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A new approach for synthesis of SiO2/poly(2-hydroxyethyl methacrylate):Tb3+ nanohybrids by combination of surface-initiated raft polymerization and coordination chemistry
A facile strategy for growing the poly(2-hydroxyethyl methacrylate) encapsulated on the surface of SiO 2 nanoparticles (SiO 2 /PHEMA) as a molecular host matrix for the luminescent Tb 3+ via a combination of surface-initiated reversible addition fragmentation chain transfer polymerization and coordi...
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| Published in: | Polymer bulletin (Berlin, Germany) Germany), 2016-09, Vol.73 (9), p.2627-2638 |
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| Main Authors: | , , , , |
| Format: | Article |
| Language: | English |
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| cited_by | cdi_FETCH-LOGICAL-c283t-2ac0eb47225499ea772da3e28206bf93d0f6a5e7b36054f0f1c73ed45743de533 |
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| cites | cdi_FETCH-LOGICAL-c283t-2ac0eb47225499ea772da3e28206bf93d0f6a5e7b36054f0f1c73ed45743de533 |
| container_end_page | 2638 |
| container_issue | 9 |
| container_start_page | 2627 |
| container_title | Polymer bulletin (Berlin, Germany) |
| container_volume | 73 |
| creator | Bach, Long Giang Bui, Quynh Thi Phuong Cao, Xuan Thang Ho, Van Thi Thanh Lim, Kwon Taek |
| description | A facile strategy for growing the poly(2-hydroxyethyl methacrylate) encapsulated on the surface of SiO
2
nanoparticles (SiO
2
/PHEMA) as a molecular host matrix for the luminescent Tb
3+
via a combination of surface-initiated reversible addition fragmentation chain transfer polymerization and coordination chemistry was successfully developed. The structure, morphology and fluorescence properties of the materials were investigated using relevant physical and spectral techniques. The core–shell structure and uniform dispersion of SiO
2
/PHEMA and SiO
2
/PHEMA:Tb
3+
complexes were found according to SEM and TEM analyses while their surface bonding characteristics were determined via FT-IR analysis. In photoluminescence measurement, the SiO
2
/PHEMA:Tb
3+
nanoparticles showed characteristic emissions of Tb
3+
with the strongest (
5
D
4
→
7
F
5
) green emission without detectable emissions of ligands, demonstrating that SiO
2
framework covalently bonded with PHEMA segments acting as an efficient matrix for sensitization of fluorescent Tb
3+
ions. |
| doi_str_mv | 10.1007/s00289-016-1712-5 |
| format | article |
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2
nanoparticles (SiO
2
/PHEMA) as a molecular host matrix for the luminescent Tb
3+
via a combination of surface-initiated reversible addition fragmentation chain transfer polymerization and coordination chemistry was successfully developed. The structure, morphology and fluorescence properties of the materials were investigated using relevant physical and spectral techniques. The core–shell structure and uniform dispersion of SiO
2
/PHEMA and SiO
2
/PHEMA:Tb
3+
complexes were found according to SEM and TEM analyses while their surface bonding characteristics were determined via FT-IR analysis. In photoluminescence measurement, the SiO
2
/PHEMA:Tb
3+
nanoparticles showed characteristic emissions of Tb
3+
with the strongest (
5
D
4
→
7
F
5
) green emission without detectable emissions of ligands, demonstrating that SiO
2
framework covalently bonded with PHEMA segments acting as an efficient matrix for sensitization of fluorescent Tb
3+
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2
nanoparticles (SiO
2
/PHEMA) as a molecular host matrix for the luminescent Tb
3+
via a combination of surface-initiated reversible addition fragmentation chain transfer polymerization and coordination chemistry was successfully developed. The structure, morphology and fluorescence properties of the materials were investigated using relevant physical and spectral techniques. The core–shell structure and uniform dispersion of SiO
2
/PHEMA and SiO
2
/PHEMA:Tb
3+
