Loading…
Synthesis and Physicochemical Properties of Yttrium Subgroup REE Lactates Ln(C3H5O3)3·2H2O (Ln = Y, Tb–Lu)
A series of yttrium subgroup rare earth elements (REE) lactates of [Ln(C 3 H 5 O 3 ) 3 (H 2 O) 2 ] (Ln = Tb–Lu) composition isostructural to yttrium lactate has been prepared for the first time. Synthesis of crystalline REE lactates has been performed from solutions of REE nitrates in the presence o...
Saved in:
| Published in: | Russian journal of inorganic chemistry 2023-10, Vol.68 (10), p.1414-1424 |
|---|---|
| Main Authors: | , , , , , |
| Format: | Article |
| Language: | English |
| Subjects: | |
| Citations: | Items that this one cites |
| Online Access: | Get full text |
| Tags: |
Add Tag
No Tags, Be the first to tag this record!
|
| cited_by | |
|---|---|
| cites | cdi_FETCH-LOGICAL-c1830-19e568231be84731e52986992421a382047c139c0445f90cba5ba515024d0c193 |
| container_end_page | 1424 |
| container_issue | 10 |
| container_start_page | 1414 |
| container_title | Russian journal of inorganic chemistry |
| container_volume | 68 |
| creator | Golikova, M. V. Yapryntsev, A. D. Jia, Z. Fatyushina, E. V. Baranchikov, A. E. Ivanov, V. K. |
| description | A series of yttrium subgroup rare earth elements (REE) lactates of [Ln(C
3
H
5
O
3
)
3
(H
2
O)
2
] (Ln = Tb–Lu) composition isostructural to yttrium lactate has been prepared for the first time. Synthesis of crystalline REE lactates has been performed from solutions of REE nitrates in the presence of L-lactic acid and hexamethylenetetramine. The composition and structure of the obtained compounds have been confirmed by X-ray powder diffraction, thermal, and chemical (CHN) analysis. The coordination type of lactate anions to REE cations has been determined by IR spectroscopy. Thermal decomposition of REE lactates at 800°C leads to formation of nanocrystalline (20–40 nm) REE (Y, Tb–Lu) oxides. |
| doi_str_mv | 10.1134/S0036023623601800 |
| format | article |
| fullrecord | <record><control><sourceid>proquest_cross</sourceid><recordid>TN_cdi_proquest_journals_2902508464</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>2902508464</sourcerecordid><originalsourceid>FETCH-LOGICAL-c1830-19e568231be84731e52986992421a382047c139c0445f90cba5ba515024d0c193</originalsourceid><addsrcrecordid>eNp1kM1Kw0AUhQdRsFYfwN2AmxaM3jszSScLF1KqFQItti66Csl00qY0P84ki-58Bx_GvY_ikzilggsRLtzF-c653EPIJcINIhe3MwAeAOOBG0AJcEQ66HP0ZID8mHT2srfXT8mZtRsAIWAgO6SY7cpmrW1uaVIu6XS9s7mq1FoXuUq2dGqqWpsm15ZWGV00jcnbgs7adGWqtqbPoxGNEtUkjQOisjfkY3_C-_zzg43ZhPaikt7RxTWdp19v71HbPycnWbK1-uJnd8nLw2g-HHvR5PFpeB95CiUHD0PtB5JxTLUUA47aZ6EMwpAJhgmXDMRAIQ-Ve8LPQlBp4rtBH5hYgsKQd8nVIbc21WurbRNvqtaU7mTMQmA-SBEIR-GBUqay1ugsrk1eJGYXI8T7VuM_rToPO3isY8uVNr_J_5u-AZsDdWc</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>2902508464</pqid></control><display><type>article</type><title>Synthesis and Physicochemical Properties of Yttrium Subgroup REE Lactates Ln(C3H5O3)3·2H2O (Ln = Y, Tb–Lu)</title><source>Springer Link</source><creator>Golikova, M. V. ; Yapryntsev, A. D. ; Jia, Z. ; Fatyushina, E. V. ; Baranchikov, A. E. ; Ivanov, V. K.</creator><creatorcontrib>Golikova, M. V. ; Yapryntsev, A. D. ; Jia, Z. ; Fatyushina, E. V. ; Baranchikov, A. E. ; Ivanov, V. K.</creatorcontrib><description>A series of yttrium subgroup rare earth elements (REE) lactates of [Ln(C
3
H
5
O
3
)
3
(H
2
O)
2
] (Ln = Tb–Lu) composition isostructural to yttrium lactate has been prepared for the first time. Synthesis of crystalline REE lactates has been performed from solutions of REE nitrates in the presence of L-lactic acid and hexamethylenetetramine. The composition and structure of the obtained compounds have been confirmed by X-ray powder diffraction, thermal, and chemical (CHN) analysis. The coordination type of lactate anions to REE cations has been determined by IR spectroscopy. Thermal decomposition of REE lactates at 800°C leads to formation of nanocrystalline (20–40 nm) REE (Y, Tb–Lu) oxides.