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Study of Hydrolysis of Nitrile Derivatives of closo-Dodecaborate Anion (Et4N)[B12H11N≡C–R] (R = Me, Et, nPr, iPr)
The reaction of nitrile derivatives of closo -dodecaborate anion (Et 4 N)[B 12 H 11 N≡C–R] (R = Me, Et, n Pr, i Pr) with water has yielded a series of (Et 4 N)[B 12 H 11 NH=C(OH)–R] iminols. It has been demonstrated that the hydrolysis products are in acid–base iminol–amide equilibrium, which can be...
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| Published in: | Russian journal of inorganic chemistry 2023-06, Vol.68 (6), p.684-689 |
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| Main Authors: | , , , , , , , |
| Format: | Article |
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| cites | cdi_FETCH-LOGICAL-c316t-af48822b42044a78c5d32525513ce39e3118f4dffc9c022b7a7d079a5f711c213 |
| container_end_page | 689 |
| container_issue | 6 |
| container_start_page | 684 |
| container_title | Russian journal of inorganic chemistry |
| container_volume | 68 |
| creator | Nelyubin, A. V. Klyukvin, I. N. Selivanov, N. A. Bykov, A. Yu Kubasov, A. S. Zhdanov, A. P. Zhizhin, K. Yu Kuznetsov, N. T. |
| description | The reaction of nitrile derivatives of
closo
-dodecaborate anion (Et
4
N)[B
12
H
11
N≡C–R] (R = Me, Et,
n
Pr,
i
Pr) with water has yielded a series of (Et
4
N)[B
12
H
11
NH=C(OH)–R] iminols. It has been demonstrated that the hydrolysis products are in acid–base iminol–amide equilibrium, which can be controlled by changing the pH of a medium. The reaction products have been identified by
11
В,
1
Н,
13
С NMR, IR spectroscopy, and ESI mass spectrometry. The structures of the [B
12
H
11
(
Z
-NH=C(OH)
n
C
3
H
7
)]
−
and [B
12
H
11
(
E
-NH–C(O)
n
C
3
H
7
)]
2−
anions have been determined by X-ray single-crystal diffraction. |
| doi_str_mv | 10.1134/S003602362360048X |
| format | article |
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closo
-dodecaborate anion (Et
4
N)[B
12
H
11
N≡C–R] (R = Me, Et,
n
Pr,
i
Pr) with water has yielded a series of (Et
4
N)[B
12
H
11
NH=C(OH)–R] iminols. It has been demonstrated that the hydrolysis products are in acid–base iminol–amide equilibrium, which can be controlled by changing the pH of a medium. The reaction products have been identified by
11
В,
1
Н,
13
С NMR, IR spectroscopy, and ESI mass spectrometry. The structures of the [B
12
H
11
(
Z
-NH=C(OH)
n
C
3
H
7
)]
−
and [B
12
H
11
(
E
-NH–C(O)
n
C
3
H
7
)]
2−
anions have been determined by X-ray single-crystal diffraction.</description><identifier>ISSN: 0036-0236</identifier><identifier>EISSN: 1531-8613</identifier><identifier>DOI: 10.1134/S003602362360048X</identifier><language>eng</language><publisher>Moscow: Pleiades Publishing</publisher><subject>Anions ; Chemistry ; Chemistry and Materials Science ; Hydrolysis ; Infrared spectroscopy ; Inorganic Chemistry ; Mass spectrometry ; NMR ; Nuclear magnetic resonance ; Reaction products ; Single crystals ; Synthesis and Properties of Inorganic Compounds</subject><ispartof>Russian journal of inorganic chemistry, 2023-06, Vol.68 (6), p.684-689</ispartof><rights>Pleiades Publishing, Ltd. 2023. ISSN 0036-0236, Russian Journal of Inorganic Chemistry, 2023, Vol. 68, No. 6, pp. 684–689. © Pleiades Publishing, Ltd., 2023. ISSN 0036-0236, Russian Journal of Inorganic Chemistry, 2023. © Pleiades Publishing, Ltd., 2023. Russian Text © The Author(s), 2023, published in Zhurnal Neorganicheskoi Khimii, 2023, Vol. 68, No. 6, pp. 768–773.