Preparation and characterization of quaternary bacterial cellulose composites for antimicrobial oil‐absorbing materials

• Published in: Journal of applied polymer science 2024-03, Vol.141 (9)
• Main Authors: Men, Ying, Yang, Ruiting, Yang, Xubing, Qin, Ziyu, Yin, Xueqiong
• Format: Article
• Language: English
• Subjects: Absorption; Cellulose; Composite materials; Contact angle; E coli; Environmental protection; Hydrophobicity; Hydroxyl groups; Mechanical properties; Process parameters; Structural analysis; Wastewater treatment
• ISSN: 0021-8995; 1097-4628
• DOI: 10.1002/app.55022

The treatment of various types of oily wastewater is paramount for environmental protection. Bacterial cellulose (BC) stands out as a highly promising material for oil/water separation, owing to its exceptional mechanical properties and three‐dimensional porous structures. However, excessive hydroxyl groups on BC make it highly hydrophilic, reducing oil absorption and promoting bacterial growth, affecting its stability. To address these challenges, we developed a straightforward in situ polymerization method for the preparation of BC‐DMC composites. The innovation lies in the concurrent enhancement of BC's hydrophobicity and antimicrobial properties only through the addition of 2‐(Methacryloyloxy)ethyltrimethylammonium chloride (DMC), considerably simplifying the synthesis of materials possessing oil‐absorbing and antimicrobial properties. Morphological and structural characterization results confirmed the successful combination of DMC onto BC while maintaining its porous structure. After process parameter optimization, the BC‐DMC composites exhibited a remarkable increase in contact angle (117.7° compared with pure BC's 19.5°). It also demonstrated excellent oil absorption performance, with maximum capacities exceeding 30 g/g for different oils, maintaining values above 20 g/g even after eight cycles. In addition, the BC‐DMC composites exhibited strong antibacterial activity, with rates of 82.4% against Escherichia coli and 97.5% against Staphylococcus aureus . The antibacterial mechanism of the BC‐DMC composites was also discussed. Our novel BC‐DMC composites provides excellent oil absorption and antibacterial properties, making it highly applicable in the field of oily wastewater treatment and serving as a valuable reference for other researchers.