Hydrophilic Surface Modification of Poly(methyl methacrylate)/Poly(methyl methacrylate‐co‐acrylic acid) Composite Film by Surface Activation

• Published in: Macromolecular chemistry and physics 2024-01, Vol.225 (1), p.n/a
• Main Authors: Sun, Xin, Hu, Keling, Wang, Kai, Su, Chengkun, Wang, Rui, Ma, Zhengfeng
• Format: Article
• Language: English
• Subjects: Acrylic acid; Caustic soda; composite films; Contact angle; Copolymers; Functional groups; Hydrogen bonding; Hydrogen bonds; Hydrophilic surfaces; Hydrophilicity; Infrared absorption; Metal-metal bonding; poly(methyl methacrylate); poly(methyl methacrylate‐co‐acrylic acid); Polymethyl methacrylate; Sodium; Sodium hydroxide; Surface activation; Surface chemistry; Surface roughness; Surface structure; Thermal stability
• ISSN: 1022-1352; 1521-3935
• DOI: 10.1002/macp.202300312

Focusing on hydrophilic surface modification of poly(methyl methacrylate)/poly(methyl methacrylate‐co‐acrylic acid) (PMMA/PMMA‐co‐PAA) composite film, a copolymer is synthesized to improve the hydrophilicity and compatibility with PMMA matrix, and the composite film is subjected to surface activation using a sodium hydroxide solution. The infrared absorption peaks corresponding to –OH and –C═O functional groups become progressively weaker with the increase of copolymer content, indicating the formation of intermolecular hydrogen bonds. The hydroxyl absorption peak is significant and two new absorption peaks corresponding to the symmetric contraction and antisymmetric contraction of –COO– appear, indicating that sodium hydroxide solution can disrupt the intermolecular hydrogen bond and react with acrylic acid to form sodium acrylate to make the surface contain sodium elements. The elemental sodium content on the composite film can reach 1.9% and the nanostructures contain 20 times more sodium than the smooth parts, indicating the sodium acrylate can induce surface segregation of PMMA and form nanoparticle‐like structures to improve surface roughness. The hydrophilic component combined with the surface structure makes the contact angle less than 10°. Furthermore, thermostability can be slightly promoted by introducing the copolymer which is closely related to the intermolecular hydrogen bonding formed directly between the copolymer and the PMMA matrix. This project successfully constructs a hydrophilic PMMA/PMMA‐co‐PAA composite film surface by solution blending and surface activation methods. Compared to classical hydrophilic modification approaches such as coatings and plasma treatments, direct mixing of PMMA with hydrophilic copolymer solutions and surface activation with sodium hydroxide solutions is a simpler method and it is a promising method for hydrophilic modification.