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Biogenic ZnO/CuO/Fe2O3 Nanocomposite: A Groundbreaking Approach for Enhanced Degradation Capabilities and Reusability in Dye Removal Applications
We present the successful synthesis of a biogenic ZnO/CuO/Fe 2 O 3 nanocomposite using an aqueous leaf extract of Ocimum Basilicum L . The confirmation of biosynthesis was achieved through UV–Visible spectrophotometry (UV–Vis), which provided evidence of ZnO/CuO/Fe 2 O 3 NC formation. Scanning Elect...
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| Published in: | Arabian journal for science and engineering (2011) 2024, Vol.49 (1), p.753-764 |
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| Main Authors: | , , , , , , , , , |
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| cites | cdi_FETCH-LOGICAL-c363t-55637252acd491062bb0d16cdfabd7b99e1089d4ae83847eb082e4601109bbb73 |
| container_end_page | 764 |
| container_issue | 1 |
| container_start_page | 753 |
| container_title | Arabian journal for science and engineering (2011) |
| container_volume | 49 |
| creator | Serouti, Abdelghani Eddine, Laouini Salah Meneceur, Souhaila Hasan, Gamil Gamal Mohammed, Hamdi Ali Salmi, Chaima Iman, Kir Ferhat, Mohammed Fouad Ali, Ouarda Ben Abdullah, Johar Amin Ahmed |
| description | We present the successful synthesis of a biogenic ZnO/CuO/Fe
2
O
3
nanocomposite using an aqueous leaf extract of
Ocimum Basilicum L
. The confirmation of biosynthesis was achieved through UV–Visible spectrophotometry (UV–Vis), which provided evidence of ZnO/CuO/Fe
2
O
3
NC formation. Scanning Electron Microscopy further confirmed the nanoscale size of the NC, measuring at 65 nm. X-Ray Diffraction analysis revealed a hexagonal structure for ZnO and a monoclinic structure for CuO. The successful synthesis of the environmentally friendly ZnO/CuO/Fe
2
O
3
NC was further verified using Fourier transformed infrared (FT-IR) spectroscopy, which identified the functional groups present in the composite. Notably, the ZnO/CuO/Fe
2
O
3
NC demonstrated exceptional degradation capabilities for toluidine blue (TB), p-toluidine (PT), and m-Toluidine (MT), with degradation rates of 99%, 99.1%, and 99.7%, respectively, within a reaction time of 120 min. The reaction kinetics followed a pseudo-first order model, with rate constant (k) values of 0.0314 min
−1
and 0.0189 min
−1
for TB and PT, respectively. This high rate of dye degradation can be attributed to the low band gap of the NC, which was determined to be 1.44 eV for the indirect bandgap. Furthermore, the nanocomposite exhibited excellent degradation reusability, maintaining a high degradation rate in each cycle. |
| doi_str_mv | 10.1007/s13369-023-08495-0 |
| format | article |
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2
O
3
nanocomposite using an aqueous leaf extract of
Ocimum Basilicum L
. The confirmation of biosynthesis was achieved through UV–Visible spectrophotometry (UV–Vis), which provided evidence of ZnO/CuO/Fe
2
O
3
NC formation. Scanning Electron Microscopy further confirmed the nanoscale size of the NC, measuring at 65 nm. X-Ray Diffraction analysis revealed a hexagonal structure for ZnO and a monoclinic structure for CuO. The successful synthesis of the environmentally friendly ZnO/CuO/Fe
2
O
3
NC was further verified using Fourier transformed infrared (FT-IR) spectroscopy, which identified the functional groups present in the composite. Notably, the ZnO/CuO/Fe
2
O
3
