Rücktitelbild: Mixed‐Valence CuI/CuIII Metal–Organic Frameworks with Non‐innocent Ligand for Multielectron Transfer (Angew. Chem. 50/2023)

Two novel Cu(I)/Cu(III) mixed‐valence metal–organic frameworks (MOFs) are synthesized from Cu(II) and redox‐non‐innocent ligand 1,4‐dicyano‐2,3,5,6‐tetrahydroxybenzene, as reported by Watchareeya Kaveevivitchai, Teng‐Hao Chen et al. in their Research Article (e202312494). The coordination between th...

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Bibliographic Details
Published in:Angewandte Chemie 2023-12, Vol.135 (50), p.n/a
Main Authors: Fu, Shang‐Yuan, Chang, Cheng‐Han, Ivanov, Alexander S., Popovs, Ilja, Chen, Jeng‐Lung, Liao, Yen‐Fa, Liu, Hsin‐Kuan, Chirra, Suman, Chiang, Yun‐Wei, Lee, Jui‐Chin, Liu, Wei‐Ling, Kaveevivitchai, Watchareeya, Chen, Teng‐Hao
Format: Article
Language:English
Subjects:
Charge transfer
Chemistry
Copper
Cu(I)/Cu(III)
Ligands
Metal-organic frameworks
Metals
Mixed-Valence
Non-innocent Ligand
Redox Chemistry
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Summary:Two novel Cu(I)/Cu(III) mixed‐valence metal–organic frameworks (MOFs) are synthesized from Cu(II) and redox‐non‐innocent ligand 1,4‐dicyano‐2,3,5,6‐tetrahydroxybenzene, as reported by Watchareeya Kaveevivitchai, Teng‐Hao Chen et al. in their Research Article (e202312494). The coordination between the mixed‐valence metal and redox‐non‐innocent ligand promotes through‐bond charge transfer between Cu metal sites, leading to semiconducting behavior and multielectron transfer.
ISSN:0044-8249
1521-3757
DOI:10.1002/ange.202315461