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c316t-af48822b42044a78c5d32525513ce39e3118f4dffc9c022b7a7d079a5f711c213</citedby><cites>FETCH-LOGICAL-c316t-af48822b42044a78c5d32525513ce39e3118f4dffc9c022b7a7d079a5f711c213</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,778,782,27907,27908</link.rule.ids></links><search><creatorcontrib>Nelyubin, A. V.</creatorcontrib><creatorcontrib>Klyukvin, I. N.</creatorcontrib><creatorcontrib>Selivanov, N. A.</creatorcontrib><creatorcontrib>Bykov, A. Yu</creatorcontrib><creatorcontrib>Kubasov, A. S.</creatorcontrib><creatorcontrib>Zhdanov, A. P.</creatorcontrib><creatorcontrib>Zhizhin, K. Yu</creatorcontrib><creatorcontrib>Kuznetsov, N. T.</creatorcontrib><title>Study of Hydrolysis of Nitrile Derivatives of closo-Dodecaborate Anion (Et4N)[B12H11N≡C–R] (R = Me, Et, nPr, iPr)</title><title>Russian journal of inorganic chemistry</title><addtitle>Russ. J. Inorg. Chem</addtitle><description>The reaction of nitrile derivatives of
closo
-dodecaborate anion (Et
4
N)[B
12
H
11
N≡C–R] (R = Me, Et,
n
Pr,
i
Pr) with water has yielded a series of (Et
4
N)[B
12
H
11
NH=C(OH)–R] iminols. It has been demonstrated that the hydrolysis products are in acid–base iminol–amide equilibrium, which can be controlled by changing the pH of a medium. The reaction products have been identified by
11
В,
1
Н,
13
С NMR, IR spectroscopy, and ESI mass spectrometry. The structures of the [B
12
H
11
(
Z
-NH=C(OH)
n
C
3
H
7
)]
−
and [B
12
H
11
(
E
-NH–C(O)
n
C
3
H
7
)]
2−
anions have been determined by X-ray single-crystal diffraction.</description><subject>Anions</subject><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Hydrolysis</subject><subject>Infrared spectroscopy</subject><subject>Inorganic Chemistry</subject><subject>Mass spectrometry</subject><subject>NMR</subject><subject>Nuclear magnetic resonance</subject><subject>Reaction products</subject><subject>Single crystals</subject><subject>Synthesis and Properties of Inorganic Compounds</subject><issn>0036-0236</issn><issn>1531-8613</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2023</creationdate><recordtype>article</recordtype><recordid>eNp1kM9KAzEQxoMoWKsP4C3gpYWuZpL9e_BQ22qFWkurIIgsaTYrW-qmJruFvXn17BP4an0Ss1bwIMLAMDO_75thEDoGcgrA3LMZIcwnlPk2CHHDhx3UAI-BE_rAdlGjHjv1fB8dGLOwiEuCsIHKWVEmFVYpHlaJVsvKZKauxlmhs6XEfamzNS-ytfxui6UyyumrRAo-V5oXEnfzTOW4NSjccfvxAugQYLx5_-xt3j6mT7g1xef4RnbwoOjgfKI7OJvo9iHaS_nSyKOf3ET3l4O73tAZ3V5d97ojRzDwC4enbhhSOnepPZcHofASRj3qecCEZJFkAGHqJmkqIkEsF_AgIUHEvTQAEBRYE51sfVdavZbSFPFClTq3K2MaEYgYtclSsKWEVsZomcYrnb1wXcVA4vq78Z_vWg3daoxl82epf53_F30BpYd5hA</recordid><startdate>20230601</startdate><enddate>20230601</enddate><creator>Nelyubin, A. V.</creator><creator>Klyukvin, I. N.</creator><creator>Selivanov, N. A.</creator><creator>Bykov, A. Yu</creator><creator>Kubasov, A. S.</creator><creator>Zhdanov, A. P.</creator><creator>Zhizhin, K. Yu</creator><creator>Kuznetsov, N. T.</creator><general>Pleiades Publishing</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>20230601</creationdate><title>Study of Hydrolysis of Nitrile Derivatives of closo-Dodecaborate Anion (Et4N)[B12H11N≡C–R] (R = Me, Et, nPr, iPr)</title><author>Nelyubin, A. V. ; Klyukvin, I. N. ; Selivanov, N. A. ; Bykov, A. Yu ; Kubasov, A. S. ; Zhdanov, A. P. ; Zhizhin, K. Yu ; Kuznetsov, N. T.