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Fabrication of polyurushiol/Ag composite porous films using an in situ photoreduction method
In this work, polyurushiol (PUS) was synthesized through a Friedel–Crafts reaction using brönsted acid as a catalyst. The product was then utilized in the fabrication of honeycomb porous films by breath figures (BFs). The PUS porous films were subsequently exposed to a high pressure mercury lamp for...
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| Published in: | Polymer bulletin (Berlin, Germany) Germany), 2016-06, Vol.73 (6), p.1639-1647 |
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| cites | cdi_FETCH-LOGICAL-c353t-19e31edab660eef303a8015a3e0b40fee8da2d821a1130ea0ae2eae8d20c79e83 |
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| container_issue | 6 |
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| container_title | Polymer bulletin (Berlin, Germany) |
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| creator | Wang, Donghui Zhang, Meng Luo, Zhen Bai, Weibin Xu, Yanlian Lin, Jinhuo |
| description | In this work, polyurushiol (PUS) was synthesized through a Friedel–Crafts reaction using brönsted acid as a catalyst. The product was then utilized in the fabrication of honeycomb porous films by breath figures (BFs). The PUS porous films were subsequently exposed to a high pressure mercury lamp for several seconds (5–30 s). An AgNO
3
solution was then dripped onto the surface of films to form PUS/Ag composite porous films through the in situ photoreduction method, avoiding the use of harmful reducing agents. Key preparation factors, including solvent type, UV irradiation time and AgNO
3
concentration, were systematically investigated. The composite films were characterized using scanning electron microscopy (SEM), energy dispersive X-ray spectroscopy (EDS) and X-ray diffraction (XRD). Ag particles (approximate size of 50 nm) were formed on the surface of PUS porous films when water was used as a solvent. In addition, increased AgNO
3
concentration or UV irradiation time facilitated a change in the conductivity state of PUS/Ag porous films from insulator to semiconductor. The as-prepared PUS/Ag composite porous films provided excellent electronic properties and thus provided significant potential for future application in various fields.
Graphical abstract |
| doi_str_mv | 10.1007/s00289-015-1568-0 |
| format | article |
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3
solution was then dripped onto the surface of films to form PUS/Ag composite porous films through the in situ photoreduction method, avoiding the use of harmful reducing agents. Key preparation factors, including solvent type, UV irradiation time and AgNO
3
concentration, were systematically investigated. The composite films were characterized using scanning electron microscopy (SEM), energy dispersive X-ray spectroscopy (EDS) and X-ray diffraction (XRD). Ag particles (approximate size of 50 nm) were formed on the surface of PUS porous films when water was used as a solvent. In addition, increased AgNO
3
concentration or UV irradiation time facilitated a change in the conductivity state of PUS/Ag porous films from insulator to semiconductor. The as-prepared PUS/Ag composite porous films provided excellent electronic properties and thus provided significant potential for future application in various fields.
Graphical abstract</description><identifier>ISSN: 0170-0839</identifier><identifier>EISSN: 1436-2449</identifier><identifier>DOI: 10.1007/s00289-015-1568-0</identifier><language>eng</language><publisher>Berlin/Heidelberg: Springer Berlin Heidelberg</publisher><subject>Aqueous solutions ; Characterization and Evaluation of Materials ; Chemistry ; Chemistry and Materials Science ; Complex Fluids and Microfluidics ; Electronic properties ; Friedel-Crafts reaction ; Humidity ; Irradiation ; Mercury lamps ; Molecular weight ; Nanoparticles ; Organic Chemistry ; Original Paper ; Physical Chemistry ; Polymer films ; Polymer Sciences ; Polymers ; Pore size ; Reducing agents ; Scanning electron microscopy ; Silver ; Silver nitrate ; Soft and Granular Matter ; Solvents ; Ultraviolet radiation</subject><ispartof>Polymer bulletin (Berlin, Germany), 2016-06, Vol.73 (6), p.1639-1647</ispartof><rights>Springer-Verlag Berlin Heidelberg 2015</rights><rights>Springer-Verlag Berlin Heidelberg 2015.