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Innenrücktitelbild: Cation‐Radius‐Controlled Sn−O Bond Length Boosting CO2 Electroreduction over Sn‐Based Perovskite Oxides
Sn‐based perovskite oxides have shown intriguing potential in CO2 electroreduction. In their Research Article (e202305530), Jiawei Zhu and co‐workers report an effective strategy to promote CO2‐to‐HCOOH conversion of Sn‐based perovskite oxides by A‐site‐radius‐controlled Sn−O bond lengths. With the...
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Published in: | Angewandte Chemie 2023-10, Vol.135 (44) |
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Main Authors: | , , , , , , , , |
Format: | Article |
Language: | English |
Subjects: | |
Online Access: | Get full text |
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Summary: | Sn‐based perovskite oxides have shown intriguing potential in CO2 electroreduction. In their Research Article (e202305530), Jiawei Zhu and co‐workers report an effective strategy to promote CO2‐to‐HCOOH conversion of Sn‐based perovskite oxides by A‐site‐radius‐controlled Sn−O bond lengths. With the Ba1−xSrxSnO3 (x from 0 to 1) series as proof‐of‐concept catalysts, it is demonstrated that their activity/selectivity for HCOOH featured a volcano‐type dependence on the Sn−O bond lengths, with a maximum point corresponding to Ba0.5Sr0.5SnO3. |
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ISSN: | 0044-8249 1521-3757 |
DOI: | 10.1002/ange.202312433 |