Synthesis and Structure of New Potassium and Cesium Zinc Diphosphates

This article presents the results of a study of new solid solutions formed in the system of diphosphates of alkaline elements and zinc: K 2 Zn 3 (P 2 O 7 ) 2 –Cs 2 Zn 3 (P 2 O 7 ) 2 . The obtained materials are promising as matrices for creating phosphors. The formation of phases containing two alka...

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Bibliographic Details
Published in:Glass physics and chemistry 2023-12, Vol.49 (6), p.657-663
Main Authors: Tsygankova, D. I., Sinel’shchikova, O. Yu, Ugolkov, V. L.
Format: Article
Language:English
Subjects:
Ceramics
Cesium
Characterization and Evaluation of Materials
Chemistry and Materials Science
Composites
Diphosphates
Glass
Materials Science
Natural Materials
Phosphors
Physical Chemistry
Solid phase synthesis
Solid solutions
Stability analysis
Thermal stability
Zinc
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Summary:This article presents the results of a study of new solid solutions formed in the system of diphosphates of alkaline elements and zinc: K 2 Zn 3 (P 2 O 7 ) 2 –Cs 2 Zn 3 (P 2 O 7 ) 2 . The obtained materials are promising as matrices for creating phosphors. The formation of phases containing two alkali cations is established on samples obtained by solid-phase synthesis by X-ray phase analysis, and the results of studying their thermal stability are presented.
ISSN:1087-6596
1608-313X
DOI:10.1134/S1087659623600643