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The Unique Ambiphilicity of Tellurium in the [MesitylTe(I)(I 2 )(I 3 )] − Anion
A first example of an aryltellurium(II) compound with three different bonding modes to iodine featuring covalent and non‐covalent bonds such as two orthogonal, ambiphilic σ‐hole interactions is introduced: [MesTe(I)(I 2 )(I 3 )] − . It is a member of a series of mesityltellurenyl anions, which are f...
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| Published in: | European journal of inorganic chemistry 2023-10, Vol.26 (30) |
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| Main Authors: | , , , , |
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| Language: | English |
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| container_issue | 30 |
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| container_title | European journal of inorganic chemistry |
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| creator | Matos, Vinícius Zimmermann Londero, Ana Júlia Roca Jungfer, Maximilian Abram, Ulrich Schulz Lang, Ernesto |
| description | A first example of an aryltellurium(II) compound with three different bonding modes to iodine featuring covalent and non‐covalent bonds such as two orthogonal, ambiphilic σ‐hole interactions is introduced: [MesTe(I)(I
2
)(I
3
)]
−
. It is a member of a series of mesityltellurenyl anions, which are formed during reactions of (MesTe)
2
with ZnI
2
, phenanthroline (phen) and iodine. [Zn(phen)
3
][MesTe(I)
2
] (
1
), [Zn(phen)
3
][{MesTe(I)‐(I)…Te(I)Mes}{MesTeI
2
}] (
2
) and [Zn(phen)
3
][MesTe(I)(I
2
)(I
3
)][MesTeI
2
] (
3
) are isolated depending on the amount of iodine used. The products contain tellurium atoms bonded to a variety of iodine species (I
−
, μ
2
‐I
−
, I
2
and I
3
−
) and are, thus, perfectly suitable to explore the amphiphilic behavior of tellurium(II) and its relevance for the formation of non‐covalent bonds, where tellurium acts as both donor and acceptor simultaneously. The character of chalcogen and halogen bonds are evaluated by the combination of crystallographic data and computational methods. |
| doi_str_mv | 10.1002/ejic.202300478 |
| format | article |
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2
)(I
3
)]
−
. It is a member of a series of mesityltellurenyl anions, which are formed during reactions of (MesTe)
2
with ZnI
2
, phenanthroline (phen) and iodine. [Zn(phen)
3
][MesTe(I)
2
] (
1
), [Zn(phen)
3
][{MesTe(I)‐(I)…Te(I)Mes}{MesTeI
2
}] (
2
) and [Zn(phen)
3
][MesTe(I)(I
2
)(I
3
)][MesTeI
2
] (
3
) are isolated depending on the amount of iodine used. The products contain tellurium atoms bonded to a variety of iodine species (I
−
, μ
2
‐I
−
, I
2
and I
3
−
) and are, thus, perfectly suitable to explore the amphiphilic behavior of tellurium(II) and its relevance for the formation of non‐covalent bonds, where tellurium acts as both donor and acceptor simultaneously. The character of chalcogen and halogen bonds are evaluated by the combination of crystallographic data and computational methods.</description><identifier>ISSN: 1434-1948</identifier><identifier>EISSN: 1099-0682</identifier><identifier>DOI: 10.1002/ejic.202300478</identifier><language>eng</language><publisher>Weinheim: Wiley Subscription Services, Inc</publisher><subject>Anions ; Chemical bonds ; Covalence ; Covalent bonds ; Crystallography ; Inorganic chemistry ; Iodine ; Tellurium</subject><ispartof>European journal of inorganic chemistry, 2023-10, Vol.26 (30)</ispartof><rights>2023. This article is published under http://creativecommons.org/licenses/by/4.0/ (the “License”). Notwithstanding the ProQuest Terms and Conditions, you may use this content in accordance with the terms of the License.</rights><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed><cites>FETCH-LOGICAL-c262t-c7c5f5440bad1d6a88266e24ab82a56412b96cf2089ff1dbda28bf90eb4bed4b3</cites><orcidid>0000-0001-7583-9634 ; 0000-0002-1747-7927</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,780,784,27924,27925</link.rule.ids></links><search><creatorcontrib>Matos, Vinícius</creatorcontrib><creatorcontrib>Zimmermann Londero, Ana Júlia</creatorcontrib><creatorcontrib>Roca Jungfer, Maximilian</creatorcontrib><creatorcontrib>Abram, Ulrich</creatorcontrib><creatorcontrib>Schulz Lang, Ernesto</creatorcontrib><title>The Unique Ambiphilicity of Tellurium in the [MesitylTe(I)(I 2 )(I 3 )] − Anion</title><title>European journal of inorganic chemistry</title><description>A first example of an aryltellurium(II) compound with three different bonding modes to iodine featuring covalent and non‐covalent bonds such as two orthogonal, ambiphilic σ‐hole interactions is introduced: [MesTe(I)(I
2
)(I
3
)]
−
. It is a member of a series of mesityltellurenyl anions, which are formed during reactions of (MesTe)
2
with ZnI
2
, phenanthroline (phen) and iodine. [Zn(phen)
3
][MesTe(I)
2
] (
1
), [Zn(phen)
3
][{MesTe(I)‐(I)…Te(I)Mes}{MesTeI
2
}] (
2
) and [Zn(phen)
3
][MesTe(I)(I
2
)(I
3
)][MesTeI
2
] (
3
) are isolated depending on the amount of iodine used. The products contain tellurium atoms bonded to a variety of iodine species (I
−
, μ
2
‐I
−
, I
2
and I
3
−