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c353t-19e31edab660eef303a8015a3e0b40fee8da2d821a1130ea0ae2eae8d20c79e83</citedby><cites>FETCH-LOGICAL-c353t-19e31edab660eef303a8015a3e0b40fee8da2d821a1130ea0ae2eae8d20c79e83</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,780,784,27924,27925</link.rule.ids></links><search><creatorcontrib>Wang, Donghui</creatorcontrib><creatorcontrib>Zhang, Meng</creatorcontrib><creatorcontrib>Luo, Zhen</creatorcontrib><creatorcontrib>Bai, Weibin</creatorcontrib><creatorcontrib>Xu, Yanlian</creatorcontrib><creatorcontrib>Lin, Jinhuo</creatorcontrib><title>Fabrication of polyurushiol/Ag composite porous films using an in situ photoreduction method</title><title>Polymer bulletin (Berlin, Germany)</title><addtitle>Polym. Bull</addtitle><description>In this work, polyurushiol (PUS) was synthesized through a Friedel–Crafts reaction using brönsted acid as a catalyst. The product was then utilized in the fabrication of honeycomb porous films by breath figures (BFs). The PUS porous films were subsequently exposed to a high pressure mercury lamp for several seconds (5–30 s). An AgNO
3
solution was then dripped onto the surface of films to form PUS/Ag composite porous films through the in situ photoreduction method, avoiding the use of harmful reducing agents. Key preparation factors, including solvent type, UV irradiation time and AgNO
3
concentration, were systematically investigated. The composite films were characterized using scanning electron microscopy (SEM), energy dispersive X-ray spectroscopy (EDS) and X-ray diffraction (XRD). Ag particles (approximate size of 50 nm) were formed on the surface of PUS porous films when water was used as a solvent. In addition, increased AgNO
3
concentration or UV irradiation time facilitated a change in the conductivity state of PUS/Ag porous films from insulator to semiconductor. The as-prepared PUS/Ag composite porous films provided excellent electronic properties and thus provided significant potential for future application in various fields.
Graphical abstract</description><subject>Aqueous solutions</subject><subject>Characterization and Evaluation of Materials</subject><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Complex Fluids and Microfluidics</subject><subject>Electronic properties</subject><subject>Friedel-Crafts reaction</subject><subject>Humidity</subject><subject>Irradiation</subject><subject>Mercury lamps</subject><subject>Molecular weight</subject><subject>Nanoparticles</subject><subject>Organic Chemistry</subject><subject>Original Paper</subject><subject>Physical Chemistry</subject><subject>Polymer films</subject><subject>Polymer Sciences</subject><subject>Polymers</subject><subject>Pore size</subject><subject>Reducing agents</subject><subject>Scanning electron microscopy</subject><subject>Silver</subject><subject>Silver nitrate</subject><subject>Soft and Granular Matter</subject><subject>Solvents</subject><subject>Ultraviolet radiation</subject><issn>0170-0839</issn><issn>1436-2449</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2016</creationdate><recordtype>article</recordtype><recordid>eNp1UM9LwzAUDqLgnP4B3gKe416Srk2PYzgVBl70JoSsfd0y2qYmzWH_vZkVPHl6vPf94n2E3HN45ADFIgAIVTLgS8aXuWJwQWY8kzkTWVZekhnwAhgoWV6TmxCOkPY85zPyuTE7byszWtdT19DBtafoYzhY1y5We1q5bnDBjpgQ72KgjW27QGOw_Z6antqeJjTS4eBG57GO1Y9Th-PB1bfkqjFtwLvfOScfm6f39Qvbvj2_rldbVsmlHBkvUXKszS7PAbGRII1KjxiJsMugQVS1EbUS3HAuAQ0YFGjSVUBVlKjknDxMvoN3XxHDqI8u-j5FalHyQhVS5ZBYfGJV3oXgsdGDt53xJ81Bn0vUU4k6ZetzifqsEZMmJG6_R__n_L_oG9WedoA</recordid><startdate>20160601</startdate><enddate>20160601</enddate><creator>Wang, Donghui</creator><creator>Zhang, Meng</creator><creator>Luo, Zhen</creator><creator>Bai, Weibin</creator><creator>Xu, Yanlian</creator><creator>Lin, Jinhuo</creator><general>Springer Berlin Heidelberg</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope><scope>8FE</scope><scope>8FG</scope><scope>ABJCF</scope><scope>AFKRA</scope><scope>BENPR</scope><scope>BGLVJ</scope><scope>CCPQU</scope><scope>D1I</scope><scope>DWQXO</scope><scope>HCIFZ</scope><scope>KB.</scope><scope>PDBOC</scope><scope>PQEST</scope><scope>PQQKQ</scope><scope>PQUKI</scope></search><sort><creationdate>20160601</creationdate><title>Fabrication of polyurushiol/Ag composite porous films using an in situ photoreduction method</title><author>Wang, Donghui ; Zhang, Meng ; Luo, Zhen ; Bai, Weibin ; Xu, Yanlian ; Lin, Jinhuo</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c353t-19e31edab660eef303a8015a3e0b40fee8da2d821a1130ea0ae2eae8d20c79e83</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2016</creationdate><topic>Aqueous solutions</topic><topic>Characterization and Evaluation of Materials</topic><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>Complex Fluids and Microfluidics</topic><topic>Electronic properties</topic><topic>Friedel-Crafts