Calcium alginate film with excellent shape memory effect

• Published in: Pigment & resin technology 2024-01, Vol.53 (2), p.133-136
• Main Authors: Wang, Wenjun, Shen, Luting, Si, Yinsong, MD Zahidul, Islam, Abdullaev, Azim, Dong, Yubing
• Format: Article
• Language: English
• Subjects: Biodegradation; Calcium alginate; Calcium chloride; Conflicts of interest; Crosslinking; Mechanical properties; Performance degradation; Phase transitions; Polysaccharides; Shape effects; Shape memory; Smart materials; Sodium; Sodium alginate; Soil mechanics; Soil testing; Temperature; Textiles; Thin films
• ISSN: 0369-9420; 1758-6941; 0369-9420
• DOI: 10.1108/PRT-03-2022-0034

Purpose Sodium alginate (Na-Alg) is a natural polysaccharide with a rich and renewable production that is widely used in the food, pharmaceutical and daily necessities industries, among other fields. The purpose of this study is to obtain a green and degradable shape memory material, calcium alginate (Ca-Alg) film was prepared and the mechanical properties, the shape memory effect of the film were investigated and confirmed. Design/methodology/approach The Ca-Alg films were prepared by Na-Alg, calcium chloride (CaCl2) solution, and flow extension method. Dissolve sodium alginate powder, remove bubbles, pour into petri dish, dry at 60°C, add calcium chloride solution cross-linking and finally dry naturally. The effect of CaCl2 solution concentration on the mechanical properties of the films were investigated and discussed by universal tensile tester. The shape memory behavior and degradation performance of thin films were verified and studied by the fold-deploy shape memory test and soil embedding method, respectively. Findings The Ca-Alg films exhibited good mechanical and shape memory properties, with a 72.2% shape memory fixity ratio and a 92.3% shape memory recovery ratio, respectively. For a period of 120 days, the film treated with a 6 wt% CaCl2 solution degraded at a rate of approximately 53%. Research limitations/implications Shape memory polymers (SMPs) as intelligent materials are an important research direction for the development of modern high-tech materials. On the other hand, plastic pollution is a major problem today; as a result, preparing green degradable SMPs is essential. Originality/value This study synthesized transparent and degradable shape memory Ca-Alg films using Na-Alg and CaCl2 solution and the flow extension method.