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Tetrahydrofuran intercalated layered vanadium(III) phosphate electrode for aqueous zinc-ion battery
Layered VOPO 4 ·2H 2 O is considered a good electrode material structure for the insertion and extraction of energy storage ions, but the lattice water may affect the electrochemical stability. To provide more active site and more stable layered structure, the lattice water was replaced by tetrahydr...
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| Published in: | Ionics 2023-11, Vol.29 (11), p.4743-4749 |
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| Main Authors: | , , , , , , |
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| Language: | English |
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| container_end_page | 4749 |
| container_issue | 11 |
| container_start_page | 4743 |
| container_title | Ionics |
| container_volume | 29 |
| creator | Qiao, Yifan Yuan, Jingjing Lu, Yuchen Ren, Yihan Li, Yifan Zhang, Zhihao Chen, Haiqun |
| description | Layered VOPO
4
·2H
2
O is considered a good electrode material structure for the insertion and extraction of energy storage ions, but the lattice water may affect the electrochemical stability. To provide more active site and more stable layered structure, the lattice water was replaced by tetrahydrofuran (THF), and the THF intercalated VOPO
4
was obtained. The interlayer spacing has changed from 7.4 to 6.3 Å after THF intercalation, and the layered structure of VOPO
4
-THF is well preserved. It offers enhanced structural stability during charge and discharge processes, minimizing electrode degradation. In addition, increasing the oxidation state of pentavalent vanadium in VOPO
4
-THF is also beneficial for enhancing the capacitance of electrode materials. Combining the stable layered structure with a high oxidation state, VOPO
4
-THF electrode material exhibits good capacity and long cycle life. Our work convert traditional VOPO
4
·2H
2
O electrode into a promising high-performance active electrode for zinc-ion batteries. |
| doi_str_mv | 10.1007/s11581-023-05197-3 |
| format | article |
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4
·2H
2
O is considered a good electrode material structure for the insertion and extraction of energy storage ions, but the lattice water may affect the electrochemical stability. To provide more active site and more stable layered structure, the lattice water was replaced by tetrahydrofuran (THF), and the THF intercalated VOPO
4
was obtained. The interlayer spacing has changed from 7.4 to 6.3 Å after THF intercalation, and the layered structure of VOPO
4
-THF is well preserved. It offers enhanced structural stability during charge and discharge processes, minimizing electrode degradation. In addition, increasing the oxidation state of pentavalent vanadium in VOPO
4
-THF is also beneficial for enhancing the capacitance of electrode materials. Combining the stable layered structure with a high oxidation state, VOPO
4
-THF electrode material exhibits good capacity and long cycle life. Our work convert traditional VOPO
4
·2H
2
O electrode into a promising high-performance active electrode for zinc-ion batteries.</description><identifier>ISSN: 0947-7047</identifier><identifier>EISSN: 1862-0760</identifier><identifier>DOI: 10.1007/s11581-023-05197-3</identifier><language>eng</language><publisher>Berlin/Heidelberg: Springer Berlin Heidelberg</publisher><subject>Chemistry ; Chemistry and Materials Science ; Condensed Matter Physics ; Electrochemistry ; Electrode materials ; Electrodes ; Energy Storage ; Interlayers ; Optical and Electronic Materials ; Oxidation ; Rechargeable batteries ; Renewable and Green Energy ; Structural stability ; Tetrahydrofuran ; Valence ; Vanadium</subject><ispartof>Ionics, 2023-11, Vol.29 (11), p.4743-4749</ispartof><rights>The Author(s), under exclusive licence to Springer-Verlag GmbH Germany, part of Springer Nature 2023. Springer Nature or its licensor (e.g. a society or other partner) holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><cites>FETCH-LOGICAL-c270t-1a4098b74f918d341433a96dcd9482ae6386a2b878a5c20d7d63da6857ee536b3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,780,784,27924,27925</link.rule.ids></links><search><creatorcontrib>Qiao, Yifan</creatorcontrib><creatorcontrib>Yuan, Jingjing</creatorcontrib><creatorcontrib>Lu, Yuchen</creatorcontrib><creatorcontrib>Ren, Yihan</creatorcontrib><creatorcontrib>Li, Yifan</creatorcontrib><creatorcontrib>Zhang, Zhihao</creatorcontrib><creatorcontrib>Chen, Haiqun</creatorcontrib><title>Tetrahydrofuran intercalated layered vanadium(III) phosphate electrode for aqueous zinc-ion battery</title><title>Ionics</title><addtitle>Ionics</addtitle><description>Layered VOPO
4
·2H
2
O is considered a good electrode material structure for the insertion and extraction of energy storage ions, but the lattice water may affect the electrochemical stability. To provide more active site and more stable layered structure, the lattice water was replaced by tetrahydrofuran (THF), and the THF intercalated VOPO
4
was obtained. The interlayer spacing has changed from 7.4 to 6.3 Å after THF intercalation, and the layered structure of VOPO
4
-THF is well preserved. It offers enhanced structural stability during charge and discharge processes, minimizing electrode degradation. In addition, increasing the oxidation state of pentavalent vanadium in VOPO
4
-THF is also beneficial for enhancing the capacitance of electrode materials. Combining the stable layered structure with a high oxidation state, VOPO
