on the Effects and Mechanism of Temperature and AO Flux Density in the AO Interaction with Upilex-S Using the ReaxFF Method

Atomic oxygen (AO), which is one of the most predominant and conspicuous space environmental factors in the low earth orbit, leads to severe deterioration of polymeric materials in spacecraft. The AO flux density and ambient temperature vary while a craft orbits in space; thus, it is necessary to pa...

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Bibliographic Details
Published in:Coatings (Basel) 2023-09, Vol.13 (9), p.1586
Main Authors: Qiao, Shiying, Jiang, Haifu, Zhai, Ruiqiong, Liu, Yuming, Li, Tao, Xu, Yanlin, Jiang, Lixiang
Format: Article
Language:English
Subjects:
Ambient temperature
Analysis
Atomic oxygen
Carbon
Connectivity
Flux density
Graphene
Low earth orbits
Low temperature
Methods
Molecular dynamics
Polyethylene terephthalate
Polymers
Reaction products
Simulation
Space ships
Space vehicles
Spacecraft
Spacecraft construction materials
Specific gravity
Temperature effects
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Summary:Atomic oxygen (AO), which is one of the most predominant and conspicuous space environmental factors in the low earth orbit, leads to severe deterioration of polymeric materials in spacecraft. The AO flux density and ambient temperature vary while a craft orbits in space; thus, it is necessary to pay close attention to the flux density and temperature effects on the mechanism of the AO interaction with materials. In past years, polyimide has been widely used on spacecraft due to its excellent performance—that is the reason why we chose Upilex-S as the object for study. It was analyzed using the ReaxFF reactive force field molecular dynamics simulation, respectively from the aspect of impact-induced temperature variation, mass loss, reaction product and erosion yield. The results show that dense AO deposition on the surface impedes further erosion at low temperatures, and the AO interaction with Upilex-S is exacerbated as the ambient temperature increases. However, the accelerating rate is inversely proportional to the ambient temperature, which means the higher the ambient temperature is, the slower it increases. On the other hand, the interaction rate of AO induced to Upilex-S is aggravated as the flux density increases at the lower stage, while the interaction rate begins to drop as the flux density increases at the higher level. The AO erosion effect is a complicated process rather than a simple summation of single atomic oxygen interactions. Our study could be used as a technical reference for the wide usage of Upilex-S on spacecraft.
ISSN:2079-6412
2079-6412
DOI:10.3390/coatings13091586