Hydrothermal conversion of cerium oxalate to CeO2: a parade of oxalate and water coordination modes

Hydrothemal conversion of lanthanide/actinide oxalate salts to nanocrystalline oxide has gained technological importance in the chemistry of f-elements. Herein, we present a study describing the mechanism behind the hydrothermal recrystallization and decomposition of cerium (and Ce-Gd) oxalate to ox...

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Published in:New journal of chemistry 2024-01, Vol.48 (3), p.1071-1075
Main Authors: Assi, Navid, Lahoud, Christophe, Brázda, Petr, Zákutná, Dominika, Rainer, Daniel N, Hraníček, Jakub, Rohlíček, Jan, Tyrpekl, Václav
Format: Article
Language:English
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Cerium oxides
Electron diffraction
Gadolinium
Recrystallization
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container_end_page 1075
container_issue 3
container_start_page 1071
container_title New journal of chemistry
container_volume 48
creator Assi, Navid
Lahoud, Christophe
Brázda, Petr
Zákutná, Dominika
Rainer, Daniel N
Hraníček, Jakub
Rohlíček, Jan
Tyrpekl, Václav
description Hydrothemal conversion of lanthanide/actinide oxalate salts to nanocrystalline oxide has gained technological importance in the chemistry of f-elements. Herein, we present a study describing the mechanism behind the hydrothermal recrystallization and decomposition of cerium (and Ce-Gd) oxalate to oxide. Structural determination of all intermediate nanocrystalline products was possible thanks to three-dimensional electron diffraction. This work reveals the enormous structural abilities of simple oxalate ligands.
doi_str_mv 10.1039/d3nj04635d
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source Royal Society of Chemistry:Jisc Collections:Royal Society of Chemistry Read and Publish 2022-2024 (reading list)
subjects Cerium oxides
Electron diffraction
Gadolinium
Recrystallization
title Hydrothermal conversion of cerium oxalate to CeO2: a parade of oxalate and water coordination modes
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