reaction</topic><topic>Humidity</topic><topic>Irradiation</topic><topic>Mercury lamps</topic><topic>Molecular weight</topic><topic>Nanoparticles</topic><topic>Organic Chemistry</topic><topic>Original Paper</topic><topic>Physical Chemistry</topic><topic>Polymer films</topic><topic>Polymer Sciences</topic><topic>Polymers</topic><topic>Pore size</topic><topic>Reducing agents</topic><topic>Scanning electron microscopy</topic><topic>Silver</topic><topic>Silver nitrate</topic><topic>Soft and Granular Matter</topic><topic>Solvents</topic><topic>Ultraviolet radiation</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Wang, Donghui</creatorcontrib><creatorcontrib>Zhang, Meng</creatorcontrib><creatorcontrib>Luo, Zhen</creatorcontrib><creatorcontrib>Bai, Weibin</creatorcontrib><creatorcontrib>Xu, Yanlian</creatorcontrib><creatorcontrib>Lin, Jinhuo</creatorcontrib><collection>CrossRef</collection><collection>ProQuest SciTech Collection</collection><collection>ProQuest Technology Collection</collection><collection>Materials Science & Engineering Collection</collection><collection>ProQuest Central</collection><collection>AUTh Library subscriptions: ProQuest Central</collection><collection>Technology Collection</collection><collection>ProQuest One Community College</collection><collection>ProQuest Materials Science Collection</collection><collection>ProQuest Central</collection><collection>SciTech Premium Collection</collection><collection>Materials Science Database</collection><collection>Materials Science Collection</collection><collection>ProQuest One Academic Eastern Edition (DO NOT USE)</collection><collection>ProQuest One Academic</collection><collection>ProQuest One Academic UKI Edition</collection><jtitle>Polymer bulletin (Berlin, Germany)</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Wang, Donghui</au><au>Zhang, Meng</au><au>Luo, Zhen</au><au>Bai, Weibin</au><au>Xu, Yanlian</au><au>Lin, Jinhuo</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Fabrication of polyurushiol/Ag composite porous films using an in situ photoreduction method</atitle><jtitle>Polymer bulletin (Berlin, Germany)</jtitle><stitle>Polym. Bull</stitle><date>2016-06-01</date><risdate>2016</risdate><volume>73</volume><issue>6</issue><spage>1639</spage><epage>1647</epage><pages>1639-1647</pages><issn>0170-0839</issn><eissn>1436-2449</eissn><abstract>In this work, polyurushiol (PUS) was synthesized through a Friedel–Crafts reaction using brönsted acid as a catalyst. The product was then utilized in the fabrication of honeycomb porous films by breath figures (BFs). The PUS porous films were subsequently exposed to a high pressure mercury lamp for several seconds (5–30 s). An AgNO
3
solution was then dripped onto the surface of films to form PUS/Ag composite porous films through the in situ photoreduction method, avoiding the use of harmful reducing agents. Key preparation factors, including solvent type, UV irradiation time and AgNO
3
concentration, were systematically investigated. The composite films were characterized using scanning electron microscopy (SEM), energy dispersive X-ray spectroscopy (EDS) and X-ray diffraction (XRD). Ag particles (approximate size of 50 nm) were formed on the surface of PUS porous films when water was used as a solvent. In addition, increased AgNO
3
concentration or UV irradiation time facilitated a change in the conductivity state of PUS/Ag porous films from insulator to semiconductor. The as-prepared PUS/Ag composite porous films provided excellent electronic properties and thus provided significant potential for future application in various fields.
Graphical abstract</abstract><cop>Berlin/Heidelberg</cop><pub>Springer Berlin Heidelberg</pub><doi>10.1007/s00289-015-1568-0</doi><tpages>9</tpages></addata></record> |
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| ispartof | Polymer bulletin (Berlin, Germany), 2016-06, Vol.73 (6), p.1639-1647 |
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| subjects | Aqueous solutions Characterization and Evaluation of Materials Chemistry Chemistry and Materials Science Complex Fluids and Microfluidics Electronic properties Friedel-Crafts reaction Humidity Irradiation Mercury lamps Molecular weight Nanoparticles Organic Chemistry Original Paper Physical Chemistry Polymer films Polymer Sciences Polymers Pore size Reducing agents Scanning electron microscopy Silver Silver nitrate Soft and Granular Matter Solvents Ultraviolet radiation |
| title | Fabrication of polyurushiol/Ag composite porous films using an in situ photoreduction method |
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