NC demonstrated exceptional degradation capabilities for toluidine blue (TB), p-toluidine (PT), and m-Toluidine (MT), with degradation rates of 99%, 99.1%, and 99.7%, respectively, within a reaction time of 120 min. The reaction kinetics followed a pseudo-first order model, with rate constant (k) values of 0.0314 min
−1
and 0.0189 min
−1
for TB and PT, respectively. This high rate of dye degradation can be attributed to the low band gap of the NC, which was determined to be 1.44 eV for the indirect bandgap. Furthermore, the nanocomposite exhibited excellent degradation reusability, maintaining a high degradation rate in each cycle.</description><identifier>ISSN: 2193-567X</identifier><identifier>ISSN: 1319-8025</identifier><identifier>EISSN: 2191-4281</identifier><identifier>DOI: 10.1007/s13369-023-08495-0</identifier><language>eng</language><publisher>Berlin/Heidelberg: Springer Berlin Heidelberg</publisher><subject>Biosynthesis ; Degradation ; Dyes ; Energy gap ; Engineering ; Functional groups ; Humanities and Social Sciences ; Infrared spectroscopy ; multidisciplinary ; Nanocomposites ; Reaction kinetics ; Research Article-Chemistry ; Science ; Spectrophotometry ; Toluidine blue ; Zinc oxide</subject><ispartof>Arabian journal for science and engineering (2011), 2024, Vol.49 (1), p.753-764</ispartof><rights>The Author(s) 2023</rights><rights>The Author(s) 2023. This work is published under http://creativecommons.org/licenses/by/4.0/ (the “License”). Notwithstanding the ProQuest Terms and Conditions, you may use this content in accordance with the terms of the License.</rights><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c363t-55637252acd491062bb0d16cdfabd7b99e1089d4ae83847eb082e4601109bbb73</citedby><cites>FETCH-LOGICAL-c363t-55637252acd491062bb0d16cdfabd7b99e1089d4ae83847eb082e4601109bbb73</cites><orcidid>0000-0002-5923-8254</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,780,784,27924,27925</link.rule.ids></links><search><creatorcontrib>Serouti, Abdelghani</creatorcontrib><creatorcontrib>Eddine, Laouini Salah</creatorcontrib><creatorcontrib>Meneceur, Souhaila</creatorcontrib><creatorcontrib>Hasan, Gamil Gamal</creatorcontrib><creatorcontrib>Mohammed, Hamdi Ali</creatorcontrib><creatorcontrib>Salmi, Chaima</creatorcontrib><creatorcontrib>Iman, Kir</creatorcontrib><creatorcontrib>Ferhat, Mohammed Fouad</creatorcontrib><creatorcontrib>Ali, Ouarda Ben</creatorcontrib><creatorcontrib>Abdullah, Johar Amin Ahmed</creatorcontrib><title>Biogenic ZnO/CuO/Fe2O3 Nanocomposite: A Groundbreaking Approach for Enhanced Degradation Capabilities and Reusability in Dye Removal Applications</title><title>Arabian journal for science and engineering (2011)</title><addtitle>Arab J Sci Eng</addtitle><description>We present the successful synthesis of a biogenic ZnO/CuO/Fe
2
O
3
nanocomposite using an aqueous leaf extract of
Ocimum Basilicum L
. The confirmation of biosynthesis was achieved through UV–Visible spectrophotometry (UV–Vis), which provided evidence of ZnO/CuO/Fe
2
O
3
NC formation. Scanning Electron Microscopy further confirmed the nanoscale size of the NC, measuring at 65 nm. X-Ray Diffraction analysis revealed a hexagonal structure for ZnO and a monoclinic structure for CuO. The successful synthesis of the environmentally friendly ZnO/CuO/Fe
2
O
3
NC was further verified using Fourier transformed infrared (FT-IR) spectroscopy, which identified the functional groups present in the composite. Notably, the ZnO/CuO/Fe
2
O
3
NC demonstrated exceptional degradation capabilities for toluidine blue (TB), p-toluidine (PT), and m-Toluidine (MT), with degradation rates of 99%, 99.1%, and 99.7%, respectively, within a reaction time of 120 min. The reaction kinetics followed a pseudo-first order model, with rate constant (k) values of 0.0314 min
