Preconcentration and Test Determination of Phenols Using a Polyamide-Based Nanofiber

• Published in: Journal of analytical chemistry (New York, N.Y.) N.Y.), 2023-10, Vol.78 (10), p.1355-1361
• Main Authors: Makhova, T. M., Arzhanukhina, A. I., Doronin, S. Yu
• Format: Article
• Language: English
• Subjects: 2-chlorophenol; Analytical Chemistry; Aqueous solutions; Chemical properties; Chemistry; Chemistry and Materials Science; Chlorine; Colorimetry; condensation reactions; derivatization; Digital imaging; Measurement; Nanofibers; Nanoparticles; Ortho-chlorophenol; phenol; Phenols; Polyamide resins; Polyamides; Sorption
• ISSN: 1061-9348; 1608-3199
• DOI: 10.1134/S1061934823100131

New test tools made of nanofibers based on polyamide-6 (PA-6) for the sorption preconcentration of some phenols as their azo derivatives followed by colorimetric determination are obtained. Approaches to the derivatization of phenol and chlorine derivatives by azo coupling with 4-nitrophenyldiazonium and oxidative condensation with 4-aminoantipyrine for improving the sorption characteristics of the studied phenols are proposed. The efficiency of the two derivatization methods is compared. The sorption kinetics of phenol and 2-chlorophenol derivatives and the effect of pH on the nature of their sorption are studied. The features of the sorption of phenol derivatives on nonwoven materials and the corresponding sorption isotherms are interpreted. Examples of the quantitative assessment of the concentration of phenols in aqueous media by the mathematical processing of digital images of the colored areas of test tools are presented. It is shown that the proposed methods can be used for the determination of phenol and 2-chlorophenol with the preconcentration of their derivatives on a PA-6 nanofiber in the range 0.2–1.0 μM (≈0.02–0.09 mg/L for phenol, ≈0.03–0.13 mg/L for 2-chlorophenol) with an error of colorimetric determination of no more than 20% (MAC hshld phenol is 0.001 mg/L for the amount of volatile phenols in water bodies, provided that water is disinfected with chlorine; in other cases, the MAC is 0.1 mg/L).