Composites produced from waste plastic with agricultural and energy sector by‐products

• Published in: Journal of applied polymer science 2024-01, Vol.141 (3), p.n/a
• Main Authors: Lopez, Claudia V., Smith, Rhett C.
• Format: Article
• Language: English
• Subjects: Agricultural wastes; Animal fat; brown grease; Composite materials; Compressive strength; Energy industry; Esterification; Fatty acids; Glycolysis; Greases; inverse vulcanization; Mechanical properties; Mixtures; Polyethylene terephthalate; Portland cements; Residential buildings; Sulfur; sustainable composites; triglyceride; Vulcanization
• ISSN: 0021-8995; 1097-4628
• DOI: 10.1002/app.54828

A three‐stage route to chemically upcycle post‐consumer poly(ethylene terephthalate) (PET) to produce high compressive strength composites is reported. This procedure involves initial glycolysis with diethylene glycol to produce a mixture (GPET) comprising oligomers of 2–7 terephthalate units followed by trans/esterification of GPET with fatty acid chains supplied by brown grease, an agricultural by‐product of animal fat of relatively low nutritional or fuel value. This process yields PGB comprising a mixture of mono‐terephthalate ester derivatives. The olefin units provided by unsaturated fatty acid chains in brown grease were crosslinked by an inverse vulcanization reaction with elemental sulfur to give composites GBSx (x = wt% S, varied from 80%–90%). The compressive strengths of GBS80 (27.5 ± 2.6 MPa) and GBS90 (19.2 ± 0.8 MPa) exceed the compressive strength required of ordinary Portland cement (17 MPa) for its use in residential building foundations. The current route represents a way to repurpose waste plastic, energy sector by‐product sulfur, and agricultural by‐product brown grease to give high strength composites with mechanical properties suggesting their possible use to replace less sustainably sourced legacy structural materials.