−1
and 0.0189 min
−1
for TB and PT, respectively. This high rate of dye degradation can be attributed to the low band gap of the NC, which was determined to be 1.44 eV for the indirect bandgap. Furthermore, the nanocomposite exhibited excellent degradation reusability, maintaining a high degradation rate in each cycle.</description><subject>Biosynthesis</subject><subject>Degradation</subject><subject>Dyes</subject><subject>Energy gap</subject><subject>Engineering</subject><subject>Functional groups</subject><subject>Humanities and Social Sciences</subject><subject>Infrared spectroscopy</subject><subject>multidisciplinary</subject><subject>Nanocomposites</subject><subject>Reaction kinetics</subject><subject>Research Article-Chemistry</subject><subject>Science</subject><subject>Spectrophotometry</subject><subject>Toluidine blue</subject><subject>Zinc oxide</subject><issn>2193-567X</issn><issn>1319-8025</issn><issn>2191-4281</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2024</creationdate><recordtype>article</recordtype><recordid>eNp9kEtLAzEUhQdRsKh_wFXA9di85hF3tVoVxIIoiJuQx20bbZMxmRH6M_zHjh3Bnat7OZzvXO7JslOCzwnG1TgRxkqRY8pyXHNR5HgvG1EiSM5pTfZ3O8uLsno5zE5SchrzmomCEDbKvi5dWIJ3Br36-XjazcczoHOGHpQPJmyakFwLF2iCbmLovNUR1LvzSzRpmhiUWaFFiOjar5Q3YNEVLKOyqnXBo6lqlHZr1zpISHmLHqFLg7JFzqOrLfTSJnyq9U_a2pkdl46zg4VaJzj5nUfZ8-z6aXqb389v7qaT-9ywkrV5UZSsogVVxnJBcEm1xpaUxi6UtpUWAgiuheUKalbzCjSuKfASE4KF1rpiR9nZkNs_8tFBauVb6KLvT0oqCKswJ4L3Ljq4TAwpRVjIJrqNiltJsPxpXw7ty759uWtf4h5iA5R6s19C_Iv-h_oGBrqIlw</recordid><startdate>2024</startdate><enddate>2024</enddate><creator>Serouti, Abdelghani</creator><creator>Eddine, Laouini Salah</creator><creator>Meneceur, Souhaila</creator><creator>Hasan, Gamil Gamal</creator><creator>Mohammed, Hamdi Ali</creator><creator>Salmi, Chaima</creator><creator>Iman, Kir</creator><creator>Ferhat, Mohammed Fouad</creator><creator>Ali, Ouarda Ben</creator><creator>Abdullah, Johar Amin Ahmed</creator><general>Springer Berlin Heidelberg</general><general>Springer Nature B.V</general><scope>C6C</scope><scope>AAYXX</scope><scope>CITATION</scope><orcidid>https://orcid.org/0000-0002-5923-8254</orcidid></search><sort><creationdate>2024</creationdate><title>Biogenic ZnO/CuO/Fe2O3 Nanocomposite: A Groundbreaking Approach for Enhanced Degradation Capabilities and Reusability in Dye Removal Applications</title><author>Serouti, Abdelghani ; Eddine, Laouini Salah ; Meneceur, Souhaila ; Hasan, Gamil Gamal ; Mohammed, Hamdi Ali ; Salmi, Chaima ; Iman, Kir ; Ferhat, Mohammed Fouad ; Ali, Ouarda Ben ; Abdullah, Johar Amin Ahmed</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c363t-55637252acd491062bb0d16cdfabd7b99e1089d4ae83847eb082e4601109bbb73</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2024</creationdate><topic>Biosynthesis</topic><topic>Degradation</topic><topic>Dyes</topic><topic>Energy gap</topic><topic>Engineering</topic><topic>Functional groups</topic><topic>Humanities and Social Sciences</topic><topic>Infrared spectroscopy</topic><topic>multidisciplinary</topic><topic>Nanocomposites</topic><topic>Reaction kinetics</topic><topic>Research Article-Chemistry</topic><topic>Science</topic><topic>Spectrophotometry</topic><topic>Toluidine blue</topic><topic>Zinc oxide</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Serouti, Abdelghani</creatorcontrib><creatorcontrib>Eddine, Laouini Salah</creatorcontrib><creatorcontrib>Meneceur, Souhaila</creatorcontrib><creatorcontrib>Hasan, Gamil