Performic acid—dichloromethane system as chemoselective reagent in the synthesis of 29-nor-20-O-formyl derivatives of betulin

A comparative study of the chemical behavior of performic acid in chloroform and methylene chloride revealed that the HCOOH—H 2 O 2 —CH 2 Cl 2 system ensured effective and chemoselective synthesis of 29- nor -20- O -formyl derivatives of betulin.

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Bibliographic Details
Published in:Russian chemical bulletin 2023-10, Vol.72 (10), p.2484-2491
Main Authors: Yakovleva, M. P., Sayakhov, R. R., Nugumanov, T. R., Medvedeva, N. I., Ishmuratova, N. M., Ishmuratov, G. Yu
Format: Article
Language:English
Subjects:
Chemistry
Chemistry and Materials Science
Chemistry/Food Science
Chloroform
Comparative studies
Dichloromethane
Full Articles
Hydrogen peroxide
Inorganic Chemistry
Organic Chemistry
Reagents
Synthesis
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Description
Summary:A comparative study of the chemical behavior of performic acid in chloroform and methylene chloride revealed that the HCOOH—H 2 O 2 —CH 2 Cl 2 system ensured effective and chemoselective synthesis of 29- nor -20- O -formyl derivatives of betulin.
ISSN:1066-5285
1573-9171
DOI:10.1007/s11172-023-4050-4