complexes were found according to SEM and TEM analyses while their surface bonding characteristics were determined via FT-IR analysis. In photoluminescence measurement, the SiO
2
/PHEMA:Tb
3+
nanoparticles showed characteristic emissions of Tb
3+
with the strongest (
5
D
4
→
7
F
5
) green emission without detectable emissions of ligands, demonstrating that SiO
2
framework covalently bonded with PHEMA segments acting as an efficient matrix for sensitization of fluorescent Tb
3+
ions.</description><subject>Addition polymerization</subject><subject>Aqueous solutions</subject><subject>Chain transfer</subject><subject>Characterization and Evaluation of Materials</subject><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Chromatography</subject><subject>Complex Fluids and Microfluidics</subject><subject>Coordination</subject><subject>Core-shell structure</subject><subject>Emulsion polymerization</subject><subject>Ethanol</subject><subject>Fluorescence</subject><subject>Infrared analysis</subject><subject>Nanocomposites</subject><subject>Nanoparticles</subject><subject>Organic Chemistry</subject><subject>Original Paper</subject><subject>Photoluminescence</subject><subject>Physical Chemistry</subject><subject>Polyhydroxyethyl methacrylate</subject><subject>Polymer Sciences</subject><subject>Polymers</subject><subject>Silicon dioxide</subject><subject>Soft and Granular Matter</subject><subject>Spectral methods</subject><issn>0170-0839</issn><issn>1436-2449</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2016</creationdate><recordtype>article</recordtype><recordid>eNp1kU1rFTEUhoMoeG39Ae4CbhSJPUlmJjPuSvELCl20rkMmH07KneSa5KLxJ_VXmssorro6HHif98B5EHpF4T0FEBcZgI0TAToQKigj_RO0ox0fCOu66SnaARVAYOTTc_Qi53to-zDQHXq4xMH-xOpwSFHpBbuYcK6hLDb7jKPDt_6GXRzivr5hZKkmxV_VlqXu8dqG0qnuVbFvP9zN_B0OKsSlzsmbjOeKdVxnH1TxMZya8jE5pS3xwRffIIOTcgWfuleb_O8tqIJpYEzmH6kXu_pcUj1Hz5zaZ_vy7zxD3z59vLv6Qq5vPn-9urwmmo28EKY02LkTjPXdNFklBDOKWzYyGGY3cQNuUL0VMx-g7xw4qgW3putFx43tOT9Dr7fe9pIfR5uLvI_HFNpJySYqRsGBji1Ft5ROMedknTwkv6pUJQV5UiI3JbIpkSclsm8M25jcsuG7Tf-bH4f-AHn3kmY</recordid><startdate>20160901</startdate><enddate>20160901</enddate><creator>Bach, Long Giang</creator><creator>Bui, Quynh Thi Phuong</creator><creator>Cao, Xuan Thang</creator><creator>Ho, Van Thi Thanh</creator><creator>Lim, Kwon Taek</creator><general>Springer Berlin Heidelberg</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope><scope>8FE</scope><scope>8FG</scope><scope>ABJCF</scope><scope>AFKRA</scope><scope>BENPR</scope><scope>BGLVJ</scope><scope>CCPQU</scope><scope>D1I</scope><scope>DWQXO</scope><scope>HCIFZ</scope><scope>KB.</scope><scope>PDBOC</scope><scope>PQEST</scope><scope>PQQKQ</scope><scope>PQUKI</scope></search><sort><creationdate>20160901</creationdate><title>A new approach for synthesis of SiO2/poly(2-hydroxyethyl methacrylate):Tb3+ nanohybrids by combination of surface-initiated raft polymerization and coordination chemistry</title><author>Bach, Long Giang ; Bui, Quynh Thi Phuong ; Cao, Xuan Thang ; Ho, Van Thi Thanh ; Lim, Kwon Taek</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c283t-2ac0eb47225499ea772da3e28206bf93d0f6a5e7b36054f0f1c73ed45743de533</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2016</creationdate><topic>Addition polymerization</topic><topic>Aqueous solutions</topic><topic>Chain transfer</topic><topic>Characterization and Evaluation of Materials</topic><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>Chromatography</topic><topic>Complex Fluids and Microfluidics</topic><topic>Coordination</topic><topic>Core-shell structure</topic><topic>Emulsion polymerization</topic><topic>Ethanol</topic><topic>Fluorescence</topic><topic>Infrared analysis</topic><topic>Nanocomposites</topic><topic>Nanoparticles</topic><topic>Organic Chemistry</topic><topic>Original Paper</topic><topic>Photoluminescence</topic><topic>Physical Chemistry</topic><topic>Polyhydroxyethyl methacrylate</topic><topic>Polymer Sciences</topic><topic>Polymers</topic><topic>Silicon dioxide</topic><topic>Soft and Granular Matter</topic><topic>Spectral