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Synthesis of a Novel Dinuclear Ruthenium(III) Ono Pincer Complex Containing a M–M Bond: an XRD Study
A novel dinuclear ruthenium(III) ONO pincer complex was synthesized from RuCl 3 ·H 2 O and 2,6-pyridinedicarboxylic acid (H 2 pydc) in methanol by using triethylamine as a base. The single crystal XRD disclosed the crystalline nature of the complex that was found to be monoclinic, space group P 121/...
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| Published in: | Journal of structural chemistry 2023-11, Vol.64 (11), p.2082-2089 |
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| Main Authors: | , , , , |
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| container_end_page | 2089 |
| container_issue | 11 |
| container_start_page | 2082 |
| container_title | Journal of structural chemistry |
| container_volume | 64 |
| creator | Jerome, P. Swaminathan, S. Bhuvanesh, N. S. P. Oh, T. H. Karvembu, R. |
| description | A novel dinuclear ruthenium(III) ONO pincer complex was synthesized from RuCl
3
·H
2
O and 2,6-pyridinedicarboxylic acid (H
2
pydc) in methanol by using triethylamine as a base. The single crystal XRD disclosed the crystalline nature of the complex that was found to be monoclinic, space group
P
121/
c
1, with unit cell dimensions
a
= 9.4603(7) Å,
b
= 16.4025(12) Å,
c
= 6.6844(5) Å, β = 91.839(2)°. The complex showed a rare
transoid
configuration ′Ru(μ-OMe)
2
(μ-O
2
CN)
2
Ru′ core along with monodentate aqua ligand coordination. To the best of our knowledge, this is a rare case of bridged dinuclear ruthenium complex (only a couple of reports) and the first one containing a pincer ligand. |
| doi_str_mv | 10.1134/S0022476623110057 |
| format | article |
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3
·H
2
O and 2,6-pyridinedicarboxylic acid (H
2
pydc) in methanol by using triethylamine as a base. The single crystal XRD disclosed the crystalline nature of the complex that was found to be monoclinic, space group
P
121/
c
1, with unit cell dimensions
a
= 9.4603(7) Å,
b
= 16.4025(12) Å,
c
= 6.6844(5) Å, β = 91.839(2)°. The complex showed a rare
transoid
configuration ′Ru(μ-OMe)
2
(μ-O
2
CN)
2
Ru′ core along with monodentate aqua ligand coordination. To the best of our knowledge, this is a rare case of bridged dinuclear ruthenium complex (only a couple of reports) and the first one containing a pincer ligand.</description><identifier>ISSN: 0022-4766</identifier><identifier>EISSN: 1573-8779</identifier><identifier>DOI: 10.1134/S0022476623110057</identifier><language>eng</language><publisher>Moscow: Pleiades Publishing</publisher><subject>Atomic ; Atomic/Molecular Structure and Spectra ; Chemistry ; Chemistry and Materials Science ; Inorganic Chemistry ; Ligands ; Molecular ; Optical and Plasma Physics ; Physical Chemistry ; Ruthenium compounds ; Ruthenium trichloride ; Single crystals ; Solid State Physics ; Triethylamine ; Unit cell</subject><ispartof>Journal of structural chemistry, 2023-11, Vol.64 (11), p.2082-2089</ispartof><rights>Pleiades Publishing, Ltd. 2023</rights><rights>Pleiades Publishing, Ltd. 2023.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><cites>FETCH-LOGICAL-c268t-14ecbcd3089765bf99aaa14eec41a1099e77d5ccbcfd352d41680a499917eb233</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,776,780,27903,27904</link.rule.ids></links><search><creatorcontrib>Jerome, P.</creatorcontrib><creatorcontrib>Swaminathan, S.</creatorcontrib><creatorcontrib>Bhuvanesh, N. S. P.</creatorcontrib><creatorcontrib>Oh, T. H.</creatorcontrib><creatorcontrib>Karvembu, R.</creatorcontrib><title>Synthesis of a Novel Dinuclear Ruthenium(III) Ono Pincer Complex Containing a M–M Bond: an XRD Study</title><title>Journal of structural chemistry</title><addtitle>J Struct Chem</addtitle><description>A novel dinuclear ruthenium(III) ONO pincer complex was synthesized from RuCl
3
·H
2
O and 2,6-pyridinedicarboxylic acid (H
2
pydc) in methanol by using triethylamine as a base. The single crystal XRD disclosed the crystalline nature of the complex that was found to be monoclinic, space group
P
121/
c
1, with unit cell dimensions
a
= 9.4603(7) Å,
b
= 16.4025(12) Å,
c
= 6.6844(5) Å, β = 91.839(2)°. The complex showed a rare
transoid
configuration ′Ru(μ-OMe)
2
(μ-O
2
CN)
2