</description><identifier>ISSN: 0036-0236</identifier><identifier>EISSN: 1531-8613</identifier><identifier>DOI: 10.1134/S0036023623601800</identifier><language>eng</language><publisher>Moscow: Pleiades Publishing</publisher><subject>Chemistry ; Chemistry and Materials Science ; Composition ; Coordination Compounds ; Hexamethylenetetramine ; Infrared spectroscopy ; Inorganic Chemistry ; Lactates ; Lactic acid ; Rare earth elements ; Subgroups ; Synthesis ; Thermal decomposition ; X ray powder diffraction ; Yttrium</subject><ispartof>Russian journal of inorganic chemistry, 2023-10, Vol.68 (10), p.1414-1424</ispartof><rights>Pleiades Publishing, Ltd. 2023. ISSN 0036-0236, Russian Journal of Inorganic Chemistry, 2023, Vol. 68, No. 10, pp. 1414–1424. © Pleiades Publishing, Ltd., 2023. ISSN 0036-0236, Russian Journal of Inorganic Chemistry, 2023. © Pleiades Publishing, Ltd., 2023. Russian Text © The Author(s), 2023, published in Zhurnal Neorganicheskoi Khimii, 2023, Vol. 68, No. 10, pp. 1422–1432.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><cites>FETCH-LOGICAL-c1830-19e568231be84731e52986992421a382047c139c0445f90cba5ba515024d0c193</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,780,784,27924,27925</link.rule.ids></links><search><creatorcontrib>Golikova, M. V.</creatorcontrib><creatorcontrib>Yapryntsev, A. D.</creatorcontrib><creatorcontrib>Jia, Z.</creatorcontrib><creatorcontrib>Fatyushina, E. V.</creatorcontrib><creatorcontrib>Baranchikov, A. E.</creatorcontrib><creatorcontrib>Ivanov, V. K.</creatorcontrib><title>Synthesis and Physicochemical Properties of Yttrium Subgroup REE Lactates Ln(C3H5O3)3·2H2O (Ln = Y, Tb–Lu)</title><title>Russian journal of inorganic chemistry</title><addtitle>Russ. J. Inorg. Chem</addtitle><description>A series of yttrium subgroup rare earth elements (REE) lactates of [Ln(C
3
H
5
O
3
)
3
(H
2
O)
2
] (Ln = Tb–Lu) composition isostructural to yttrium lactate has been prepared for the first time. Synthesis of crystalline REE lactates has been performed from solutions of REE nitrates in the presence of L-lactic acid and hexamethylenetetramine. The composition and structure of the obtained compounds have been confirmed by X-ray powder diffraction, thermal, and chemical (CHN) analysis. The coordination type of lactate anions to REE cations has been determined by IR spectroscopy. Thermal decomposition of REE lactates at 800°C leads to formation of nanocrystalline (20–40 nm) REE (Y, Tb–Lu) oxides.</description><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Composition</subject><subject>Coordination Compounds</subject><subject>Hexamethylenetetramine</subject><subject>Infrared spectroscopy</subject><subject>Inorganic Chemistry</subject><subject>Lactates</subject><subject>Lactic acid</subject><subject>Rare earth elements</subject><subject>Subgroups</subject><subject>Synthesis</subject><subject>Thermal decomposition</subject><subject>X ray powder diffraction</subject><subject>Yttrium</subject><issn>0036-0236</issn><issn>1531-8613</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2023</creationdate><recordtype>article</recordtype><recordid>eNp1kM1Kw0AUhQdRsFYfwN2AmxaM3jszSScLF1KqFQItti66Csl00qY0P84ki-58Bx_GvY_ikzilggsRLtzF-c653EPIJcINIhe3MwAeAOOBG0AJcEQ66HP0ZID8mHT2srfXT8mZtRsAIWAgO6SY7cpmrW1uaVIu6XS9s7mq1FoXuUq2dGqqWpsm15ZWGV00jcnbgs7adGWqtqbPoxGNEtUkjQOisjfkY3_C-_zzg43ZhPaikt7RxTWdp19v71HbPycnWbK1-uJnd8nLw2g-HHvR5PFpeB95CiUHD0PtB5JxTLUUA47aZ6EMwpAJhgmXDMRAIQ-Ve8LPQlBp4rtBH5hYgsKQd8nVIbc21WurbRNvqtaU7mTMQmA-SBEIR-GBUqay1ugsrk1eJGYXI8T7VuM_rToPO3isY8uVNr_J_5u-AZsDdWc</recordid><startdate>20231001</startdate><enddate>20231001</enddate><creator>Golikova, M. V.</creator><creator>Yapryntsev, A. D.</creator><creator>Jia, Z.</creator><creator>Fatyushina, E. V.</creator><creator>Baranchikov, A. E.</creator><creator>Ivanov, V. K.</creator><general>Pleiades Publishing</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>20231001</creationdate><title>Synthesis and Physicochemical Properties of Yttrium Subgroup REE Lactates Ln(C3H5O3)3·2H2O (Ln = Y, Tb–Lu)</title><author>Golikova, M. V. ; Yapryntsev, A. D. ; Jia, Z. ; Fatyushina, E. V. ; Baranchikov, A. E. ; Ivanov, V. K.