methods</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Bach, Long Giang</creatorcontrib><creatorcontrib>Bui, Quynh Thi Phuong</creatorcontrib><creatorcontrib>Cao, Xuan Thang</creatorcontrib><creatorcontrib>Ho, Van Thi Thanh</creatorcontrib><creatorcontrib>Lim, Kwon Taek</creatorcontrib><collection>CrossRef</collection><collection>ProQuest SciTech Collection</collection><collection>ProQuest Technology Collection</collection><collection>Materials Science & Engineering Collection</collection><collection>ProQuest Central</collection><collection>AUTh Library subscriptions: ProQuest Central</collection><collection>Technology Collection</collection><collection>ProQuest One Community College</collection><collection>ProQuest Materials Science Collection</collection><collection>ProQuest Central</collection><collection>SciTech Premium Collection</collection><collection>https://resources.nclive.org/materials</collection><collection>Materials Science Collection</collection><collection>ProQuest One Academic Eastern Edition (DO NOT USE)</collection><collection>ProQuest One Academic</collection><collection>ProQuest One Academic UKI Edition</collection><jtitle>Polymer bulletin (Berlin, Germany)</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Bach, Long Giang</au><au>Bui, Quynh Thi Phuong</au><au>Cao, Xuan Thang</au><au>Ho, Van Thi Thanh</au><au>Lim, Kwon Taek</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>A new approach for synthesis of SiO2/poly(2-hydroxyethyl methacrylate):Tb3+ nanohybrids by combination of surface-initiated raft polymerization and coordination chemistry</atitle><jtitle>Polymer bulletin (Berlin, Germany)</jtitle><stitle>Polym. Bull</stitle><date>2016-09-01</date><risdate>2016</risdate><volume>73</volume><issue>9</issue><spage>2627</spage><epage>2638</epage><pages>2627-2638</pages><issn>0170-0839</issn><eissn>1436-2449</eissn><abstract>A facile strategy for growing the poly(2-hydroxyethyl methacrylate) encapsulated on the surface of SiO
2
nanoparticles (SiO
2
/PHEMA) as a molecular host matrix for the luminescent Tb
3+
via a combination of surface-initiated reversible addition fragmentation chain transfer polymerization and coordination chemistry was successfully developed. The structure, morphology and fluorescence properties of the materials were investigated using relevant physical and spectral techniques. The core–shell structure and uniform dispersion of SiO
2
/PHEMA and SiO
2
/PHEMA:Tb
3+
complexes were found according to SEM and TEM analyses while their surface bonding characteristics were determined via FT-IR analysis. In photoluminescence measurement, the SiO
2
/PHEMA:Tb
3+
nanoparticles showed characteristic emissions of Tb
3+
with the strongest (
5
D
4
→
7
F
5
) green emission without detectable emissions of ligands, demonstrating that SiO
2
framework covalently bonded with PHEMA segments acting as an efficient matrix for sensitization of fluorescent Tb
3+
ions.</abstract><cop>Berlin/Heidelberg</cop><pub>Springer Berlin Heidelberg</pub><doi>10.1007/s00289-016-1712-5</doi><tpages>12</tpages></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 0170-0839 |
| ispartof | Polymer bulletin (Berlin, Germany), 2016-09, Vol.73 (9), p.2627-2638 |
| issn | 0170-0839 1436-2449 |
| language | eng |
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| source | Springer Link |
| subjects | Addition polymerization Aqueous solutions Chain transfer Characterization and Evaluation of Materials Chemistry Chemistry and Materials Science Chromatography Complex Fluids and Microfluidics Coordination Core-shell structure Emulsion polymerization Ethanol Fluorescence Infrared analysis Nanocomposites Nanoparticles Organic Chemistry Original Paper Photoluminescence Physical Chemistry Polyhydroxyethyl methacrylate Polymer Sciences Polymers Silicon dioxide Soft and Granular Matter Spectral methods |
| title | A new approach for synthesis of SiO2/poly(2-hydroxyethyl methacrylate):Tb3+ nanohybrids by combination of surface-initiated raft polymerization and coordination chemistry |
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