Reactivity of Radical Anions and Dianions of Organic Compounds: A Review

The results of experimental and theoretical studies of reactions involving π*-radical anions and π*‑dianions are analyzed. Particular attention is paid to their role in electrochemical reduction processes. By the example of three most typical reactions for these particles, the main factors determini...

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Bibliographic Details
Published in:Russian journal of electrochemistry 2023-12, Vol.59 (12), p.999-1031
Main Authors: Mendkovich, A. S., Rusakov, A. I.
Format: Article
Language:English
Subjects:
Anions
Chemical reduction
Chemistry
Chemistry and Materials Science
Electrochemistry
Organic compounds
Physical Chemistry
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Summary:The results of experimental and theoretical studies of reactions involving π*-radical anions and π*‑dianions are analyzed. Particular attention is paid to their role in electrochemical reduction processes. By the example of three most typical reactions for these particles, the main factors determining their reactivity are considered.
ISSN:1023-1935
1608-3342
DOI:10.1134/S1023193523120078