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c1830-19e568231be84731e52986992421a382047c139c0445f90cba5ba515024d0c193</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2023</creationdate><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>Composition</topic><topic>Coordination Compounds</topic><topic>Hexamethylenetetramine</topic><topic>Infrared spectroscopy</topic><topic>Inorganic Chemistry</topic><topic>Lactates</topic><topic>Lactic acid</topic><topic>Rare earth elements</topic><topic>Subgroups</topic><topic>Synthesis</topic><topic>Thermal decomposition</topic><topic>X ray powder diffraction</topic><topic>Yttrium</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Golikova, M. V.</creatorcontrib><creatorcontrib>Yapryntsev, A. D.</creatorcontrib><creatorcontrib>Jia, Z.</creatorcontrib><creatorcontrib>Fatyushina, E. V.</creatorcontrib><creatorcontrib>Baranchikov, A. E.</creatorcontrib><creatorcontrib>Ivanov, V. K.</creatorcontrib><collection>CrossRef</collection><jtitle>Russian journal of inorganic chemistry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Golikova, M. V.</au><au>Yapryntsev, A. D.</au><au>Jia, Z.</au><au>Fatyushina, E. V.</au><au>Baranchikov, A. E.</au><au>Ivanov, V. K.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Synthesis and Physicochemical Properties of Yttrium Subgroup REE Lactates Ln(C3H5O3)3·2H2O (Ln = Y, Tb–Lu)</atitle><jtitle>Russian journal of inorganic chemistry</jtitle><stitle>Russ. J. Inorg. Chem</stitle><date>2023-10-01</date><risdate>2023</risdate><volume>68</volume><issue>10</issue><spage>1414</spage><epage>1424</epage><pages>1414-1424</pages><issn>0036-0236</issn><eissn>1531-8613</eissn><abstract>A series of yttrium subgroup rare earth elements (REE) lactates of [Ln(C
3
H
5
O
3
)
3
(H
2
O)
2
] (Ln = Tb–Lu) composition isostructural to yttrium lactate has been prepared for the first time. Synthesis of crystalline REE lactates has been performed from solutions of REE nitrates in the presence of L-lactic acid and hexamethylenetetramine. The composition and structure of the obtained compounds have been confirmed by X-ray powder diffraction, thermal, and chemical (CHN) analysis. The coordination type of lactate anions to REE cations has been determined by IR spectroscopy. Thermal decomposition of REE lactates at 800°C leads to formation of nanocrystalline (20–40 nm) REE (Y, Tb–Lu) oxides.</abstract><cop>Moscow</cop><pub>Pleiades Publishing</pub><doi>10.1134/S0036023623601800</doi><tpages>11</tpages></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 0036-0236 |
| ispartof | Russian journal of inorganic chemistry, 2023-10, Vol.68 (10), p.1414-1424 |
| issn | 0036-0236 1531-8613 |
| language | eng |
| recordid | cdi_proquest_journals_2902508464 |
| source | Springer Link |
| subjects | Chemistry Chemistry and Materials Science Composition Coordination Compounds Hexamethylenetetramine Infrared spectroscopy Inorganic Chemistry Lactates Lactic acid Rare earth elements Subgroups Synthesis Thermal decomposition X ray powder diffraction Yttrium |
| title | Synthesis and Physicochemical Properties of Yttrium Subgroup REE Lactates Ln(C3H5O3)3·2H2O (Ln = Y, Tb–Lu) |
| url | http://sfxeu10.hosted.exlibrisgroup.com/loughborough?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2024-12-21T02%3A55%3A11IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest_cross&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Synthesis%20and%20Physicochemical%20Properties%20of%20Yttrium%20Subgroup%20REE%20Lactates%20Ln(C3H5O3)3%C2%B72H2O%20(Ln%20=%20Y,%20Tb%E2%80%93Lu)&rft.jtitle=Russian%20journal%20of%20inorganic%20chemistry&rft.au=Golikova,%20M.%20V.&rft.date=2023-10-01&rft.volume=68&rft.issue=10&rft.spage=1414&rft.epage=1424&rft.pages=1414-1424&rft.issn=0036-0236&rft.eissn=1531-8613&rft_id=info:doi/10.1134/S0036023623601800&rft_dat=%3Cproquest_cross%3E2902508464%3C/proquest_cross%3E%3Cgrp_id%3Ecdi_FETCH-LOGICAL-c1830-19e568231be84731e52986992421a382047c139c0445f90cba5ba515024d0c193%3C/grp_id%3E%3Coa%3E%3C/oa%3E%3Curl%3E%3C/url%3E&rft_id=info:oai/&rft_pqid=2902508464&rft_id=info:pmid/&rfr_iscdi=true |