) and are, thus, perfectly suitable to explore the amphiphilic behavior of tellurium(II) and its relevance for the formation of non‐covalent bonds, where tellurium acts as both donor and acceptor simultaneously. The character of chalcogen and halogen bonds are evaluated by the combination of crystallographic data and computational methods.</description><subject>Anions</subject><subject>Chemical bonds</subject><subject>Covalence</subject><subject>Covalent bonds</subject><subject>Crystallography</subject><subject>Inorganic chemistry</subject><subject>Iodine</subject><subject>Tellurium</subject><issn>1434-1948</issn><issn>1099-0682</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2023</creationdate><recordtype>article</recordtype><recordid>eNo9kE1LAzEQhoMoWKtXzwEv7WHXySSbZo-l-FGoiLA9iYRNNqEp2926H4f-A8_-RH-JWypeZgbeh5nhIeSWQcwA8N5tg40RkAOImTojIwZpGoFUeD7MgouIpUJdkqu23QIABy5H5C3bOLquwmfv6Hxnwn4TymBDd6C1p5kry74J_Y6GinYD-P7i2iErMzdZTidLivRYOZ1-0J-vbzqvQl1dkwufl627-etjsn58yBbP0er1abmYryKLErvIzmziEyHA5AUrZK4USulQ5EZhnkjB0KTSegSVes8KU-SojE_BGWFcIQwfk7vT3n1TD9-3nd7WfVMNJzWqmUJIQMJAxSfKNnXbNs7rfRN2eXPQDPRRmz5q0__a-C99TV67</recordid><startdate>20231024</startdate><enddate>20231024</enddate><creator>Matos, Vinícius</creator><creator>Zimmermann Londero, Ana Júlia</creator><creator>Roca Jungfer, Maximilian</creator><creator>Abram, Ulrich</creator><creator>Schulz Lang, Ernesto</creator><general>Wiley Subscription Services, Inc</general><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>7U5</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope><scope>L7M</scope><orcidid>https://orcid.org/0000-0001-7583-9634</orcidid><orcidid>https://orcid.org/0000-0002-1747-7927</orcidid></search><sort><creationdate>20231024</creationdate><title>The Unique Ambiphilicity of Tellurium in the [MesitylTe(I)(I 2 )(I 3 )] − Anion</title><author>Matos, Vinícius ; Zimmermann Londero, Ana Júlia ; Roca Jungfer, Maximilian ; Abram, Ulrich ; Schulz Lang, Ernesto</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c262t-c7c5f5440bad1d6a88266e24ab82a56412b96cf2089ff1dbda28bf90eb4bed4b3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2023</creationdate><topic>Anions</topic><topic>Chemical bonds</topic><topic>Covalence</topic><topic>Covalent bonds</topic><topic>Crystallography</topic><topic>Inorganic chemistry</topic><topic>Iodine</topic><topic>Tellurium</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Matos, Vinícius</creatorcontrib><creatorcontrib>Zimmermann Londero, Ana Júlia</creatorcontrib><creatorcontrib>Roca Jungfer, Maximilian</creatorcontrib><creatorcontrib>Abram, Ulrich</creatorcontrib><creatorcontrib>Schulz Lang, Ernesto</creatorcontrib><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><collection>Advanced Technologies Database with Aerospace</collection><jtitle>European journal of inorganic chemistry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Matos, Vinícius</au><au>Zimmermann Londero, Ana Júlia</au><au>Roca Jungfer, Maximilian</au><au>Abram, Ulrich</au><au>Schulz Lang, Ernesto</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>The Unique Ambiphilicity of Tellurium in the [MesitylTe(I)(I 2 )(I 3 )] − Anion</atitle><jtitle>European journal of inorganic chemistry</jtitle><date>2023-10-24</date><risdate>2023</risdate><volume>26</volume><issue>30</issue><issn>1434-1948</issn><eissn>1099-0682</eissn><abstract>A first example of an aryltellurium(II) compound with three different bonding modes to iodine featuring covalent and non‐covalent bonds such as two orthogonal, ambiphilic σ‐hole interactions is introduced: [MesTe(I)(I
2
)(I
3
)]
−
. It is a member of a series of mesityltellurenyl anions, which are formed during reactions of (MesTe)
2
with ZnI
2
, phenanthroline (phen) and iodine. [Zn(phen)
3
][MesTe(I)
2
] (
1
), [Zn(phen)
3
][{MesTe(I)‐(I)…Te(I)Mes}{MesTeI
2
}] (
2
) and [Zn(phen)
3
][MesTe(I)(I
2
)(I
3
)][MesTeI
2
] (
3
) are isolated depending on the amount of iodine used. The products contain tellurium atoms bonded to a variety of iodine species (I
−
, μ
2
‐I
−
, I
2
and I
3
−
) and are, thus, perfectly suitable to explore the amphiphilic behavior of tellurium(II) and its relevance for the formation of non‐covalent bonds, where tellurium acts as both donor and acceptor simultaneously. The character of chalcogen and halogen bonds are evaluated by the combination of crystallographic data and computational methods.</abstract><cop>Weinheim</cop><pub>Wiley Subscription Services, Inc</pub><doi>10.1002/ejic.202300478</doi><orcidid>https://orcid.org/0000-0001-7583-9634</orcidid><orcidid>https://orcid.org/0000-0002-1747-7927</orcidid><oa>free_for_read</oa></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 1434-1948 |
| ispartof | European journal of inorganic chemistry, 2023-10, Vol.26 (30) |
| issn | 1434-1948 1099-0682 |
| language | eng |
| recordid | cdi_proquest_journals_2878205060 |
| source | Wiley-Blackwell Read & Publish Collection |
| subjects | Anions Chemical bonds Covalence Covalent bonds Crystallography Inorganic chemistry Iodine Tellurium |
| title | The Unique Ambiphilicity of Tellurium in the [MesitylTe(I)(I 2 )(I 3 )] − Anion |
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