Loading…
Tandem Design of Functional Separators for Li Metal Batteries with Long‐Term Stability and High‐Rate Capability
The lithium (Li) dendrite growth seriously hinders the applications of lithium metal batteries (LMBs). Numerous methods have been proposed to restrict the formation of Li dendrites by improving the Li‐ion transference number (t Li + ) through separator modification according to Sand's time equa...
Saved in:
| Published in: | Advanced functional materials 2023-10, Vol.33 (43) |
|---|---|
| Main Authors: | , , , , , , |
| Format: | Article |
| Language: | English |
| Subjects: | |
| Citations: | Items that this one cites Items that cite this one |
| Online Access: | Get full text |
| Tags: |
Add Tag
No Tags, Be the first to tag this record!
|
| cited_by | cdi_FETCH-LOGICAL-c267t-c3ba3f7319171ca2c38de22a78c79dce285079972c0a709771cc083e1d77f6623 |
|---|---|
| cites | cdi_FETCH-LOGICAL-c267t-c3ba3f7319171ca2c38de22a78c79dce285079972c0a709771cc083e1d77f6623 |
| container_end_page | |
| container_issue | 43 |
| container_start_page | |
| container_title | Advanced functional materials |
| container_volume | 33 |
| creator | Ding, Luoyi Yue, Xinyang Chen, Yuanmao Wang, Zhiyong Liu, Jijiang Shi, Zhangqin Liang, Zheng |
| description | The lithium (Li) dendrite growth seriously hinders the applications of lithium metal batteries (LMBs). Numerous methods have been proposed to restrict the formation of Li dendrites by improving the Li‐ion transference number (t
Li
+
) through separator modification according to Sand's time equation. However, ignoring the positive contribution of anion motion to solid electrolyte interphase (SEI) formation will result in insufficient inorganic components, which impedes practical implementation of LMBs. Herein, a “tandem” separator is constructed (ZSM‐5‐Poly dimethyl diallyl ammonium chloride (PDDA)/Polyethylene (PE)/SbF
3
), which anchored anions and built an inorganic‐rich SEI at the same time. The resulting SEI from SbF
3
(SBF) coating on side facing Li is rich in Li‐Sb alloy (Li
3
Sb) and LiF. Li
3
Sb can significantly reduce the migration energy barrier of Li ion (Li
+
) and facilitate Li
+
transport. Simultaneously, ZSM‐5‐PDDA (Z5P) coating at the other side can effectively immobilize anions and increase the t
Li
+
. Moreover, the regular pore structure is conducive to homogenizing Li
+
flux and also capable to uniform temperature distribution, significantly improving safety. Hence, the lifespan of Li|Li and Li|Cu cells assemble with Z5P/PE/SBF separator is significantly extended. In addition, full cells with LiNi
0.8
Co
0.1
Mn
0.1
O
2
(NCM811) and LiFePO
4
(LFP) cathodes show excellent cycle stability and superior rate performance. |
| doi_str_mv | 10.1002/adfm.202304386 |
| format | article |
| fullrecord | <record><control><sourceid>proquest_cross</sourceid><recordid>TN_cdi_proquest_journals_2878220987</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>2878220987</sourcerecordid><originalsourceid>FETCH-LOGICAL-c267t-c3ba3f7319171ca2c38de22a78c79dce285079972c0a709771cc083e1d77f6623</originalsourceid><addsrcrecordid>eNo9kE1Lw0AQhhdRsFavnhc8p-5HzWyOWq0VIoKt4C1MN5t2S5ONu1ukN3-Cv9FfYkpLTzPM-_DCPIRcczbgjIlbLKt6IJiQbChVekJ6POVpIplQp8edf56TixBWjHEAOeyRMMOmNDV9NMEuGuoqOt40OlrX4JpOTYseo_OBVs7T3NJXE7v7A8ZovDWBftu4pLlrFn8_vzPjazqNOLdrG7e066UTu1h2yTtGQ0fYHqJLclbhOpirw-yTj_HTbDRJ8rfnl9F9nmiRQky0nKOsQPKMA9cotFSlEQJBachKbYS6Y5BlIDRDYBl0kGZKGl4CVGkqZJ_c7Htb7742JsRi5Ta-eywUQoESgmUKOmqwp7R3IXhTFa23NfptwVmxE1vsxBZHsfIf9KVtvw</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>2878220987</pqid></control><display><type>article</type><title>Tandem Design of Functional Separators for Li Metal Batteries with Long‐Term Stability and High‐Rate Capability</title><source>Wiley-Blackwell Read & Publish Collection</source><creator>Ding, Luoyi ; Yue, Xinyang ; Chen, Yuanmao ; Wang, Zhiyong ; Liu, Jijiang ; Shi, Zhangqin ; Liang, Zheng</creator><creatorcontrib>Ding, Luoyi ; Yue, Xinyang ; Chen, Yuanmao ; Wang, Zhiyong ; Liu, Jijiang ; Shi, Zhangqin ; Liang, Zheng</creatorcontrib><description>The lithium (Li) dendrite growth seriously hinders the applications of lithium metal batteries (LMBs). Numerous methods have been proposed to restrict the formation of Li dendrites by improving the Li‐ion transference number (t
