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Preparation of surfactant-free vinyl polymers by conventional emulsion polymerization using hydrolysable emulsifiers
Emulsion polymerizations of several vinyl monomers, styrene, methyl methacrylate, butyl methacrylate, butyl acrylate, and vinyl acetate, in water using alkali–hydrolysable cationic surfactants with a betaine ester group (1-alkoxycarbonylmethyl)trimethylammonium chlorides, as emulsifiers were carried...
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| Published in: | Polymer bulletin (Berlin, Germany) Germany), 2011-11, Vol.67 (8), p.1455-1462 |
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| Main Authors: | , , , , |
| Format: | Article |
| Language: | English |
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| cited_by | cdi_FETCH-LOGICAL-c470t-d852eef394c5b4a1c39fcc24aa2aecc51abeec995fb28e763329d6068a0f78a03 |
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| cites | cdi_FETCH-LOGICAL-c470t-d852eef394c5b4a1c39fcc24aa2aecc51abeec995fb28e763329d6068a0f78a03 |
| container_end_page | 1462 |
| container_issue | 8 |
| container_start_page | 1455 |
| container_title | Polymer bulletin (Berlin, Germany) |
| container_volume | 67 |
| creator | Itoh, Yoshihiro Sahara, Fumiya Ozaki, Kaori Akasaka, Ryo Teramoto, Akira |
| description | Emulsion polymerizations of several vinyl monomers, styrene, methyl methacrylate, butyl methacrylate, butyl acrylate, and vinyl acetate, in water using alkali–hydrolysable cationic surfactants with a betaine ester group (1-alkoxycarbonylmethyl)trimethylammonium chlorides, as emulsifiers were carried out and properties of the resulting latices and the polymers recovered by hydrolysis and salting out were investigated. There were little influences of the surfactants and monomers used here on the polymerizations, forming stable and monodisperse latices with a mean diameter of ca. 70 nm and giving a high molecular weight of polymers at high yields. All polymers were precipitated and recovered by adding a small amount of sodium hydroxide into the latex solutions contained little amount of ionic species. Solvent-cast films of the polymers were found to have surfaces as hydrophobic as those for the corresponding pure polymers prepared by bulk polymerization. |
| doi_str_mv | 10.1007/s00289-011-0462-7 |
| format | article |
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| identifier | ISSN: 0170-0839 |
| ispartof | Polymer bulletin (Berlin, Germany), 2011-11, Vol.67 (8), p.1455-1462 |
| issn | 0170-0839 1436-2449 |
| language | eng |
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| source | Springer Nature |
| subjects | Applied sciences Aqueous solutions Bulk polymerization Characterization and Evaluation of Materials Chemistry Chemistry and Materials Science Complex Fluids and Microfluidics Emulsifiers Emulsion polymerization Exact sciences and technology Hydrocarbons Latex Monomers Organic Chemistry Organic polymers Original Paper Particle size Physical Chemistry Physicochemistry of polymers Polymer films Polymer Sciences Polymerization Polymers Polymethyl methacrylate Preparation, kinetics, thermodynamics, mechanism and catalysts Salting Sodium hydroxide Soft and Granular Matter Spectrum analysis Surfactants Vinyl acetate Vinyl polymers Viscosity |
| title | Preparation of surfactant-free vinyl polymers by conventional emulsion polymerization using hydrolysable emulsifiers |
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