Preparation of polyacetylenes via organometallic C-C coupling reactions

SummaryDehalogenative polycondensation of 1,2-dibromoethylene, trans-1,2-dichloroethylene, and cis-1,2-dichloroethylene with a Ni(0) complex gave a black polymer whose IR spectrum essentially agreed with that of trans-polyacetylene. Suzuki-Miyaura coupling between 1,2-dibromoethylene and vinylene di...

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Published in:Polymer bulletin (Berlin, Germany) Germany), 2004-11, Vol.52 (5), p.315-319
Main Authors: YAMAMOTO, Takakazu, KOBAYASHI, Kazuaki, YASUDA, Takuma, ZHOU, Zhen-Hua, YAMAGUCHI, Isao, ISHIKAWA, Tadahiko, KOSHIHARA, Shin-Ya
Format: Article
Language:English
Subjects:
Applied sciences
Chemical reactions
Chemical synthesis
Exact sciences and technology
Organic polymers
Physicochemistry of polymers
Polyacetylene
Polycondensation
Preparation, kinetics, thermodynamics, mechanism and catalysts
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cited_by cdi_FETCH-LOGICAL-c347t-3381f49d7f83e17d1a70b19ed0995c640902ebcf9ed780608f5a2896f0b87c243
cites cdi_FETCH-LOGICAL-c347t-3381f49d7f83e17d1a70b19ed0995c640902ebcf9ed780608f5a2896f0b87c243
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container_title Polymer bulletin (Berlin, Germany)
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creator YAMAMOTO, Takakazu
KOBAYASHI, Kazuaki
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KOSHIHARA, Shin-Ya
description SummaryDehalogenative polycondensation of 1,2-dibromoethylene, trans-1,2-dichloroethylene, and cis-1,2-dichloroethylene with a Ni(0) complex gave a black polymer whose IR spectrum essentially agreed with that of trans-polyacetylene. Suzuki-Miyaura coupling between 1,2-dibromoethylene and vinylene diboronic compounds was applied to synthesis of π-conjugated polymers.
doi_str_mv 10.1007/s00289-004-0291-z
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subjects Applied sciences
Chemical reactions
Chemical synthesis
Exact sciences and technology
Organic polymers
Physicochemistry of polymers
Polyacetylene
Polycondensation
Preparation, kinetics, thermodynamics, mechanism and catalysts
title Preparation of polyacetylenes via organometallic C-C coupling reactions
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