Li
+
) through separator modification according to Sand's time equation. However, ignoring the positive contribution of anion motion to solid electrolyte interphase (SEI) formation will result in insufficient inorganic components, which impedes practical implementation of LMBs. Herein, a “tandem” separator is constructed (ZSM‐5‐Poly dimethyl diallyl ammonium chloride (PDDA)/Polyethylene (PE)/SbF
3
), which anchored anions and built an inorganic‐rich SEI at the same time. The resulting SEI from SbF
3
(SBF) coating on side facing Li is rich in Li‐Sb alloy (Li
3
Sb) and LiF. Li
3
Sb can significantly reduce the migration energy barrier of Li ion (Li
+
) and facilitate Li
+
transport. Simultaneously, ZSM‐5‐PDDA (Z5P) coating at the other side can effectively immobilize anions and increase the t
Li
+
. Moreover, the regular pore structure is conducive to homogenizing Li
+
flux and also capable to uniform temperature distribution, significantly improving safety. Hence, the lifespan of Li|Li and Li|Cu cells assemble with Z5P/PE/SBF separator is significantly extended. In addition, full cells with LiNi
0.8
Co
0.1
Mn
0.1
O
2
(NCM811) and LiFePO
4
(LFP) cathodes show excellent cycle stability and superior rate performance.</description><identifier>ISSN: 1616-301X</identifier><identifier>EISSN: 1616-3028</identifier><identifier>DOI: 10.1002/adfm.202304386</identifier><language>eng</language><publisher>Hoboken: Wiley Subscription Services, Inc</publisher><subject>Ammonium chloride ; Anions ; Antimony fluorides ; Electrolytic cells ; Lithium batteries ; Materials science ; Polyethylenes ; Separators ; Solid electrolytes ; Stability ; Temperature distribution</subject><ispartof>Advanced functional materials, 2023-10, Vol.33 (43)</ispartof><rights>2023 Wiley‐VCH GmbH</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c267t-c3ba3f7319171ca2c38de22a78c79dce285079972c0a709771cc083e1d77f6623</citedby><cites>FETCH-LOGICAL-c267t-c3ba3f7319171ca2c38de22a78c79dce285079972c0a709771cc083e1d77f6623</cites><orcidid>0000-0001-9137-0338</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,780,784,27924,27925</link.rule.ids></links><search><creatorcontrib>Ding, Luoyi</creatorcontrib><creatorcontrib>Yue, Xinyang</creatorcontrib><creatorcontrib>Chen, Yuanmao</creatorcontrib><creatorcontrib>Wang, Zhiyong</creatorcontrib><creatorcontrib>Liu, Jijiang</creatorcontrib><creatorcontrib>Shi, Zhangqin</creatorcontrib><creatorcontrib>Liang, Zheng</creatorcontrib><title>Tandem Design of Functional Separators for Li Metal Batteries with Long‐Term Stability and High‐Rate Capability</title><title>Advanced functional materials</title><description>The lithium (Li) dendrite growth seriously hinders the applications of lithium metal batteries (LMBs). Numerous methods have been proposed to restrict the formation of Li dendrites by improving the Li‐ion transference number (t
Li
+
) through separator modification according to Sand's time equation. However, ignoring the positive contribution of anion motion to solid electrolyte interphase (SEI) formation will result in insufficient inorganic components, which impedes practical implementation of LMBs. Herein, a “tandem” separator is constructed (ZSM‐5‐Poly dimethyl diallyl ammonium chloride (PDDA)/Polyethylene (PE)/SbF