4
-THF electrode material exhibits good capacity and long cycle life. Our work convert traditional VOPO
4
·2H
2
O electrode into a promising high-performance active electrode for zinc-ion batteries.</description><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Condensed Matter Physics</subject><subject>Electrochemistry</subject><subject>Electrode materials</subject><subject>Electrodes</subject><subject>Energy Storage</subject><subject>Interlayers</subject><subject>Optical and Electronic Materials</subject><subject>Oxidation</subject><subject>Rechargeable batteries</subject><subject>Renewable and Green Energy</subject><subject>Structural stability</subject><subject>Tetrahydrofuran</subject><subject>Valence</subject><subject>Vanadium</subject><issn>0947-7047</issn><issn>1862-0760</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2023</creationdate><recordtype>article</recordtype><recordid>eNp9kEtLxDAUhYMoOI7-AVcFN7qI5tEm6VIGHwMDbsZ1uE1Sp0OnqUkr1F9vtII7V2fznXMvH0KXlNxSQuRdpLRQFBPGMSloKTE_QguqBMNECnKMFqTMJZYkl6foLMY9IUJQJhfIbN0QYDfZ4OsxQJc13eCCgRYGZ7MWJhdSfkAHthkP1-v1-ibrdz72uwRkrnVmCN66rPYhg_fR-TFmn01ncOO7rIIhjU3n6KSGNrqL31yi18eH7eoZb16e1qv7DTZMkgFTyEmpKpnXJVWW5zTnHEphjS1zxcAJrgSwSkkFhWHESiu4BaEK6VzBRcWX6Gre7YNPr8RB7_0YunRSM6VkkRdSkUSxmTLBxxhcrfvQHCBMmhL9LVPPMnWSqX9kap5KfC7FBHdvLvxN_9P6AuJSeEE</recordid><startdate>20231101</startdate><enddate>20231101</enddate><creator>Qiao, Yifan</creator><creator>Yuan, Jingjing</creator><creator>Lu, Yuchen</creator><creator>Ren, Yihan</creator><creator>Li, Yifan</creator><creator>Zhang, Zhihao</creator><creator>Chen, Haiqun</creator><general>Springer Berlin Heidelberg</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>20231101</creationdate><title>Tetrahydrofuran intercalated layered vanadium(III) phosphate electrode for aqueous zinc-ion battery</title><author>Qiao, Yifan ; Yuan, Jingjing ; Lu, Yuchen ; Ren, Yihan ; Li, Yifan ; Zhang, Zhihao ; Chen, Haiqun</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c270t-1a4098b74f918d341433a96dcd9482ae6386a2b878a5c20d7d63da6857ee536b3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2023</creationdate><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>Condensed Matter Physics</topic><topic>Electrochemistry</topic><topic>Electrode materials</topic><topic>Electrodes</topic><topic>Energy Storage</topic><topic>Interlayers</topic><topic>Optical and Electronic Materials</topic><topic>Oxidation</topic><topic>Rechargeable batteries</topic><topic>Renewable and Green Energy</topic><topic>Structural stability</topic><topic>Tetrahydrofuran</topic><topic>Valence</topic><topic>Vanadium</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Qiao, Yifan</creatorcontrib><creatorcontrib>Yuan, Jingjing</creatorcontrib><creatorcontrib>Lu, Yuchen</creatorcontrib><creatorcontrib>Ren, Yihan</creatorcontrib><creatorcontrib>Li, Yifan</creatorcontrib><creatorcontrib>Zhang, Zhihao</creatorcontrib><creatorcontrib>Chen, Haiqun</creatorcontrib><collection>CrossRef</collection><jtitle>Ionics</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Qiao, Yifan</au><au>Yuan, Jingjing</au><au>Lu, Yuchen</au><au>Ren, Yihan</au><au>Li, Yifan</au><au>Zhang, Zhihao</au><au>Chen, Haiqun</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Tetrahydrofuran intercalated layered vanadium(III) phosphate electrode for aqueous zinc-ion battery</atitle><jtitle>Ionics</jtitle><stitle>Ionics</stitle><date>2023-11-01</date><risdate>2023</risdate><volume>29</volume><issue>11</issue><spage>4743</spage><epage>4749</epage><pages>4743-4749</pages><issn>0947-7047</issn><eissn>1862-0760</eissn><abstract>Layered VOPO
4
·2H
2
O is considered a good electrode material structure for the insertion and extraction of energy storage ions, but the lattice water may affect the electrochemical stability. To provide more active site and more stable layered structure, the lattice water was replaced by tetrahydrofuran (THF), and the THF intercalated VOPO
4
was obtained. The interlayer spacing has changed from 7.4 to 6.3 Å after THF intercalation, and the layered structure of VOPO
4
-THF is well preserved. It offers enhanced structural stability during charge and discharge processes, minimizing electrode degradation. In addition, increasing the oxidation state of pentavalent vanadium in VOPO
4
-THF is also beneficial for enhancing the capacitance of electrode materials. Combining the stable layered structure with a high oxidation state, VOPO
4
-THF electrode material exhibits good capacity and long cycle life. Our work convert traditional VOPO
4
·2H
2
O electrode into a promising high-performance active electrode for zinc-ion batteries.</abstract><cop>Berlin/Heidelberg</cop><pub>Springer Berlin Heidelberg</pub><doi>10.1007/s11581-023-05197-3</doi><tpages>7</tpages></addata></record> |
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| ispartof | Ionics, 2023-11, Vol.29 (11), p.4743-4749 |
| issn | 0947-7047 1862-0760 |
| language | eng |
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| source | Springer Link |
| subjects | Chemistry Chemistry and Materials Science Condensed Matter Physics Electrochemistry Electrode materials Electrodes Energy Storage Interlayers Optical and Electronic Materials Oxidation Rechargeable batteries Renewable and Green Energy Structural stability Tetrahydrofuran Valence Vanadium |
| title | Tetrahydrofuran intercalated layered vanadium(III) phosphate electrode for aqueous zinc-ion battery |
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