Fischer–Tropsch Synthesis over Bifunctional Catalysts Based on HBeta Zeolite

A number of catalysts were synthesized from a composite mixture consisting of a metal component (specifically, a Co–Al 2 O 3 /SiO 2 catalyst in an amount of 20–40% for the synthesis of long-chain hydrocarbons), an acid component (Beta zeolite in the H-form, 20–50%), and a binder (boehmite). The cata...

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Bibliographic Details
Published in:Petroleum chemistry 2023-07, Vol.63 (7), p.737-745
Main Authors: Papeta, O. P., Sulima, S. I., Bakun, V. G., Zubkov, I. N., Saliev, A. N., Yakovenko, R. E.
Format: Article
Language:English
Subjects:
Aluminum oxide
Argon
Boehmite
Catalysis
Catalysts
Chemical synthesis
Chemistry
Chemistry and Materials Science
Diesel fuels
Fischer-Tropsch process
Hydrocarbons
Industrial Chemistry/Chemical Engineering
Isomerization
Low temperature
Silicon dioxide
Zeolites
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Summary:A number of catalysts were synthesized from a composite mixture consisting of a metal component (specifically, a Co–Al 2 O 3 /SiO 2 catalyst in an amount of 20–40% for the synthesis of long-chain hydrocarbons), an acid component (Beta zeolite in the H-form, 20–50%), and a binder (boehmite). The catalysts were characterized by XRD, low-temperature argon adsorption/desorption, and TPR, and tested in Fischer–Tropsch synthesis at 2.0 MPa, 240°C, and GHSV 1000 h –1 . The activity and selectivity of the catalysts were compared, and the composition of the synthetic products was investigated. The content of the zeolite component was found to be critical to the cracking and isomerization activity of the catalysts. It was further shown that the ratio between the active components correlates with the C 5+ productivity and the selectivity towards fuel-range hydrocarbons. The catalysts with Co–Al 2 O 3 /SiO 2 to HBeta ratios of 0.75 and 1.3 were found to be optimal for high-performance synthesis of gasoline-range (C 5 –C 10 ) and diesel-range (C 11 –C 18 ) hydrocarbons, respectively.
ISSN:0965-5441
1555-6239
DOI:10.1134/S0965544123060063