3
), which anchored anions and built an inorganic‐rich SEI at the same time. The resulting SEI from SbF
3
(SBF) coating on side facing Li is rich in Li‐Sb alloy (Li
3
Sb) and LiF. Li
3
Sb can significantly reduce the migration energy barrier of Li ion (Li
+
) and facilitate Li
+
transport. Simultaneously, ZSM‐5‐PDDA (Z5P) coating at the other side can effectively immobilize anions and increase the t
Li
+
. Moreover, the regular pore structure is conducive to homogenizing Li
+
flux and also capable to uniform temperature distribution, significantly improving safety. Hence, the lifespan of Li|Li and Li|Cu cells assemble with Z5P/PE/SBF separator is significantly extended. In addition, full cells with LiNi
0.8
Co
0.1
Mn
0.1
O
2
(NCM811) and LiFePO
4
(LFP) cathodes show excellent cycle stability and superior rate performance.</description><subject>Ammonium chloride</subject><subject>Anions</subject><subject>Antimony fluorides</subject><subject>Electrolytic cells</subject><subject>Lithium batteries</subject><subject>Materials science</subject><subject>Polyethylenes</subject><subject>Separators</subject><subject>Solid electrolytes</subject><subject>Stability</subject><subject>Temperature distribution</subject><issn>1616-301X</issn><issn>1616-3028</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2023</creationdate><recordtype>article</recordtype><recordid>eNo9kE1Lw0AQhhdRsFavnhc8p-5HzWyOWq0VIoKt4C1MN5t2S5ONu1ukN3-Cv9FfYkpLTzPM-_DCPIRcczbgjIlbLKt6IJiQbChVekJ6POVpIplQp8edf56TixBWjHEAOeyRMMOmNDV9NMEuGuoqOt40OlrX4JpOTYseo_OBVs7T3NJXE7v7A8ZovDWBftu4pLlrFn8_vzPjazqNOLdrG7e066UTu1h2yTtGQ0fYHqJLclbhOpirw-yTj_HTbDRJ8rfnl9F9nmiRQky0nKOsQPKMA9cotFSlEQJBachKbYS6Y5BlIDRDYBl0kGZKGl4CVGkqZJ_c7Htb7742JsRi5Ta-eywUQoESgmUKOmqwp7R3IXhTFa23NfptwVmxE1vsxBZHsfIf9KVtvw</recordid><startdate>20231018</startdate><enddate>20231018</enddate><creator>Ding, Luoyi</creator><creator>Yue, Xinyang</creator><creator>Chen, Yuanmao</creator><creator>Wang, Zhiyong</creator><creator>Liu, Jijiang</creator><creator>Shi, Zhangqin</creator><creator>Liang, Zheng</creator><general>Wiley Subscription Services, Inc</general><scope>AAYXX</scope><scope>CITATION</scope><scope>7SP</scope><scope>7SR</scope><scope>7U5</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope><scope>L7M</scope><orcidid>https://orcid.org/0000-0001-9137-0338</orcidid></search><sort><creationdate>20231018</creationdate><title>Tandem Design of Functional Separators for Li Metal Batteries with Long‐Term Stability and High‐Rate Capability</title><author>Ding, Luoyi ; Yue, Xinyang ; Chen, Yuanmao ; Wang, Zhiyong ; Liu, Jijiang ; Shi, Zhangqin ; Liang, Zheng</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c267t-c3ba3f7319171ca2c38de22a78c79dce285079972c0a709771cc083e1d77f6623</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2023</creationdate><topic>Ammonium chloride</topic><topic>Anions</topic><topic>Antimony fluorides</topic><topic>Electrolytic cells</topic><topic>Lithium batteries</topic><topic>Materials science</topic><topic>Polyethylenes</topic><topic>Separators</topic><topic>Solid electrolytes</topic><topic>Stability</topic><topic>Temperature distribution</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Ding, Luoyi</creatorcontrib><creatorcontrib>Yue, Xinyang</creatorcontrib><creatorcontrib>Chen, Yuanmao</creatorcontrib><creatorcontrib>Wang, Zhiyong</creatorcontrib><creatorcontrib>Liu, Jijiang</creatorcontrib><creatorcontrib>Shi, Zhangqin</creatorcontrib><creatorcontrib>Liang, Zheng</creatorcontrib><collection>CrossRef</collection><collection>Electronics & Communications Abstracts</collection><collection>Engineered Materials Abstracts</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><collection>Advanced