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c316t-af48822b42044a78c5d32525513ce39e3118f4dffc9c022b7a7d079a5f711c213</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2023</creationdate><topic>Anions</topic><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>Hydrolysis</topic><topic>Infrared spectroscopy</topic><topic>Inorganic Chemistry</topic><topic>Mass spectrometry</topic><topic>NMR</topic><topic>Nuclear magnetic resonance</topic><topic>Reaction products</topic><topic>Single crystals</topic><topic>Synthesis and Properties of Inorganic Compounds</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Nelyubin, A. V.</creatorcontrib><creatorcontrib>Klyukvin, I. N.</creatorcontrib><creatorcontrib>Selivanov, N. A.</creatorcontrib><creatorcontrib>Bykov, A. Yu</creatorcontrib><creatorcontrib>Kubasov, A. S.</creatorcontrib><creatorcontrib>Zhdanov, A. P.</creatorcontrib><creatorcontrib>Zhizhin, K. Yu</creatorcontrib><creatorcontrib>Kuznetsov, N. T.</creatorcontrib><collection>CrossRef</collection><jtitle>Russian journal of inorganic chemistry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Nelyubin, A. V.</au><au>Klyukvin, I. N.</au><au>Selivanov, N. A.</au><au>Bykov, A. Yu</au><au>Kubasov, A. S.</au><au>Zhdanov, A. P.</au><au>Zhizhin, K. Yu</au><au>Kuznetsov, N. T.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Study of Hydrolysis of Nitrile Derivatives of closo-Dodecaborate Anion (Et4N)[B12H11N≡C–R] (R = Me, Et, nPr, iPr)</atitle><jtitle>Russian journal of inorganic chemistry</jtitle><stitle>Russ. J. Inorg. Chem</stitle><date>2023-06-01</date><risdate>2023</risdate><volume>68</volume><issue>6</issue><spage>684</spage><epage>689</epage><pages>684-689</pages><issn>0036-0236</issn><eissn>1531-8613</eissn><abstract>The reaction of nitrile derivatives of
closo
-dodecaborate anion (Et
4
N)[B
12
H
11
N≡C–R] (R = Me, Et,
n
Pr,
i
Pr) with water has yielded a series of (Et
4
N)[B
12
H
11
NH=C(OH)–R] iminols. It has been demonstrated that the hydrolysis products are in acid–base iminol–amide equilibrium, which can be controlled by changing the pH of a medium. The reaction products have been identified by
11
В,
1
Н,
13
С NMR, IR spectroscopy, and ESI mass spectrometry. The structures of the [B
12
H
11
(
Z
-NH=C(OH)
n
C
3
H
7
)]
−
and [B
12
H
11
(
E
-NH–C(O)
n
C
3
H
7
)]
2−
anions have been determined by X-ray single-crystal diffraction.</abstract><cop>Moscow</cop><pub>Pleiades Publishing</pub><doi>10.1134/S003602362360048X</doi><tpages>6</tpages></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 0036-0236 |
| ispartof | Russian journal of inorganic chemistry, 2023-06, Vol.68 (6), p.684-689 |
| issn | 0036-0236 1531-8613 |
| language | eng |
| recordid | cdi_proquest_journals_2901932290 |
| source | Springer Nature |
| subjects | Anions Chemistry Chemistry and Materials Science Hydrolysis Infrared spectroscopy Inorganic Chemistry Mass spectrometry NMR Nuclear magnetic resonance Reaction products Single crystals Synthesis and Properties of Inorganic Compounds |
| title | Study of Hydrolysis of Nitrile Derivatives of closo-Dodecaborate Anion (Et4N)[B12H11N≡C–R] (R = Me, Et, nPr, iPr) |
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