Ru′ core along with monodentate aqua ligand coordination. To the best of our knowledge, this is a rare case of bridged dinuclear ruthenium complex (only a couple of reports) and the first one containing a pincer ligand.</description><subject>Atomic</subject><subject>Atomic/Molecular Structure and Spectra</subject><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Inorganic Chemistry</subject><subject>Ligands</subject><subject>Molecular</subject><subject>Optical and Plasma Physics</subject><subject>Physical Chemistry</subject><subject>Ruthenium compounds</subject><subject>Ruthenium trichloride</subject><subject>Single crystals</subject><subject>Solid State Physics</subject><subject>Triethylamine</subject><subject>Unit cell</subject><issn>0022-4766</issn><issn>1573-8779</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2023</creationdate><recordtype>article</recordtype><recordid>eNp1kMtKAzEYhYMoWKsP4C7gRhejuUwmE3faehlorbQK7oY0k6lTpkmbzIjd-Q6-oU9iSgUX4urAf75zfjgAHGN0jjGNLyYIERLzJCEUY4QY3wEdzDiNUs7FLuhs7Gjj74MD7-cIIZGKpAPKydo0r9pXHtoSSvhg33QN-5VpVa2lg-M2uKZqF6dZlp3BkbHwsTJKO9izi2Wt34OaRlamMrMQH359fA7htTXFJZQGvoz7cNK0xfoQ7JWy9vroR7vg-fbmqXcfDUZ3We9qECmSpE2EY62mqqAoFTxh01IIKWU4ahVjiZEQmvOCqcCUBWWkiHGSIhkLITDXU0JpF5xse5fOrlrtm3xuW2fCy5ykglEcCyYChbeUctZ7p8t86aqFdOsco3wzZ_5nzpAh24wPrJlp99v8f-gbAyt17g</recordid><startdate>20231101</startdate><enddate>20231101</enddate><creator>Jerome, P.</creator><creator>Swaminathan, S.</creator><creator>Bhuvanesh, N. S. P.</creator><creator>Oh, T. H.</creator><creator>Karvembu, R.</creator><general>Pleiades Publishing</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>20231101</creationdate><title>Synthesis of a Novel Dinuclear Ruthenium(III) Ono Pincer Complex Containing a M–M Bond: an XRD Study</title><author>Jerome, P. ; Swaminathan, S. ; Bhuvanesh, N. S. P. ; Oh, T. H. ; Karvembu, R.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c268t-14ecbcd3089765bf99aaa14eec41a1099e77d5ccbcfd352d41680a499917eb233</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2023</creationdate><topic>Atomic</topic><topic>Atomic/Molecular Structure and Spectra</topic><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>Inorganic Chemistry</topic><topic>Ligands</topic><topic>Molecular</topic><topic>Optical and Plasma Physics</topic><topic>Physical Chemistry</topic><topic>Ruthenium compounds</topic><topic>Ruthenium trichloride</topic><topic>Single crystals</topic><topic>Solid State Physics</topic><topic>Triethylamine</topic><topic>Unit cell</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Jerome, P.</creatorcontrib><creatorcontrib>Swaminathan, S.</creatorcontrib><creatorcontrib>Bhuvanesh, N. S. P.</creatorcontrib><creatorcontrib>Oh, T. H.</creatorcontrib><creatorcontrib>Karvembu, R.</creatorcontrib><collection>CrossRef</collection><jtitle>Journal of structural chemistry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Jerome, P.</au><au>Swaminathan, S.</au><au>Bhuvanesh, N. S. P.</au><au>Oh, T. H.</au><au>Karvembu, R.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Synthesis of a Novel Dinuclear Ruthenium(III) Ono Pincer Complex Containing a M–M Bond: an XRD Study</atitle><jtitle>Journal of structural chemistry</jtitle><stitle>J Struct Chem</stitle><date>2023-11-01</date><risdate>2023</risdate><volume>64</volume><issue>11</issue><spage>2082</spage><epage>2089</epage><pages>2082-2089</pages><issn>0022-4766</issn><eissn>1573-8779</eissn><abstract>A novel dinuclear ruthenium(III) ONO pincer complex was synthesized from RuCl
3
·H
2
O and 2,6-pyridinedicarboxylic acid (H
2
pydc) in methanol by using triethylamine as a base. The single crystal XRD disclosed the crystalline nature of the complex that was found to be monoclinic, space group
P
121/
c
1, with unit cell dimensions
a
= 9.4603(7) Å,
b
= 16.4025(12) Å,
c
= 6.6844(5) Å, β = 91.839(2)°. The complex showed a rare
transoid
configuration ′Ru(μ-OMe)
2
(μ-O
2
CN)
2
Ru′ core along with monodentate aqua ligand coordination. To the best of our knowledge, this is a rare case of bridged dinuclear ruthenium complex (only a couple of reports) and the first one containing a pincer ligand.</abstract><cop>Moscow</cop><pub>Pleiades Publishing</pub><doi>10.1134/S0022476623110057</doi><tpages>8</tpages></addata></record> |
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| identifier | ISSN: 0022-4766 |
| ispartof | Journal of structural chemistry, 2023-11, Vol.64 (11), p.2082-2089 |
| issn | 0022-4766 1573-8779 |
| language | eng |
| recordid | cdi_proquest_journals_2895314959 |
| source | Springer Nature |
| subjects | Atomic Atomic/Molecular Structure and Spectra Chemistry Chemistry and Materials Science Inorganic Chemistry Ligands Molecular Optical and Plasma Physics Physical Chemistry Ruthenium compounds Ruthenium trichloride Single crystals Solid State Physics Triethylamine Unit cell |
| title | Synthesis of a Novel Dinuclear Ruthenium(III) Ono Pincer Complex Containing a M–M Bond: an XRD Study |
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