Hydrogenation of CO2 on Co–Ni Catalysts Produced by Low-Temperature Combustion Using Modified Silica Fabric

• Published in: International journal of self-propagating high-temperature synthesis 2023-12, Vol.32 (4), p.302-312
• Main Authors: Borshch, V. N., Bystrova, I. M., Pugacheva, E. V., Khomenko, N. Yu
• Format: Article
• Language: English
• Subjects: Aluminum nitrate; Aluminum oxide; Carbon dioxide; Catalysts; Catalytic activity; Chemistry and Materials Science; Cobalt; Combustion; Low temperature; Materials Science; Mixtures; Nickel; Nitrates; Silicon dioxide; Ureas
• ISSN: 1061-3862; 1934-788X
• DOI: 10.3103/S1061386223040131

Co–Ni supported catalysts were prepared by low-temperature combustion of dried mixture of solutions of cobalt and nickel nitrates and urea after impregnation of silica fabric (>97% SiO 2 ) premodified with 5, 10, and 15 wt % Al 2 O 3 . Modification of support was carried out by low-temperature combustion of dried mixture of solutions of aluminum nitrate and urea. Prepared supports and related catalysts were characterized by XRD, SEM, EDS, and BET method. The unreduced catalysts were found to contain oxides and complex oxides of nickel and cobalt. Reduction of catalysts with hydrogen at 400°C for 1 h was shown to contribute to forming metallic phases of Co and Ni; however, the nickel phase was detected only in reduced catalyst on unmodified fabric. The catalytic activity of catalysts was determined in the temperature range of 150–400°С. It was found that the reduced catalyst on support modified with 5 wt % Al 2 O 3 possesses the highest CO 2 conversion (61.8%) and methane yield (3.61 vol %) at 400°С.