Gamal</creatorcontrib><creatorcontrib>Mohammed, Hamdi Ali</creatorcontrib><creatorcontrib>Salmi, Chaima</creatorcontrib><creatorcontrib>Iman, Kir</creatorcontrib><creatorcontrib>Ferhat, Mohammed Fouad</creatorcontrib><creatorcontrib>Ali, Ouarda Ben</creatorcontrib><creatorcontrib>Abdullah, Johar Amin Ahmed</creatorcontrib><collection>Springer Nature OA Free Journals</collection><collection>CrossRef</collection><jtitle>Arabian journal for science and engineering (2011)</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Serouti, Abdelghani</au><au>Eddine, Laouini Salah</au><au>Meneceur, Souhaila</au><au>Hasan, Gamil Gamal</au><au>Mohammed, Hamdi Ali</au><au>Salmi, Chaima</au><au>Iman, Kir</au><au>Ferhat, Mohammed Fouad</au><au>Ali, Ouarda Ben</au><au>Abdullah, Johar Amin Ahmed</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Biogenic ZnO/CuO/Fe2O3 Nanocomposite: A Groundbreaking Approach for Enhanced Degradation Capabilities and Reusability in Dye Removal Applications</atitle><jtitle>Arabian journal for science and engineering (2011)</jtitle><stitle>Arab J Sci Eng</stitle><date>2024</date><risdate>2024</risdate><volume>49</volume><issue>1</issue><spage>753</spage><epage>764</epage><pages>753-764</pages><issn>2193-567X</issn><issn>1319-8025</issn><eissn>2191-4281</eissn><abstract>We present the successful synthesis of a biogenic ZnO/CuO/Fe
2
O
3
nanocomposite using an aqueous leaf extract of
Ocimum Basilicum L
. The confirmation of biosynthesis was achieved through UV–Visible spectrophotometry (UV–Vis), which provided evidence of ZnO/CuO/Fe
2
O
3
NC formation. Scanning Electron Microscopy further confirmed the nanoscale size of the NC, measuring at 65 nm. X-Ray Diffraction analysis revealed a hexagonal structure for ZnO and a monoclinic structure for CuO. The successful synthesis of the environmentally friendly ZnO/CuO/Fe
2
O
3
NC was further verified using Fourier transformed infrared (FT-IR) spectroscopy, which identified the functional groups present in the composite. Notably, the ZnO/CuO/Fe
2
O
3
NC demonstrated exceptional degradation capabilities for toluidine blue (TB), p-toluidine (PT), and m-Toluidine (MT), with degradation rates of 99%, 99.1%, and 99.7%, respectively, within a reaction time of 120 min. The reaction kinetics followed a pseudo-first order model, with rate constant (k) values of 0.0314 min
−1
and 0.0189 min
−1
for TB and PT, respectively. This high rate of dye degradation can be attributed to the low band gap of the NC, which was determined to be 1.44 eV for the indirect bandgap. Furthermore, the nanocomposite exhibited excellent degradation reusability, maintaining a high degradation rate in each cycle.</abstract><cop>Berlin/Heidelberg</cop><pub>Springer Berlin Heidelberg</pub><doi>10.1007/s13369-023-08495-0</doi><tpages>12</tpages><orcidid>https://orcid.org/0000-0002-5923-8254</orcidid><oa>free_for_read</oa></addata></record> |
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| issn | 2193-567X 1319-8025 2191-4281 |
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| subjects | Biosynthesis Degradation Dyes Energy gap Engineering Functional groups Humanities and Social Sciences Infrared spectroscopy multidisciplinary Nanocomposites Reaction kinetics Research Article-Chemistry Science Spectrophotometry Toluidine blue Zinc oxide |
| title | Biogenic ZnO/CuO/Fe2O3 Nanocomposite: A Groundbreaking Approach for Enhanced Degradation Capabilities and Reusability in Dye Removal Applications |
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