Simply accessible platinum() complexes enabling alkene hydrosilylation at ppm catalyst loadings

An efficient olefin hydrosilylation protocol utilising Pt( ii )-thioether-based pre-catalysts is reported. These simple and readily available complexes exhibit excellent catalytic performance and offer significant advantages over existing alternatives, enabling rapid and high conversions at ppm-leve...

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Bibliographic Details
Published in:Chemical communications (Cambridge, England) England), 2023-11, Vol.59 (94), p.1417-142
Main Authors: Maliszewski, Benon P, Casillo, Eleonora, Lambert, Perrine, Nahra, Fady, Cazin, Catherine S. J, Nolan, Steven P
Format: Article
Language:English
Subjects:
Catalysts
Hydrosilylation
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Summary:An efficient olefin hydrosilylation protocol utilising Pt( ii )-thioether-based pre-catalysts is reported. These simple and readily available complexes exhibit excellent catalytic performance and offer significant advantages over existing alternatives, enabling rapid and high conversions at ppm-level catalyst loadings. An efficient olefin hydrosilylation protocol utilising Pt( ii )-thioether-based pre-catalysts is reported.
ISSN:1359-7345
1364-548X
DOI:10.1039/d3cc05033e