Technologies Database with Aerospace</collection><jtitle>Advanced functional materials</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Ding, Luoyi</au><au>Yue, Xinyang</au><au>Chen, Yuanmao</au><au>Wang, Zhiyong</au><au>Liu, Jijiang</au><au>Shi, Zhangqin</au><au>Liang, Zheng</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Tandem Design of Functional Separators for Li Metal Batteries with Long‐Term Stability and High‐Rate Capability</atitle><jtitle>Advanced functional materials</jtitle><date>2023-10-18</date><risdate>2023</risdate><volume>33</volume><issue>43</issue><issn>1616-301X</issn><eissn>1616-3028</eissn><abstract>The lithium (Li) dendrite growth seriously hinders the applications of lithium metal batteries (LMBs). Numerous methods have been proposed to restrict the formation of Li dendrites by improving the Li‐ion transference number (t
Li
+
) through separator modification according to Sand's time equation. However, ignoring the positive contribution of anion motion to solid electrolyte interphase (SEI) formation will result in insufficient inorganic components, which impedes practical implementation of LMBs. Herein, a “tandem” separator is constructed (ZSM‐5‐Poly dimethyl diallyl ammonium chloride (PDDA)/Polyethylene (PE)/SbF
3
), which anchored anions and built an inorganic‐rich SEI at the same time. The resulting SEI from SbF
3
(SBF) coating on side facing Li is rich in Li‐Sb alloy (Li
3
Sb) and LiF. Li
3
Sb can significantly reduce the migration energy barrier of Li ion (Li
+
) and facilitate Li
+
transport. Simultaneously, ZSM‐5‐PDDA (Z5P) coating at the other side can effectively immobilize anions and increase the t
Li
+
. Moreover, the regular pore structure is conducive to homogenizing Li
+
flux and also capable to uniform temperature distribution, significantly improving safety. Hence, the lifespan of Li|Li and Li|Cu cells assemble with Z5P/PE/SBF separator is significantly extended. In addition, full cells with LiNi
0.8
Co
0.1
Mn
0.1
O
2
(NCM811) and LiFePO
4
(LFP) cathodes show excellent cycle stability and superior rate performance.</abstract><cop>Hoboken</cop><pub>Wiley Subscription Services, Inc</pub><doi>10.1002/adfm.202304386</doi><orcidid>https://orcid.org/0000-0001-9137-0338</orcidid></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 1616-301X |
| ispartof | Advanced functional materials, 2023-10, Vol.33 (43) |
| issn | 1616-301X 1616-3028 |
| language | eng |
| recordid | cdi_proquest_journals_2878220987 |
| source | Wiley-Blackwell Read & Publish Collection |
| subjects | Ammonium chloride Anions Antimony fluorides Electrolytic cells Lithium batteries Materials science Polyethylenes Separators Solid electrolytes Stability Temperature distribution |
| title | Tandem Design of Functional Separators for Li Metal Batteries with Long‐Term Stability and High‐Rate Capability |
| url | http://sfxeu10.hosted.exlibrisgroup.com/loughborough?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2024-12-27T06%3A55%3A08IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest_cross&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Tandem%20Design%20of%20Functional%20Separators%20for%20Li%20Metal%20Batteries%20with%20Long%E2%80%90Term%20Stability%20and%20High%E2%80%90Rate%20Capability&rft.jtitle=Advanced%20functional%20materials&rft.au=Ding,%20Luoyi&rft.date=2023-10-18&rft.volume=33&rft.issue=43&rft.issn=1616-301X&rft.eissn=1616-3028&rft_id=info:doi/10.1002/adfm.202304386&rft_dat=%3Cproquest_cross%3E2878220987%3C/proquest_cross%3E%3Cgrp_id%3Ecdi_FETCH-LOGICAL-c267t-c3ba3f7319171ca2c38de22a78c79dce285079972c0a709771cc083e1d77f6623%3C/grp_id%3E%3Coa%3E%3C/oa%3E%3Curl%3E%3C/url%3E&rft_id=info:oai/&rft_pqid=2878220987&rft_id=info:pmid/&rfr_iscdi=true |