Cover Picture: Dynamic Stereochemistry of M8Pd6 Supramolecular Cages Based on Metal‐Center Lability for Differential Chiral Induction, Resolution, and Recognition (Angew. Chem. Int. Ed. 2/2024)

A fruitful stereochemical scenario of metal‐organic cages (MOCs) is demonstrated by Cheng‐Yong Su et al. in their Research Article (e202315053). Based on the intrinsic dynamics of different metal ions, it is shown how the dynamic stereochemistry of the cages is correlated with the coordination labil...

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Bibliographic Details
Published in:Angewandte Chemie International Edition 2024-01, Vol.63 (2), p.n/a
Main Authors: Huang, Yin‐Hui, Lu, Yu‐Lin, Zhang, Xiao‐Dong, Liu, Chen‐Hui, Ruan, Jia, Qin, Yu‐Han, Cao, Zhong‐Min, Jiang, Jijun, Xu, Hai‐Sen, Su, Cheng‐Yong
Format: Article
Language:English
Subjects:
Cages
Chiral Induction
Chiral Recognition
Coordination Cage
Host-Guest Chemistry
Lability
Metal ions
Metals
Recognition
Spontaneous Resolution
Stereochemistry
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Summary:A fruitful stereochemical scenario of metal‐organic cages (MOCs) is demonstrated by Cheng‐Yong Su et al. in their Research Article (e202315053). Based on the intrinsic dynamics of different metal ions, it is shown how the dynamic stereochemistry of the cages is correlated with the coordination lability of the metal centers, and how their chiral induction, resolution and recognition behaviors can be maneuvered through multiple guest interactions, which may enable rational design, control and application of chiral‐MOC containers.
ISSN:1433-7851
1521-3773
DOI:10.1002/anie.202317913