Synthesis of hydrogels from fractionated proteins of Moringa oleifera Lam. seeds for the treatment of water contaminated with black reactive dye 5

• Published in: Canadian journal of chemical engineering 2024-02, Vol.102 (2), p.685-702
• Main Authors: Freitas Resende, Jayana, Reck Paulino, Isabela Maria, Reis Oliveira, Marina, Ferri, Bruna Bruguer, Bergamasco, Rosângela, Guilherme, Marcos R., Rinaldi, Andrelson W., Vieira, Angélica Marquetotti Salcedo
• Format: Article
• Language: English
• Subjects: Adsorbents; Adsorption; Albumins; CI Reactive Black 5; Coagulants; Dyes; hydrogel; Hydrogels; Moringa oleifera Lam. proteins; Multilayers; Proteins; reactive black 5 dye; Synthesis; Water treatment
• ISSN: 0008-4034; 1939-019X
• DOI: 10.1002/cjce.25088

As has been portrayed in the literature, the main proteins extracted from the seeds of Moringa oleifera Lam. have coagulant and clarifying potential in water treatment. However, when using them as coagulant agents, sludge formation occurs, which is an environmental problem. Thus, it was proposed to synthesize hydrogels from the main Moringa seeds proteins and use them as adsorbents. This work aimed to synthesize albumin hydrogels and globulin hydrogels and evaluate their efficiency as adsorbents to remove the reactive black 5 dye. Through FTIR spectrum it was possible to confirm that the synthesis of hydrogels occurred successfully. The kinetic data fit the pseudo‐second order model for both hydrogels. The equilibrium isotherms showed that adsorption occurs in multilayers, due to Freundlich fitting. The maximum adsorption capacity occurred at 298 K and was 1.19 mg g−1 for the albumin hydrogel and 10.06 mg g−1 for the globulin hydrogel. Through the results it is possible to state that globulin hydrogel was more favourable for adsorption since it has a more porous morphology and requires less mass compared to albumin hydrogel.