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Photoluminescence investigation of novel KCaPO4:Sm3+ phosphors for n-UV based solid state lighting Prepared by wet chemical synthesis

The wet chemical method was used for the first time to synthesize novel KCaPO 4 :Sm 3+ phosphor. The characteristics of XRD, morphology and photoluminescence were thoroughly investigated. The hexagonal structure of KCaPO 4 is confirmed by the XRD analysis. The KCaPO 4 :Sm 3+ phosphor emission are pe...

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Published in:Optical and quantum electronics 2023-12, Vol.55 (13), Article 1173
Main Authors: Nandanwar, C. M., Kokode, N. S., Nande, A. V., Mungmode, C. D., Yerpude, A. N., Yerojwar, R. M., Dhoble, S. J.
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cited_by cdi_FETCH-LOGICAL-c249t-4b68fb0a3e719b0b3bed20ffb82bac6958576be5723a447fd954615acb5f1f03
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description The wet chemical method was used for the first time to synthesize novel KCaPO 4 :Sm 3+ phosphor. The characteristics of XRD, morphology and photoluminescence were thoroughly investigated. The hexagonal structure of KCaPO 4 is confirmed by the XRD analysis. The KCaPO 4 :Sm 3+ phosphor emission are peaks located at 565 nm, 599 nm and 646 nm under excited at 403 nm. Concentration quenching was shown to occur at 1 mol% of Sm 3+ ions. It was found that concentration quenching occurred as a result of quadrupole–quadrupole interaction according to Dexter’s theory. The CIE Chromaticity coordinate of the prepared phosphor was located in the orange region around (0.602, 0.395) with high color purity. The current study suggests that KCaPO 4 :Sm 3+ phosphors could potentially represent a promising n-UV converter material for solid-state lighting applications.
doi_str_mv 10.1007/s11082-023-05318-2
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subjects Characterization and Evaluation of Materials
Chemical synthesis
Chromaticity
Computer Communication Networks
Electrical Engineering
Emission analysis
Lasers
Lighting
Optical Devices
Optics
Phosphors
Photoluminescence
Photonics
Physics
Physics and Astronomy
Quadrupole interaction
Quadrupoles
Quenching
Solid state
title Photoluminescence investigation of novel KCaPO4:Sm3+ phosphors for n-UV based solid state lighting Prepared by wet chemical synthesis
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