Covalently Bonded Graphene Sheets on Carbon Nanotubes: Direct Growth and Outstanding Properties

Integrating 1D carbon nanotubes (CNTs) and 2D graphene with covalent bonds can inherit the outstanding properties of both components and obtain additional advantages. Here, this work reports the preparation of covalently bonded graphene/CNT (G/CNT) structure by a normal chemical vapor deposition met...

Full description

Saved in:
Bibliographic Details
Published in:Advanced functional materials 2023-10, Vol.33 (43)
Main Authors: Sheng, Jian, Han, Zhen, Jia, Guodong, Zhu, Sheng, Xu, Yifan, Zhang, Xinrui, Yao, Yixi, Li, Yan
Format: Article
Language:English
Subjects:
Carbon nanotubes
Chemical vapor deposition
Covalence
Covalent bonds
Electrical resistivity
Graphene
Graphitization
Materials science
Microwave absorption
Nucleation
Surface stability
Thermal stability
Citations: Items that this one cites
Items that cite this one
Online Access:Get full text
Tags: Add Tag
No Tags, Be the first to tag this record!
Description
Summary:Integrating 1D carbon nanotubes (CNTs) and 2D graphene with covalent bonds can inherit the outstanding properties of both components and obtain additional advantages. Here, this work reports the preparation of covalently bonded graphene/CNT (G/CNT) structure by a normal chemical vapor deposition method. Specifically, the pre‐synthesized defects on the sidewall of CNTs act as nucleation sites for the growth of graphene sheets to form a branch‐leaf structure. Graphene leaves restrict the sliding and re‐stacking of CNTs, endowing G/CNT hybrid demonstrates excellent anti‐agglomeration properties that are not present in either graphene or CNTs. In addition, the covalently bonded structure and high graphitization degree of graphene sheets and CNTs significantly enhance the comprehensive properties of the G/CNT hybrid material, such as large specific surface area, excellent thermal stability, and high electrical conductivity. Consequently, the microwave absorption properties of G/CNT are significantly enhanced compared with CNTs. This work provides a feasible pathway to synthesize high‐performance covalently bonded G/CNT hybrids.
ISSN:1616-301X
1616-3028
DOI:10.1002/adfm.202306785