Interaction and infiltration behavior between calcium–ferrum–alumina–silicate and Yb4Hf3O12 ceramics at various temperatures

The interaction and infiltration behavior between typical calcium–ferrum–alumina–silicate (CFAS) and Yb4Hf3O12 ceramics at 1300, 1400, and 1500°C for different duration times were investigated. At 1300°C, the CFAS melt first crystallized and then generated massive anorthite with high‐melting point,...

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Bibliographic Details
Published in:Journal of the American Ceramic Society 2024-01, Vol.107 (1), p.475-487
Main Authors: He, Ling, Pan, Ling, Zhou, Wei, Chen, Maolin, Zhang, Qinzhao, Pan, Wenqian, Xiao, Peng, Yang, Li
Format: Article
Language:English
Subjects:
Aluminum oxide
Anorthite
Apatite
Calcium aluminum silicates
Ceramics
Corrosion effects
Crystallization
Fluorite
Infiltration rate
Melting points
Wettability
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Summary:The interaction and infiltration behavior between typical calcium–ferrum–alumina–silicate (CFAS) and Yb4Hf3O12 ceramics at 1300, 1400, and 1500°C for different duration times were investigated. At 1300°C, the CFAS melt first crystallized and then generated massive anorthite with high‐melting point, reducing the wettability of CFAS melt and physically blocking CFAS penetration paths. As the temperature increased to 1400°C and 1500°C, the wettability of the molten CFAS correspondingly increases. A continuous reaction layer, composed of apatite, fluorite, and garnet, was formed over Yb4Hf3O12 ceramic due to the penetration of CFAS melt. Furthermore, the infiltration rate of CFAS decreases with increasing corrosion time because of the barrier effect primarily derived from the as‐mentioned continuous reaction layer.
ISSN:0002-7820
1551-2916
DOI:10.1111/jace.19413